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All Journal International Journal of Reconfigurable and Embedded Systems (IJRES) International Journal of Advances in Applied Sciences Science and Technology Indonesia
Loan, Nguyen Thi Phuong
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Biochemistry, Genetics & Molecular Biology Chemical Engineering, Chemistry & Bioengineering Earth & Planetary Sciences Economics, Econometrics & Finance Environmental Science Materials Science & Nanotechnology Mathematics Physics

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Application of KBaYSi2O7:Bi3+,Eu3+ Phosphor for White Light-Emitting Diodes with Excellent Color Quality Loan, Nguyen Thi Phuong; Thuy, Le Xuan; Thai, Nguyen Le; Lee, Hsiao Yi; Cong, Pham Hong
Science and Technology Indonesia Vol. 9 No. 3 (2024): July
Publisher : Research Center of Inorganic Materials and Coordination Complexes, FMIPA Universitas Sriwijaya

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.26554/sti.2024.9.3.756-765

Abstract

This paper examines the properties of two phosphor materials synthesized via utilizing the sol gel method: KBaYSi2O7:Bi3+ (KBYS:Bi) phosphor providing cyan/deep-blue emission and KBaYSi2O7:Bi3+,Eu3+ (KBYS:Bi,Eu) phosphor exhibiting tunable emission from near-UV to red. The optimal doping concentrations for Bi3+ and Eu3+ are 0.2% and 3.5%, respectively. It is found that the ability to give discrepant emission peaks under different excitation sources of the KBYS:Bi phosphor is attributed to the occupancy of Bi3+ in different cation hosts. Meanwhile, co doping the Eu3+ and Bi3+ into the KBYS host leads to red and cyan emission regions, enabling the emission tunability of the KBYS:Bi,Eu phosphor. KBYS:Bi,Eu phosphor was then used in combination with YAG:Ce3+ and blue chips to fabricate a white light emitting diode (LED) model. The particle sizes of KBYS:Bi,Eu phosphor are adjusted to examine its influences on the LED properties. With increasing particle sizes (≥12 µm), the KBYS:Bi,Eu phosphor can improve the scatter efficacy, transmission power, lumen output, and color performance (rendition and uniformity). Both KBYS:Bi and KBYS:Bi,Eu phosphors are promising luminescent phosphors that can be combined with other phosphor with different emission colors to obtain the full-spectrum or tunable white light for LEDs.
The impacts of optical display BaF2-Ce materials on solid-state lighting Quan, Luu Hong; Loan, Nguyen Thi Phuong
International Journal of Reconfigurable and Embedded Systems (IJRES) Vol 14, No 3: November 2025
Publisher : Institute of Advanced Engineering and Science

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.11591/ijres.v14.i3.pp717-724

Abstract

Transparent ceramic doped with barium fluorid cerium (BaF2-Ce) was created via a sintering method and its brightness and scintillation characteristics were examined. The luminescence is associated with the 5d-4f transitions in the Ce3+ ion and exhibits emitting maxima at 310 and 323 nm. For Na-22 radioisotopes, photo-maximum at 511 keV and 1274 keV were achieved using translucent ceramic BaF2-Ce. The translucent ceramic BaF2-Ce has been determined to have a power resolution of 13.5% at 662 keV. A luminescent production rate was measured for the BaF2-Ce (0.2%) ceramic, which is similar to sole crystal. Calculations of the scintillation degradation period beneath 662 keV gamma stimulation reveal a quick part of 58 ns and a somewhat sluggish part of 434 ns. The more gradual part in BaF2-Ce(0.2%) ceramic is linked to the dipole-dipole power transmission from the host structure to the Ce3+ luminous core and is quicker comparing to self-trapped excitons (STE) emitting in BaF2 host. BaF2-Ce offer various qualities, including significant illumination output, rapid degradation duration, and rapid scintillating reaction, which are desirable for many global fields such as medicine, radiation detection, industrial systems and nuclear safety.
Computer simulation and software engineering in optical analysis of phosphor-converted white light-emitting diodes utilizing barium sulfate Trang, Le Thi; Loan, Nguyen Thi Phuong; Cong, Pham Hong; Anh, Nguyen Doan Quoc; Lee, Hsiao-Yi
International Journal of Advances in Applied Sciences Vol 14, No 4: December 2025
Publisher : Institute of Advanced Engineering and Science

