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Indonesian Journal of Chemistry

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Published by Universitas Gadjah Mada

ISSN : 14119420 EISSN : 24601578 DOI : -

Core Subject : Science, Engineering,

Chemical Engineering, Chemistry & Bioengineering Chemistry

Indonesian Journal of Chemistry is an International, peer-reviewed, open access journal that publishes original research articles, review articles, as well as short communication in all areas of chemistry including applied chemistry. The journal is accredited by The Ministry of Research, Technology and Higher Education (RISTEKDIKTI) No : 21/E/KPT/2018 (in First Rank) and indexed in Scopus since 2012. Since 2018 (Volume 18), Indonesian Journal of Chemistry publish four issues (numbers) annually (February, May, August and November).

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Articles 30 Documents

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Search results for , issue "Vol 19, No 3 (2019)" : 30 Documents clear

Effect of Torrefaction Temperature, Residence Time and Particle Size on the Properties of Torrefied Food Waste Ruwaida Abdul Rasid; Thye Mei Chin; Mazni Ismail; Nahsya Nur Udzaifah Abdul Rahman
Indonesian Journal of Chemistry Vol 19, No 3 (2019)
Publisher : Universitas Gadjah Mada

Municipal solid waste (MSW) in Malaysia mainly consists of food waste. As food waste is of organic compounds, its improper management may cause serious environmental issues, as it may produce greenhouse gases and polluting leachate. Alternative management of the food waste is through its utilization. However, the main issue in the utilization of food waste is its heterogeneity, whereby the diversified cooking methods, as well as food origin, emanates different characteristics. Hence, food waste needs to be pre-treated through the torrefaction process, which is a thermochemical method that converts it to biochar at a temperature between 200–300 °C in an inert environment. The main aim of this work is to evaluate the feasibility of food waste as a potential source of energy through the torrefaction process. The torrefaction of food waste was conducted in a vertical tubular reactor under an inert atmosphere. The results obtained from this study showed that as torrefaction temperature became more severe, the produced torrefied solid is more energy-dense, with apparent higher fixed carbon content and improved heating values. These findings imply that food waste may be able to be utilized as a solid biofuel, with fuel properties comparable to conventional fuels.

Synthesis and Characterization of Cu-Doped Zirconium Titanate as A Potential Visible-Light Responsive Photocatalyst Katarina Rachma Andita; Rian Kurniawan; Akhmad Syoufian
Indonesian Journal of Chemistry Vol 19, No 3 (2019)
Publisher : Universitas Gadjah Mada

Synthesis and characterization of Cu-doped zirconium titanateas a potential visible-light responsive photocatalyst had been conducted. Titanium tetraisopropoxide (TTIP) was used as a precursor of Ti source, reacted to ZrO2 powderand CuSO4·5H2O with various Cu concentrations of 0, 1, 3, 5, 7 and 9% (w/w) by sol-gel method. Zirconium titanate with Cu concentration of 5% was calcined at various temperatures of 500, 700 and 900 °C. All materials were characterized by using XRD, FTIR, SRUV, and SEM-EDX. The characterization proved that the materials were potential as a model of visible-light responsive photocatalyst. Composite with optimum bandgap energy (Eg) was obtained at 5% Cu content after 500 °C with an absorption edge wavelength of 431.93 nm and the bandgap of 2.87 eV.

Effect of Immobilization Method on the Growth of Chlorella vulgaris and Fatty Acid Profile for Biodiesel Production Nur Hanani Rushan; Nur Hidayah Mat Yasin; Noor Raihana Abu Sepian; Farhan Mohd Said; Nurafifah Izzati Shafei
Indonesian Journal of Chemistry Vol 19, No 3 (2019)
Publisher : Universitas Gadjah Mada

The aim of this research is to study the immobilization effect on growth cell of microalgae Chlorella vulgaris. The comparison of lipid production between immobilized microalgae and free cell culture was also studied and the fatty acid methyl ester for biodiesel production was identified in this research. Four important steps were done in this research which included microalgae cultivation, harvesting method by immobilization, lipid extraction and transesterification of oil. In the immobilization method, the combination of matrix system of sodium alginate and sodium carboxymethylcellulose (SA and CMC) gave the highest number of cells of microalgae after the 9th day of the cultivation process. However, the immobilized microalgae matrix system of SA at volumetric ratio of 0.3:1 showed better results for extraction of oil, attaining an oil yield percentage of 46% compared with other matrix systems studied; SA + CA + CMC (43.00%), SA + CA (41.19%), SA + CMC (40.38%) and free cell culture (42.57%). Furthermore, the fatty acids methyl ester profile of the extracted oil showed high potential for biodiesel production. The results proved that the immobilization of microalgae had improved the oil yield and fatty acid composition as compared to the free cell culture, which may have useful application for the biofuel industry.

