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Indonesian Journal of Chemistry

ijc
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Published by Universitas Gadjah Mada

ISSN : 14119420 EISSN : 24601578 DOI : -

Core Subject : Science, Engineering,

Chemical Engineering, Chemistry & Bioengineering Chemistry

Indonesian Journal of Chemistry is an International, peer-reviewed, open access journal that publishes original research articles, review articles, as well as short communication in all areas of chemistry including applied chemistry. The journal is accredited by The Ministry of Research, Technology and Higher Education (RISTEKDIKTI) No : 21/E/KPT/2018 (in First Rank) and indexed in Scopus since 2012. Since 2018 (Volume 18), Indonesian Journal of Chemistry publish four issues (numbers) annually (February, May, August and November).

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Articles 27 Documents

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Search results for , issue "Vol 8, No 2 (2008)" : 27 Documents clear

MUTATION ON Bacillus subtilis BAC4 USING ACRIDINE ORANGE AS AN EFFORT FOR INCREASING ANTIBIOTIC PRODUCTION Supartono Supartono; Nanik Wijayati; Lina Herlina; Enny Ratnaningsih
Indonesian Journal of Chemistry Vol 8, No 2 (2008)
Publisher : Universitas Gadjah Mada

The efforts to get a new antibiotic require to be done continuously, because infection diseases still become the main health problems in Indonesia. A new local strain of Bacillus subtilis BAC4 has been known producing an antibiotic that inhibites Serratia marcescens ATCC 27117 growth. Nevertheless, the optimum conditions have not been studied seriously. The objective of this research was to conduct mutation on B. subtilis BAC4 in order to obtain a mutant cell that overproduct in producing antibiotic. The mutation process was performed by using acridine orange of 1 g.L-1 randomly at various volumes. The production of antibiotic was conducted using batch fermentation and antibiotic assay was performed with agar absorption method using S. marcescens ATCC 27117 as bacteria assay. Research result provided a B. subtilis M10 mutant with overproduction of antibiotic. Characterization of B. subtilis M10 mutant showed that the mutant cell has size of (0.5-1.0) µm x (1.85-2.5) µm; spore has the form of ellipse with thick wavy wall, positive reaction for catalase, and forming acid from glucose and xylose.

PHYTOCHEMICAL STUDY ON THE ETHYLACETATE EXTRACT OF THE LEAVES OF Mesua ferrea LINN S. M. Mizanur Rahman; Swati Shabnom; M. Abdul Quader; M. Amzad Hossain
Indonesian Journal of Chemistry Vol 8, No 2 (2008)
Publisher : Universitas Gadjah Mada

Furano-napthyl-hydroxy cyclohexyl type of compound was isolated first times in plant from the ethyl extracts of the leaves of Mesua ferrea. The structure of the compound has been established by the modern spectroscopic techniques such as UV, IR, 1H-NMR, 13C-NMR and mass spectroscopy and identified as 12, 13-furano-8-hydroxy napthyl-6-0-b-2',3',4',6' tetrahydroxy-5',5' dimethyl cyclohexyl ether.

SO2 EMISSION MEASUREMENT BY DOAS (DIFFERENTIAL OPTICAL ABSORPTION SPECTROSCOPY) AND COSPEC (CORRELATION SPECTROSCOPY) AT MERAPI VOLCANO (INDONESIA) Hanik Humaida
Indonesian Journal of Chemistry Vol 8, No 2 (2008)
Publisher : Universitas Gadjah Mada

The SO2 is one of the volcanic gases that can use as indicator of volcano activity. Commonly, SO2 emission is measured by COSPEC (Correlation Spectroscopy). This equipment has several disadvantages; such as heavy, big in size, difficulty in finding spare part, and expensive. DOAS (Differential Optical Absorption Spectroscopy) is a new method for SO2 emission measurement that has advantages compares to the COSPEC. Recently, this method has been developed. The SO2 gas emission measurement of Gunung Merapi by DOAS has been carried out at Kaliadem, and also by COSPEC method as comparation. The differences of the measurement result of both methods are not significant. However, the differences of minimum and maximum result of DOAS method are smaller than that of the COSPEC. It has range between 51 ton/day and 87 ton/day for DOAS and 87 ton/day and 201 ton/day for COSPEC. The measurement of SO2 gas emission evaluated with the seismicity data especially the rockfall showed the presence of the positive correlation. It may cause the gas pressure in the subsurface influencing instability of 2006 eruption lava.