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.11591/ijaas.v14.i4.pp1384-1392

Abstract

Achieving uniform nanoparticle dispersion in electrospun polymer nanofibers remains a critical challenge, as conventional electrospinning often leads to particle agglomeration and nozzle clogging, reducing fiber uniformity and functional efficiency. This study explicitly addresses this problem by developing poly (vinyl alcohol) (PVA)/BaSO4 composite nanofibers through both conventional and ultrasonic-assisted electrospinning. Scanning electron microscopy (SEM) revealed that ultrasonication effectively disrupted nanoparticle agglomerates, yielding smoother and more uniform fiber morphologies. X-ray diffraction (XRD) analysis further confirmed that ultrasonic processing reduced the crystalline intensity of PVA and BaSO4, indicating enhanced polymer–filler interaction and finer BaSO4 distribution. Quantitatively, the agglomeration slope decreased from 0.039 (conventional) to 0.006, and the mean crystallite size was reduced from approximately 470 to 300 nm. These results are consistent with recent advances showing that ultrasonic electrospinning improves nanoparticle dispersion and stability in polymer matrices, thereby enhancing optical and mechanical properties. Ultimately, this work demonstrates that ultrasonic-assisted electrospinning provides a robust and scalable strategy to fabricate lightweight, flexible, and multifunctional PVA-based radiation shielding materials with superior nanoparticle dispersion and structural homogeneity.
Influence of potassium bromide phosphor on optical properties of white light-emitting diodes Cong, Pham Hong; Loan, Nguyen Thi Phuong; Anh, Nguyen Doan Quoc; Lee, Hsiao-Yi
International Journal of Advances in Applied Sciences Vol 14, No 4: December 2025
Publisher : Institute of Advanced Engineering and Science

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.11591/ijaas.v14.i4.pp1359-1366

Abstract

Conventional phosphor-converted light-emitting diodes (LEDs) using silicone binders often suffer from yellowing, moisture degradation, and limited spectral tunability, restricting their performance in high-power street lighting. To overcome these limitations, this study aims to develop an advanced LED illumination system integrating a KBr-doped sol-gel/silica phosphor with total internal reflection (TIR) lenses and a reflective housing, encapsulated by an atomic layer deposition (ALD)-coated minilens panel. The sol-gel matrix, synthesized from MTEOS, TEOS, and silica granules, was engineered to achieve uniform KBr particle dispersion, reduced thermal quenching, and improved chromatic stability. The ALD laminate provides an additional moisture and heat barrier, sealing micro-defects and minimizing stress-induced cracking. Optical performance was quantitatively assessed using Monte Carlo beam-tracking simulations under various street configurations, including focal, zigzag, and single-plane pole layouts. Results demonstrated enhanced luminous efficacy, precise glare control, and high uniformity in street illumination. Overall, this integrated sol-gel/ALD LED design effectively addresses the durability and color instability problems of traditional silicone systems, offering a scalable and energy efficient solution for next-generation street lighting.
Thermally stable sol-gel yttrium aluminum garnet cerium phosphors for white light-emitting diodes Le, Phan Xuan; Loan, Nguyen Thi Phuong; Anh, Nguyen Doan Quoc; Lee, Hsiao-Yi
International Journal of Advances in Applied Sciences Vol 14, No 4: December 2025
Publisher : Institute of Advanced Engineering and Science

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.11591/ijaas.v14.i4.pp1367-1374