Docking of New Designed Compounds Derived from 1,6-Dihydro-1,3,5-triazine-2,4-diamine Toward Quadruple Mutant Plasmodium Dihydrofolate Reductase Imam Siswanto; Harno Dwi Pranowo; Mudasir Mudasir
Indonesian Journal of Chemistry Vol 19, No 3 (2019)
Publisher : Universitas Gadjah Mada

Resistance to the traditional antifolates is now widespread in Plasmodium falciparum and Plasmodium vivax. To find the interaction model of some compounds derived from 1,6-dihydro-1,3,5-triazine-2,4-diamine, molecular docking technique was carried out using these compounds ligand and pDHFR as the receptor. Complex ligand and the receptor from Protein Data Bank (PDB ID 1J3K) were chosen as an interaction model between a ligand and its receptor. Each compound was optimized using ab initio methods with 6-311G basis set. Partial charges of ligand were added using AM1-BCC methods. Each ligand was docked to the receptor utilizing Dock6 software. Theoretical prediction based on the binding energy between these compounds as the ligand with pDHFR as receptor resulted in 1 compound, namely 6,6-dimethyl-1-[3-(2-chloro-4,5-dibromophenoxy)propoxy]-1,6-dihydro-1,3,5-triazine-2,4-diamine possessing binding affinity better than that of WR99210 which was known to have good antimalarial activity.

Inhibitive Determination of Hg(II) in Aqueous Solution Using Urease Amperometric Biosensor Dhony Hermanto; Bambang Kuswandi; Dwi Siswanta; Mudasir Mudasir
Indonesian Journal of Chemistry Vol 19, No 3 (2019)
Publisher : Universitas Gadjah Mada

An amperometric biosensor for the indirect determination of Hg(II) has been developed based on inhibition of urease (EC 3.5.1.5) immobilized into alginate–chitosan polyelectrolyte complexes membrane. The biosensor response was monitored by following the reduction peak of hydrolyzed urea at around -0.15 V. The amperometric biosensor has a dynamic range 40–90 ppb Hg(II) with limit of detection of 66.45 ppb toward Hg(II) ions, repeatability (CV) value of 0.86% and only Ag(I) as the main potential interference. The sensor shows a stable and reproducible response for more than 2 weeks when it stored dry at 4 °C. The analytical results of Hg(II)-spiked water sample showed a good agreement with those obtained by atomic absorption spectrometry method, suggesting that the developed method may be applied in the determination of Hg(II) in the water samples.

Extraction of Phytosterol Concentration in Different Legume Pods by Using Microwave-Assisted Hydrodistillation Noormazlinah Noormazlinah; Norlaili Hashim; Abdurahman Hamid Nour; Mimi Sakinah Abdul Munaim; Maria Pilar Almajano; Nurul Bahirah
Indonesian Journal of Chemistry Vol 19, No 3 (2019)
Publisher : Universitas Gadjah Mada

The traditional ways in the extraction of bioactive compounds using conventional methods are disadvantageous from both economic and environmental perspectives. In this, the potential of microwave-assisted hydrodistillation conditions for extraction of phytosterol from legume pods was investigated. Salkowski test performed on the legume pod has shown the reddish brown in all sample which confirmed the presence of phytosterol qualitatively. Liebermann-Burchard procedure and ultraviolet-visible spectroscopy (UV-Vis) apparatus were used to study the concentration of phytosterol at different extraction parameters which are temperature (25–80 °C), solvent concentration (50–100% v/v), irradiation time (1–10 min) and microwave power (400–800 W). The optimal conditions for highest yield of extract (0.219 mg/L) were obtained at a microwave power of 600 W, the irradiation time of 6 min, and ethanol concentration of 75% v/v. Results obtained in this study have shown the capability of microwave-assisted hydrodistillation in the extraction of phytosterol from legume pod. Further works are nevertheless required to provide a deeper understanding of the mechanisms involved to facilitate the development of an optimum system applicable to the industry.

The Potentials of an Integrated Ultrasonic Membrane Anaerobic System (IUMAS) in Treating Sugar Cane Wastewater Abdurahman Hamid Nour; Yasmeen Hafiz Zaki; Hybat Salih Mohamed; Hesham Hussein Rassem
Indonesian Journal of Chemistry Vol 19, No 3 (2019)
Publisher : Universitas Gadjah Mada

Excess levels of organic and inorganic matters in the discharge from sugarcane mill effluent (SCME) wastewater, causes the earnest environmental issue. In this study, a single unit integrated ultrasonic membrane anaerobic system (IUMAS) has been investigated for industrial sugarcane wastewater treatment. As the “Membrane-fouling” is one of the main constraints of IUMAS which eventually reduce the processing ability. In the present study, most researchers resort to cost reduction. IUMAS was alternatively applied as an economical approach for SCME wastewater treatment. The application of “Multiple-analysis” methods (COD, BOD, TSS) and three kinetic models during the treatment, suggested the specific range of organic loading rate to produce biogas. The result showed the increased methane gas production up to 80% in the biogas, with 94 -96% of COD removal efficiency from the SCME wastewater. Results concluded the effective efficiency of IUMAS to reduce the membrane fouling and treatment of SCME wastewater as well as enhanced production of methane gas.

