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All Journal Reaktor Jurnal Sains dan Teknologi Reaksi Jurnal Vokasi Jurnal Teknologi Jurnal Riset, Inovasi, Teknologi & Terapan
Cut Aja Rahmawati
Jurusan Teknik Kimia Politeknik Negeri Lhokseumawe
Chemical Engineering, Chemistry & Bioengineering Chemistry Civil Engineering, Building, Construction & Architecture Computer Science & IT Control & Systems Engineering Economics, Econometrics & Finance Education Electrical & Electronics Engineering Energy Engineering Industrial & Manufacturing Engineering Materials Science & Nanotechnology Mechanical Engineering Social Sciences

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Journal : Reaktor

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Catalytic cracking of pyrolytic oil derived from arabica coffee parchment using Ni-NZ catalysts Nisa, Syarifah Rahimatun; Setiawan, Adi; Syam, Azhari Muhammad; Rahmawati, Cut Aja; Rizkina, Shafira
Reaktor Volume 25 No.1 April 2025
Publisher : Department of Chemical Engineering, Faculty of Engineering, Universitas Diponegoro

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.14710/reaktor.25.1.%p

Abstract

The potential of bio-oil derived from biomass has garnered significant attention among researchers due to its prospects as an environmentally friendly fuel alternative. This study utilized bio-oil extracted from Arabica coffee parchment sourced from coffee plantations in Bener Meriah Regency, Aceh, Indonesia. Nickel metal was used as a catalyst impregnated into natural zeolites to accelerate the reaction rate in the catalytic cracking method. The catalyst was prepared using the wet impregnation method, with natural zeolites first activated using 1 N HCl. During the impregnation process, stirring was conducted for 6 hours at 25 °C, followed by drying in an oven at 115 °C for 12 hours, and calcination at 500°C for 4 hours. The resulting catalyst was then characterized using TGA, XRD, and SEM analyses to determine the optimal catalyst properties. Based on XRD analysis across various concentrations, curves were observed at angles 2θ ≈ 37° and 44°, which are presumed to be peaks of nickel catalysts on the zeolite surface. In this study, the Ni-NZ catalyst concentration was varied to 15%, 20%, and 25% (w/w). GC-MS chromatogram results indicated that the highest formation of bio-benzene occurred at a 25% catalyst concentration with a residence time of 2 hours, yielding 9.28%. The findings suggest that Ni-NZ catalysts are technically capable of producing aromatic hydrocarbons from the pyrolytic oil of coffee parchment, which can be utilized as a biofuel component
Co-Authors Adi Setiawan Ambia, Warisul Azzahra, Nyak Dewi, Ratni Elfiana, E. Faridah Faridah Halim Zaini, Halim Haziri, Ahmad Abrar Mubarak, Salman Nisa, Syarifah Rahimatun Nurdin, Irwan Pardi, P. Ridwan, Ridwan Rizkina, Shafira Saifuddin Saifuddin Salmiyah Salmiyah Salmyah, S Sami, Muhammad Syam, Azhari Muhammad TA, Cut Fatmawati Usman Usman Yuniati Yuniati