Abstract

This study aims to develop structurally controlled TiO2-based materials that serve a dual purpose as high-performance photocatalysts and optical scattering agents for white light-emitting diodes (LEDs). Hollow spherical TiO2, TiO2/Ag, and TiO2/Au particles were synthesized via a one-step spray thermolysis process using aqueous titanium citrate and titanium oxalate precursors. The method enables precise control of morphology and crystalline phase composition, producing hollow microspheres with tunable anatase–rutile ratios (10–100%) and crystallite sizes ranging from 12 to 120 nm. Photocatalytic performance, evaluated through the ultraviolet (UV) driven oxidation of methylene blue, showed that as-prepared TiO2 exhibited comparable activity to Degussa P25, while metal doping accelerated the anatase-to-rutile transition with minimal plasmonic enhancement under UV light. For LED applications, incorporating hollow TiO2 particles into YAG:Ce phosphor films improved luminous intensity, reaching a peak of ∼71 lm at 1 wt.% TiO2, and enhanced color uniformity, achieving a D-CCT as low as ∼60 K at 5 wt.%. These results confirm that spray thermolysis provides a scalable route to tailor morphology and phase composition, enabling multifunctional TiO2 materials optimized for both environmental photocatalysis and high-quality LED lighting.
Optical Assessment of Titanium Oxide Employed in Phosphor-Transmuted WLED Devices Le, Phan Xuan; Loan, Nguyen Thi Phuong; Anh, Nguyen Doan Quoc
Science and Technology Indonesia Vol. 11 No. 1 (2026): January
Publisher : Research Center of Inorganic Materials and Coordination Complexes, FMIPA Universitas Sriwijaya

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.26554/sti.2026.11.1.345-355

Abstract

Utilizing inexpensive PbO-B2O3-SiO2-ZnO glass as the host, a new environmentally friendly method for phosphor-transformed WLED utilizing Ce:YAG-doped glass and Titanium oxide (TiO2) was effectively created for this study. This method demonstrated good sintering behavior and elevated visible transparency with a sintering heat level reaching 750oC while avoiding influence on phosphor samples. The optic characterization of WLED can be simply adjusted by only modifying the temperature, incorporating dosage, as well as sample breadth to suit the mucous sintering for phosphor within glass (PwG). The perfect sample amount is regulated, reaching 5 wt.% of the end combination, and the most suited thickness of samples is discovered to be 0.8 mm. As a consequence, the optimum heating condition is sintered at 700oC within 40 minutes. The built-in PwG WLED displays an elevated illuminating effectiveness of 134.33 lm/W, associated hue temperature of 4696 K, and hue rendering index of 68.5. PwG’s improved heat quenching ability when combined with traditional silicone resin and TiO2 makes it clear that the glass ceramic substance used today is highly practical for use in WLED apparatuses.
Enhancing Scattering Strength Improvement and Color Uniformity in White Light-Emitting Diodes Using High Concentration of Yttrium Oxide Cong, Pham Hong; Loan, Nguyen Thi Phuong; Tung, Ha Thanh
Science and Technology Indonesia Vol. 11 No. 1 (2026): January
Publisher : Research Center of Inorganic Materials and Coordination Complexes, FMIPA Universitas Sriwijaya

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.26554/sti.2026.11.1.174-181

Abstract

This study investigates the effect of yttrium oxide (Y2O3) doping on the phase evolution of barium titanate (BaTiO3), a key dielectric material used in multilayer ceramic capacitors (MSCCs). Two types of starting powders were examined: pure BaTiO3 and a commercial X7R composition containing 1 wt% Y2O3. Using the solid-state method under high temperature, Y2O3 was added in varying amounts, and the powders were processed under controlled sintering conditions to evaluate its influence on phase formation. The resulting ceramics were characterized to determine formational alterations as well as the potential generation of secondary phases. Increasing Y2O3 content led to a transmutation from the tetragon structure to a merger between tetragon as well as cubic phases. The commercial X7R powder exhibited greater densificating process, surpassing pure BaTiO3 and formed a cuboid formation under greater Y2O3 concentrations. Notably, the sample doped with 20 wt% Y2O3 produced the Ba6Ti17O40 phase, augmenting scattering capacity and color uniformity. These findings clarify the role of Y2O3 in phase evolution and highlight its implications for optimizing BaTiO3-based MSCC materials.
Co-Authors Anh, Nguyen Doan Quoc Cong, Pham Hong Le, Phan Xuan Lee, Hsiao Yi Lee, Hsiao-Yi Quan, Luu Hong Thai, Nguyen Le Thuy, Le Xuan Trang, Le Thi Tung, Ha Thanh