Statistical Modelling of Ultrasonic-Aided Extraction of Elaeis guineensis Leaves for Better-Quality Yield and Total Phenolic Content Nissha Bharrathi Romes; Mariani Abdul Hamid; Siti Ernieyanti Hashim; Roswanira Abdul Wahab
Indonesian Journal of Chemistry Vol 19, No 3 (2019)
Publisher : Universitas Gadjah Mada

The present study highlighted the statistical modeling of an ultrasonic-aided extraction (UAE) of Elaeis guineensis leaves extract for maximal extraction yield (EY) and total phenolic content (TPC). A Box-Behnken design investigated the effects of ethanol concentration (X1: 0−100%), extraction time (X2: 5−55 min), the solvent-to-solid ratio (X3: 15:1−35:1 mL/g) and sonification amplitude (X4: 20−100 %). Under optimized conditions, the highest EY of 14.38% was attained using 50% (v/v) ethanol:water ratio, 55 min, 35 mL/g solvent-to-solid ratio, 60% sonication amplitude, whereas maximum TPC was 209.70 mg gallic acid equivalent (GAE)/g [50% (v/v) ethanol:water ratio, 30 min, 25 mL/g solvent-to-solid ratio, 60% sonication amplitude]. Second-order polynomial models of EY and TPC showed the R2 value corresponding to 0.9303 and 0.9500, respectively, indicating their significance (p < 0.05) to predict the responses. HPLC chromatograms revealed gallic acid and catechin were present in the UAE extracts. UAE technique afforded better EY (14.38%) and TPC (209.70 mg GAE/g) than maceration (3.73%, 85.23 mg GAE/g) and Soxhlet (6.86%, 102.13 mg GAE/g) extractions, as based on scanning electron micrographs of untreated, UAE, macerated and Soxhlet treated samples. Cell walls of ultrasonic-treated E. guineensis leaves were visibly disrupted to facilitate the higher release of bioactive plant materials, thus justifying the higher EY and TPC. The application of ultrasound appeared to remarkably increase the extraction efficiency of E. guineensis leaves to extract as compared to the conventional methods.

Synthesis of Mesoporous Carbon from Merbau Wood (Intsia spp.) by Microwave Method as Ni Catalyst Support for α-Cellulose Hydrocracking Andaru Dena Prasiwi; Wega Trisunaryanti; Triyono Triyono; Iip Izul Falah; Darma Santi; Muhammad Fajar Marsuki
Indonesian Journal of Chemistry Vol 19, No 3 (2019)
Publisher : Universitas Gadjah Mada

Synthesis of mesoporous carbon from Merbau wood (Intsia spp.) waste by microwave method as nickel catalyst support for α-cellulose hydrocracking had been carried out. The Merbau wood sawdust was carbonized at 800 °C to produce C800 and the C800 was treated by microwave irradiation (399 W) for 5 min to produce C800MW. The Merbau wood flakes, which were only treated by microwave irradiation (399 Watts) for 30 min produced CMW. Wet impregnation technique was carried out to disperse the Ni metal (1.0, 1.5, and 2.0 wt.%) onto the best mesoporous carbon. The mesoporous carbons were analyzed by Fourier Transform Infra-Red Spectroscopy (FTIR), Surface Area Analyzer (SAA) and Scanning Electron Microscopy (SEM). The hydrocracking of pyrolyzed α-cellulose was carried out at 400 °C. The liquid product was analyzed by Gas Chromatograph-Mass Spectrometer (GC-MS). The results showed that the C800MW was the best performance carbon and it had a specific surface area, total pore volume, average pore diameter and acidity of 364.12 m2/g, 0.28 cm3/g, 3.03 nm, and 2.18 mmol/g, respectively. The Ni1.5/C800MW catalyst produced the highest conversion of liquid product (58.76 wt.%) than the Ni1/C800MW (57.51 wt.%) and Ni2/C800MW (34.18 wt.%).

Corrosion Inhibition of Carbon Steel Using Palm Oil Leaves Extract Nor Insyirah Hairul Salleh; Arman Abdullah
Indonesian Journal of Chemistry Vol 19, No 3 (2019)
Publisher : Universitas Gadjah Mada

Palm oil (Elaeis guineensis) leaves extract was investigated on its potential to inhibit carbon steel corrosion via weight loss and potentiodynamic polarisation methods. Corrosion inhibition of carbon steel using palm oil leaves extract was determined at various temperatures, salinities, and concentrations. The inhibition efficiency increased with the increasing of inhibitor concentration but decreased with the rise in temperature. The highest inhibitor efficiency was 83.70% with a corrosion rate of 0.44 mm/yr which was obtained at zero salinity (in distilled water) with 25% of inhibitor concentration at 303 K. The results obtained proved that the extract solution from palm oil leaves can be used as an effective inhibitor of carbon steel in seawater.

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