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INDONESIA
Indonesian Journal of Chemistry
ISSN : 14119420     EISSN : 24601578     DOI : -
Indonesian Journal of Chemistry is an International, peer-reviewed, open access journal that publishes original research articles, review articles, as well as short communication in all areas of chemistry including applied chemistry. The journal is accredited by The Ministry of Research, Technology and Higher Education (RISTEKDIKTI) No : 21/E/KPT/2018 (in First Rank) and indexed in Scopus since 2012. Since 2018 (Volume 18), Indonesian Journal of Chemistry publish four issues (numbers) annually (February, May, August and November).
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Articles 14 Documents
Search results for , issue "Vol 15, No 2 (2015)" : 14 Documents clear
Cadmium Adsorption on Chitosan/Chlorella Biomass Sorbent Prepared by Ionic-Imprinting Technique Anis Shofiyani; Narsito Narsito; Sri Juari Santosa; Sri Noegrohati; Titin Anita Zahara; Endah Sayekti
Indonesian Journal of Chemistry Vol 15, No 2 (2015)
Publisher : Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (390.111 KB) | DOI: 10.22146/ijc.21210

Abstract

Ionic-Imprinted Chitosan/Chlorella biomass sorbent (IICCb) has been synthesized for selective adsorption of Cd(II) adsorption. IICCb was prepared by coating Cd(II)-complexed-chitosan hydrogel on the biomass surface followed by cross-linking procedure. Cd(II)-imprinting ions were then eluted using Na2EDTA solution to provide a specific template for binding sites of Cd(II). Batch adsorption was carried out as function of initial pH, contact time, and initial concentration of the Cd(II) solution. Result showed that the optimum adsorption of Cd(II) was found at pH 4-6. Study of pseudo-second order kinetic showed that the adsorption of Cd(II) on IICCb went faster than that on Ionic-Imprinted Chitosan (IIC) or Non-Imprinted Ionic Chitosan/Chlorella sorbent (NIICCb). The maximum Cd(II) adsorption capacity as obtained from Langmuir adsorption isotherm was found to be 53.76 mg/g on IICCb, that was comparatively higher than that on IIC (44.44 mg/g) or on NIICCb (51.02 mg/g) adsorbent.
Synthesis and Characterization of Alumina Precursors Derived from Aluminum Metal through Electrochemical Method Eva Marlina Ginting; Nurdin Bukit
Indonesian Journal of Chemistry Vol 15, No 2 (2015)
Publisher : Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (478.763 KB) | DOI: 10.22146/ijc.21205

Abstract

This study investigated the use of the electrochemical method to prepare alumina (a-Al2O3) from aluminum metal. The a-Al2O3 precursor was calcined at 110 °C for six hours and then characterized using Fourier Transform Infrared (FTIR) spectroscopy, Particle Size Analysis (PSA), X-Ray Diffraction spectroscopy (XRD), and Scanning Electron Microscopy (SEM). To study transformation of the precursor into α-Al2O3, three samples were sintered at 400, 800, and 1200 °C, respectively and they were characterized. The most interesting result obtained was the transition of AlOOH and β-Al(OH)3 into γ-Al2O3 at low temperatures (400 to 800°C), followed by transformation of γ-Al2O3 into a-Al2O3 at high temperature (1200 °C). The overall results obtained demonstrated that electrochemical method is a potential alternative for production of α-Al2O3, which can be achieved in practically pure phase at sintering temperature at 1200 °C.
Structure and Dynamics of Zr4+ in Aqueous Solution: An Ab Initio QM/MM Molecular Dynamics Study Suwardi Suwardi; Harno Dwi Pranowo; Ria Armunanto
Indonesian Journal of Chemistry Vol 15, No 2 (2015)
Publisher : Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (443.324 KB) | DOI: 10.22146/ijc.21209

Abstract

A QM/MM molecular dynamics (MD) simulation has been carried out using three-body corrected pair potential to investigate the structural and dynamical properties of Zr4+ in dilute aqueous solution. Structural data in the form of radial distribution function, coordination number distribution, and angular distribution function were obtained. The results indicate eight water molecules coordinate to zirconium ion and have two angles of O-Zr4+-O, i.e. 72.0° and 140.0° with a Zr4+-O distance of 2.34 Å. According to these results, the hydration structure of Zr4+ ion in water was more or less well-defined square antiprismatic geometry. The dynamical properties have been characterized by the ligand’s mean residence time (MRT) and Zr4+-O stretching frequencies. The inclusion of the three-body correction was important for the description of the hydrated Zr4+ ion, and the results indicated in good agreement with experimental values.
Characteristics of Nanosize Spinel NixFe3-xO4 Prepared by Sol-Gel Method Using Egg White as Emulsifying Agent Rudy Situmeang; Sukma Wibowo; Wasinton Simanjuntak; R. Supryanto; Rizki Amalia; Mitra Septanto; Posman Manurung; Simon Sembiring
Indonesian Journal of Chemistry Vol 15, No 2 (2015)
Publisher : Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (438.236 KB) | DOI: 10.22146/ijc.21204

Abstract

In this study, sol-gel method using egg white as emulsifying agent was applied to prepare nano size spinel NixFe3-xO4 (with x = 0.2–1). Sample preparation was carried out by mixing the solution of Fe(NO3)3.9 H2O and Ni(NO3)3.6 H2O with egg white, and then the sample was stirred thoroughly using magnetic stirrer. After freeze–drying process, the sample was subjected to calcination treatment and subsequently characterized. The phase composition was evaluated using the X-ray diffraction (XRD) technique, followed by quantitative analysis using Rietveld and Debye-Scherrer Methods. The functionality of the sample was identified using Fourier Transform Infrared (FTIR) spectroscopy, and surface morphology and elemental composition were analyzed using scanning electron microscopycoupled with electron dispersive spectroscopy (SEM/EDS). The results of XRD characterization indicated that materials consist of various crystalline phases, with NiFe2O4 as a major phase. FTIR Analysis revealed the existence of both Lewis and Brønsted–Lowry acid sites, with Lewis acid as the prominent site. The sample was found to display relatively homogeneous surface morphology, having the crystallite size in the range of 33 to 61 nm according to the Debye-Scherrer equation. The EDS data indicated that the ratio of Fe/Ni is in agreement with the composition of the raw materials used.

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