SYNTHESIS OF SOME CINNAMIC ACID DERIVATIVES: EFFECT OF GROUPS ATTACHED ON AROMATIC RING TO THE REACTIVITY OF BENZALDEHYDE Marcellino Rudyanto; Lanny Hartanti
Indonesian Journal of Chemistry Vol 8, No 2 (2008)
Publisher : Universitas Gadjah Mada

Synthesis of cinnamic acid and its six derivatives has been done by employing Knoevenagel reaction. Benzaldehyde, 4-butylbenzaldehyde, 4-t-butylbenzaldehyde, 4-butoxybenzaldehyde, 4-phenylbenzaldehyde, 5-bromo-2,4-dimethoxybenzaldehyde, and 5-bromo-2,3-dimethoxybenzaldehyde were reacted with malonic acid in pyridine – piperidine to give cinnamic acid (85,3%), 4-butylcinnamic acid (69,3%), 4-t-butylcinnamic acid (77,7%), 4-butoxycinnamic acid (64,5%), 4-phenylcinnamic acid (65,5%), 5-bromo-2,4-dimethoxycinnamic acid (53,2%) and 5-bromo-2,4-dimethoxycinnamic acid (57,2%), respectively. It was disclosed that 4-alkyl, 4-alkoxy, 4-aryl, dan 2-alkoxy groups decrease the reactivity of carbonyl carbon of benzaldehyde.

PREPARATION OF CHITOSAN-GOLD NANOPARTICLES: PART 1 (OF 2). EFFECT OF REDUCING TECHNIQUE Adlim Adlim; Mohamad Abu Bakar
Indonesian Journal of Chemistry Vol 8, No 2 (2008)
Publisher : Universitas Gadjah Mada

Chitosan-stabilized gold nanoparticles were synthesized in aqueous formic acid, citric, or acetic acid with and without chitosan as the stabilizer. Refluxing in methanol, addition of hydrazine or sodium borohydride, photo-irradiation were employed as the reducing agents & reduction technique of gold ions. Dispersed particles of chitosan-stabilized gold were obtained in aqueous acetic acid-methanol solution. The chitosan-stabilized gold colloids (chi-Au) were dispersed and the particle size were in range of 9-30 nm, some of which were crystalline with various shapes. Chi-Au prepared with hydrazine as the reducing agent resulted in large and aggregated particles. The finest and dispersed chi-Au particles were obtained if NaBH4 was used as the reducing agent and the diameters could be controlled within 2.2-2.3 nm.

THE EFFECTS OF GRADIENT VELOCITY AND DETENTION TIME TO COAGULATION – FLOCCULATION OF DYES AND ORGANIC COMPOUND IN DEEP WELL WATER Muhamad Lindu
Indonesian Journal of Chemistry Vol 8, No 2 (2008)
Publisher : Universitas Gadjah Mada

The treatment of deep well water of Trisakti University by coagulation and flocculation using baffle channel system has been conducted. The detention time of hydrolic were varied. The coagulant dose was varied as 50, 100, 150, 200, 300, 350, 400, 450 and 500 ppm. Water of well sampel was added by coagulant with rotation velocity 200 rpm for 1 minute. The optimal coagulant dose was determined by measuring turbidity, colour, total suspended solids and organic compound. The result showed that the organic compound and colour of deep well water of Trisakti University could be reduced by coagulation and flocculation process by hydrolyc system. The optimal dose of the coagulant was 250 ppm. The removal efficiency of colour and organic compound using optimal dose for continuous flow reactor reached after water flow passed the reactor for 3 - 5 times detention time in the reactor. The optimal gradient velocity (G) was 30 - 35 sec-1 and collision energy (GT) was 65.000 - 79.000 to get optimal flocculation. With this condition, the removal efficiency of turbidity, colour and organic was more than 90%.

CALCIUM ABSORPTION KINETIC ON INDONESIAN RICE Chatarina Wariyah; Mary Astuti; Supriyadi Supriyadi; Chairil Anwar
Indonesian Journal of Chemistry Vol 8, No 2 (2008)
Publisher : Universitas Gadjah Mada

Calcium absorption kinetic from three varieties rice i.e. low-, medium-, and high amylose content were evaluated. Three calcium salt (calcium acetate, -lactate and - gluconate) were used as a fortifican. Each rice was soaked at the calcium salts at soaking temperatures of 80, 90 and 100 oC, for 30 min and the calcium content was analyzed periodically. Reaction rate constant was determined from slope of curve of the relation of soaking time and absorbed calcium. The activation energy was determined by Arrhenius equation. The research showed that rice calcium absorption follows the first-order kinetic and absorption rate tends to decrease with increasing temperature. Calcium absorptions were affected by calcium salt solubility. Calcium acetate was absorbed easier than calcium lactate and calcium lactate was absorbed easier than calcium gluconate, but the absorption rate constant of calcium acetate was lower than that of calcium lactate, and calcium lactate was lower than calcium gluconate. Based on amylose content of rice, the higher the amylose content, the lower calcium absorption rate. The activation anergy of the high amylose rice was higher than that of low amylose content.

