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Indonesian Journal of Chemistry

ijc
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Published by Universitas Gadjah Mada

ISSN : 14119420 EISSN : 24601578 DOI : -

Core Subject : Science, Engineering,

Chemical Engineering, Chemistry & Bioengineering Chemistry

Indonesian Journal of Chemistry is an International, peer-reviewed, open access journal that publishes original research articles, review articles, as well as short communication in all areas of chemistry including applied chemistry. The journal is accredited by The Ministry of Research, Technology and Higher Education (RISTEKDIKTI) No : 21/E/KPT/2018 (in First Rank) and indexed in Scopus since 2012. Since 2018 (Volume 18), Indonesian Journal of Chemistry publish four issues (numbers) annually (February, May, August and November).

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Articles 25 Documents

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Search results for , issue "Vol 20, No 2 (2020)" : 25 Documents clear

Chemical Literacy: Performance of First Year Chemistry Students on Chemical Kinetics Muntholib Muntholib; Suhadi Ibnu; Sri Rahayu; Fauziatul Fajaroh; Sentot Kusairi; Bambang Kuswandi
Indonesian Journal of Chemistry Vol 20, No 2 (2020)
Publisher : Universitas Gadjah Mada

This study aims to (1) develop and validate a multiple choice chemical literacy test instrument (MC-CLTI) on chemical kinetics and (2) conduct a small survey on chemical literacy of first year chemistry students. The development of the instrument involved expert consultation and judgment, validation and two times pilot studies. The first pilot study involved 119 first year chemistry students while the second pilot study involved 197 second year chemistry students. The final form of MC-CLTI consists of 30 valid and reliable items (Cronbach's Alpha coefficient = 0.744). The survey showed that the average score of respondents' chemical literacy was 63.24. This score is in the range of the average scores reported by several previous studies.

Preparation, Characterization and Study of the Photodecolorization of Mixed-Ligand Binuclear Co(II) Complex of Schiff Base by ZnO Suhad Kareem Abass; Jassim Abbas Al-Hilfi; Sawsan Khudhair Abbas; Luma Majeed Ahmed
Indonesian Journal of Chemistry Vol 20, No 2 (2020)
Publisher : Universitas Gadjah Mada

In this work, a new mixed-ligand binuclear Co(II) complex of Schiff base was prepared. Moreover, the characterization of this prepared complex was performed by measurement of melting points, UV-Vis spectra, FT-IR spectra, and magnetic susceptibility measurements, and later compared with metal and ligand solutions. It has been discovered that the Schiff bases with Co(II) ion forms a binuclear complex with a stoichiometry of molar ratio 1:2 from “metal:ligand”. The photodecolorization of this complex was done under UV light for ZnO's suspension solution. The results of this photodecolorization showed that the greatest efficiency was obtained with the use of ZnO dose of 300 mg/100 mL and at an initial pH of 7. The decolorization activation energy for this complex is a small value of 11.289 kJ mol–1. Additionally, the thermodynamic study for this reaction is non-spontaneous, endothermic and less random.

Fuel Production from LDPE-based Plastic Waste over Chromium Supported on Sulfated Zirconia Latifah Hauli; Karna Wijaya; Akhmad Syoufian
Indonesian Journal of Chemistry Vol 20, No 2 (2020)
Publisher : Universitas Gadjah Mada

The preparation, characterization, and catalytic activity test of sulfated zirconia (SZ) modified with chromium for the hydrocracking of LDPE-based plastic waste have been investigated. SZ was prepared by wet impregnation method using zirconia nanopowder (ZrO2) and H2SO4 solution. SZ was further modified with chromium (0.5, 1.0, and 1.5% wt.%) by refluxing in aqueous solution of Cr(NO3)3·9H2O, followed by calcination and reduction processes. The prepared catalysts were characterized by SEM-Mapping and TEM. Hydrocracking of LDPE-based plastic waste was conducted at various temperatures and various catalysts. In addition, the optimum catalyst was repeatedly used for the reaction to demonstrate the stability of the catalyst. Liquid products obtained by hydrocracking were characterized by GCMS. The results showed that the morphology of the prepared catalysts had different sizes and disordered shapes after the addition of sulfate and Cr. The effective temperature for hydrocracking was 250 °C. The highest selectivity to liquid product and gasoline fraction were 40.99 and 93.42 wt.%, respectively, and were obtained over Cr/SZ with 1.0 wt.% Cr. Hydrocracking of plastic waste over the used Cr/SZ catalyst with 1.0 wt.% Cr showed that the Cr/SZ catalyst was stable and reusable up to three repetitions.

Orange Peel Essential Oil Nanoemulsions Supported by Nanosilver for Antibacterial Application Doan Van Dat; Nguyen Van Cuong; Pham Hoang Ai Le; Tran Thi Lan Anh; Pham Tan Viet; Nguyen Thi Lan Huong
Indonesian Journal of Chemistry Vol 20, No 2 (2020)
Publisher : Universitas Gadjah Mada

This study is devoted to the synthesis of King Orange peel essential oil in water nanoemulsions combined with nanosilver by ultrasonic method supported by mechanical stirring for antibacterial application. The samples were characterized by Gas chromatography-mass spectrometry (GC-MS), Ultraviolet–visible (UV-Vis), Transmission electron microscopy (TEM), and Dynamic light scattering (DLS) methods. According to the above-experimental results, it was found that the emulsions based on orange essential oil (without nanosilver) and the ones combined with nanosilver have the average particle size from 66.2 nm and 42.9 nm, respectively. The obtained nanoemulsions were also tested to examine their antibacterial ability against Escherichia coli (E. coli) by the disc diffusion method. It has been also found that nanoemulsions based on orange essential oil supported by nanosilver have the superior antibacterial ability, compared with individual components of the materials.

Mathematical Modeling of Reactive Extraction of Solute from Slab Solid Material Indah Hartati; Hary Sulistyo; Wahyudi Budi Sediawan; Muhammad Mufti Azis; Moh Fahrurrozi
Indonesian Journal of Chemistry Vol 20, No 2 (2020)
Publisher : Universitas Gadjah Mada

Reactive extraction is gaining higher attention due its wide application in various solute separation processes. Here, a mathematical model of reactive extraction in slab has been proposed. The model was developed by considering simultaneous processes of active compound intra particle diffusion, second order elemental reaction of solute-active compound, and intra-particle product diffusion. The obtained partial differential equations (PDEs) were solved using Finite Difference Approximation (FDA) method by using realistic parameters. Concentration profile as well as product yield were evaluated as a function of time. As a result, the model proposed here may serve as a basis design for reactive extraction unit. Sensitivity analyses was conducted to inspect the influence of slab thickness, diffusivity and reaction rate constant to the product yield. Eventually, model validation was conducted by comparing the simulation results with analytical solutions for special cases. Validation results showed that the model gave good agreement with the analytical solution.

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