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Application of KBaYSi2O7:Bi3+,Eu3+ Phosphor for White Light-Emitting Diodes with Excellent Color Quality Loan, Nguyen Thi Phuong; Thuy, Le Xuan; Thai, Nguyen Le; Lee, Hsiao Yi; Cong, Pham Hong
Science and Technology Indonesia Vol. 9 No. 3 (2024): July
Publisher : Research Center of Inorganic Materials and Coordination Complexes, FMIPA Universitas Sriwijaya

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.26554/sti.2024.9.3.756-765

Abstract

This paper examines the properties of two phosphor materials synthesized via utilizing the sol gel method: KBaYSi2O7:Bi3+ (KBYS:Bi) phosphor providing cyan/deep-blue emission and KBaYSi2O7:Bi3+,Eu3+ (KBYS:Bi,Eu) phosphor exhibiting tunable emission from near-UV to red. The optimal doping concentrations for Bi3+ and Eu3+ are 0.2% and 3.5%, respectively. It is found that the ability to give discrepant emission peaks under different excitation sources of the KBYS:Bi phosphor is attributed to the occupancy of Bi3+ in different cation hosts. Meanwhile, co doping the Eu3+ and Bi3+ into the KBYS host leads to red and cyan emission regions, enabling the emission tunability of the KBYS:Bi,Eu phosphor. KBYS:Bi,Eu phosphor was then used in combination with YAG:Ce3+ and blue chips to fabricate a white light emitting diode (LED) model. The particle sizes of KBYS:Bi,Eu phosphor are adjusted to examine its influences on the LED properties. With increasing particle sizes (≥12 µm), the KBYS:Bi,Eu phosphor can improve the scatter efficacy, transmission power, lumen output, and color performance (rendition and uniformity). Both KBYS:Bi and KBYS:Bi,Eu phosphors are promising luminescent phosphors that can be combined with other phosphor with different emission colors to obtain the full-spectrum or tunable white light for LEDs.
The impacts of optical display BaF2-Ce materials on solid-state lighting Quan, Luu Hong; Loan, Nguyen Thi Phuong
International Journal of Reconfigurable and Embedded Systems (IJRES) Vol 14, No 3: November 2025
Publisher : Institute of Advanced Engineering and Science

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.11591/ijres.v14.i3.pp717-724

Abstract

Transparent ceramic doped with barium fluorid cerium (BaF2-Ce) was created via a sintering method and its brightness and scintillation characteristics were examined. The luminescence is associated with the 5d-4f transitions in the Ce3+ ion and exhibits emitting maxima at 310 and 323 nm. For Na-22 radioisotopes, photo-maximum at 511 keV and 1274 keV were achieved using translucent ceramic BaF2-Ce. The translucent ceramic BaF2-Ce has been determined to have a power resolution of 13.5% at 662 keV. A luminescent production rate was measured for the BaF2-Ce (0.2%) ceramic, which is similar to sole crystal. Calculations of the scintillation degradation period beneath 662 keV gamma stimulation reveal a quick part of 58 ns and a somewhat sluggish part of 434 ns. The more gradual part in BaF2-Ce(0.2%) ceramic is linked to the dipole-dipole power transmission from the host structure to the Ce3+ luminous core and is quicker comparing to self-trapped excitons (STE) emitting in BaF2 host. BaF2-Ce offer various qualities, including significant illumination output, rapid degradation duration, and rapid scintillating reaction, which are desirable for many global fields such as medicine, radiation detection, industrial systems and nuclear safety.