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PENGARUH JUMLAH KATALIS DAN TEMPERATUR PADA PROSES PEMBUATAN BAHAN BAKAR CAIR LIMBAH STYROFOAM DENGAN METODE CATALYTIC CRACKING ., Zurohaina; Zikri, Ahmad; Febriana, Ida; Amin, Jaksen M.; Pratiwi, Anggun; Pratiwi, Mitha; Reyhan, Muhammad Hifal
KINETIKA Vol. 11 No. 1 (2020): KINETIKA 01032020
Publisher : Politeknik Negeri Sriwijaya

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Abstract

Styrofoam is a thermoplastic polymer that cannot be biodegradable. Styrofoam waste is generally treated using burning method which produce a dangerous gases. Cracking is the right method to solve the problem by converting styrofoam waste into liquid fuel. In this study, the cracking process was carried out by catalytic cracking method using zeolit alam, SiO2.Al2O3 dan Ï’-Al2O3 as a catalyst. The aims of this study are to determine the effect of the number of catalyst and temperature variation on the percentage of yield, physical properties and compound content of liquid fuel. Variabels varied are the number of catalyst 5-25% from total reactants and temperatur variation 300-550 oC. The result shows, the highest %yield using zeolit alam is 77,7846% at 20% catalyst, for silica alumina with variations of temperature showed the highest % yield in the temperature 450oC is 79,09% and for Ï’-Al2O3 with variations of temperature showed the highest % yield in the temperature 500oC is 68,20%
PENGARUH VARIASI SUHU, RASIO MOL REAKTAN DAN PERSEN KATALIS TERHADAP METIL ESTER SULFONAT MENGGUNAKAN REAKTOR SULFONASI Amin, Jaksen M.; Manggala, Agus; Ningsih, Aisyah Suci; Hilmasari, Jenni; Aliza, Sintiya Nur; Al Kusari, Willy
KINETIKA Vol. 11 No. 1 (2020): KINETIKA 01032020
Publisher : Politeknik Negeri Sriwijaya

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Abstract

Surfactants are generally produced from petroleum and natural gas derivatives while petroleum reserves are depleting and cannot be renewed. This has the potential to cause an energy crisis on a global scale in the future. To solve this problem, alternative renewable raw materials are needed that can help make surfactants that are environmentally friendly, namely raw materials sourced from vegetable oil. One of the anionic surfactants that can be made from plant materials and is renewable is Methyl ester sulfonate. The purpose of this study was to determine the effect of the mole ratio, temperature and percent of the catalyst and the duration of the sulfonation reaction using NaHSO3 reactants on the resulting MES. The production process of the MES surfactant is carried out by reacting the methyl ester with the sulfonation reagent in the form of NaHSO3 and CaO catalyst in the sulfonation reactor. The results showed that MES had the best characteristics with an optimum state in the ratio of 1: 1.5 mole ratio with 1% CaO catalyst and a temperature of
UNJUK KERJA PROSES PIROLISIS KATALITIK LIMBAH BAN BEKAS MENJADI BAHAN BAKAR CAIR DITINJAU DARI JUMLAH KATALIS, VARIASI TEMPERATUR, DAN WAKTU OPERASI Effendy, Sahrul; Rusnadi, Irawan; ., Fatria; Amin, Jaksen M.; Aina, Nur; Rossa, Briliantina; Waltin, Muhammad
KINETIKA Vol. 12 No. 1 (2021): KINETIKA 01032021
Publisher : Politeknik Negeri Sriwijaya

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Abstract

Indonesia's domestic rubber consumption is largely absorbed by the manufacturing industry, especially the automotive industry. The more production of vehicle, the more people will produce tires. As a result, the waste of tires in the environment is increasing. One of the alternatives to reduce the amount of tires waste is produce it become liquid fuel by catalytic pyrolysis method. The purpose of this research is to analyze percent yield liquid product and to obtain characteristics of liquid fuel observed by the number of catalyst, variation of temperature, and operation time. The result shown that the optimum temperature is 400oC using 10% NZ catalyst with product yield of 13.0284%. The optimum NZ catalyst is 2% at 300oC with product yield of 5.7946%. Also the optimum time operation is 180 minutes using 10% NZ catalyst with product yield of 9.7965%. The liquid fuel oil spesifications obtain diesel oil by testing density, viscosity, and flash point. The liquid fuel also analyzed by the GC-MS method, and it can be concluded that the liquid fuel of tires waste is mixture of gasoline (C8-C12) and diesel (C13-C20).