PHOTODYNAMIC THERAPY: NEW LIGHT IN MEDICINE WORLD Venny Santosa; Leenawaty Limantara
Indonesian Journal of Chemistry Vol 8, No 2 (2008)
Publisher : Universitas Gadjah Mada

Photodynamic therapy (PDT) is a considerably new kind of photochemotherapeutic treatment in medical field. It combines the use of three components, which are a photosensitizer, light and oxygen. Photosensitizer is a compound activated by light. The application can be oral, topical or intravenous. It usually member of porphyrin group with ampiphilic characteristics. Photosensitizer can be of generation I, II or III, each generation step develops more specificity, selectivity and deeper tissue application. This review will discuss photosensitizer development consecutively, with its benefit and lackness. The light used is usually on red region, while the oxygen is involved in reactive oxygen species generation. Its mechanism action can go through either in type I or type II reaction. This kind of therapy is usually being used in oncology, especially in superficial and in-lining cancers, dermatology and ophthalmology field. This therapy can be safely given to patients with complication and has distinct advantages compare with other treatment such as chemotherapy and surgery. It also considerably has lesser side effects and risks. Broader application is being developed through various experiments and photosensitizer modification.

KINETICS OF PALM OIL TRANSESTERIFICATION IN METHANOL WITH POTASSIUM HYDROXIDE AS A CATALYST Yoeswono Yoeswono; Triyono Triyono; Iqmal Tahir
Indonesian Journal of Chemistry Vol 8, No 2 (2008)
Publisher : Universitas Gadjah Mada

A study on palm oil transesterification to evaluate the effect of some parameters in the reaction on the reaction kinetics has been carried out. Transesterification was started by preparing potassium methoxide from potassium hydroxide and methanol and then mixed it with the palm oil. An aliquot was taken at certain time interval during transesterification and poured into test tube filled with distilled water to stop the reaction immediately. The oil phase that separated from the glycerol phase by centrifugation was analyzed by 1H-NMR spectrometer to determine the percentage of methyl ester conversion. Temperature and catalyst concentration were varied in order to determine the reaction rate constants, activation energies, pre-exponential factors, and effective collisions. The results showed that palm oil transesterification in methanol with 0.5 and 1 % w/w KOH/palm oil catalyst concentration appeared to follow pseudo-first order reaction. The rate constants increase with temperature. After 13 min of reaction, More methyl esters were formed using KOH 1 % than using 0.5 % w/w KOH/palm oil catalyst concentration. The activation energy (Ea) and pre-exponential factor (A) for reaction using 1 % w/w KOH was lower than those using 0.5 % w/w KOH.

COMPARISON TEST OF FNAA AND AAS METHOD FOR Cu, Cd, Cr, AND Pb ANALYSIS OF CODE RIVER SEDIMENT (INDONESIA) Sunardi Sunardi; C. Supriyanto
Indonesian Journal of Chemistry Vol 8, No 2 (2008)
Publisher : Universitas Gadjah Mada

Comparison test of Fast Neutron Activation Analysis (FNAA) and Atomic Absorption Spectrometry (AAS) method for analysis of Cu, Cd, Cr, Pb elements in Code river sediment samples has been done. Comparisons of test used Standard Reference materials (SRM) sample, covering the validation test, t test and F test for both method and then these methods were used to analyze the Code river sediment samples. Comparisons test result show that the validity of both method are around 92.69 % to 98.12 % and t test show that there is no significant difference in average concentration, F test of both methods show that there is no difference in accuracy. The analysis result of Code sediment using FNAA for Cu, Cd, Cr, Pb are (15.41 - 53.92) ppm, (1.82 - 3.66) ppm, (14.72 - 87.28) ppm, (18.23 - 109.31) ppm respectively, while those using AAS method are (13.71 - 51.11) ppm, (1.64 - 3.33) ppm, (12.81 - 86.75) ppm, (15.74 - 105.53) ppm, respectively. Statistic result test using ANOVA method showed that the concentration of Cr are not significantly differences within sampling locations, while those for Cd, Cr, Pb show a significant difference within sampling location

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