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Journal : Science and Technology Indonesia

Application of KBaYSi2O7:Bi3+,Eu3+ Phosphor for White Light-Emitting Diodes with Excellent Color Quality Loan, Nguyen Thi Phuong; Thuy, Le Xuan; Thai, Nguyen Le; Lee, Hsiao Yi; Cong, Pham Hong
Science and Technology Indonesia Vol. 9 No. 3 (2024): July
Publisher : Research Center of Inorganic Materials and Coordination Complexes, FMIPA Universitas Sriwijaya

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.26554/sti.2024.9.3.756-765

Abstract

This paper examines the properties of two phosphor materials synthesized via utilizing the sol gel method: KBaYSi2O7:Bi3+ (KBYS:Bi) phosphor providing cyan/deep-blue emission and KBaYSi2O7:Bi3+,Eu3+ (KBYS:Bi,Eu) phosphor exhibiting tunable emission from near-UV to red. The optimal doping concentrations for Bi3+ and Eu3+ are 0.2% and 3.5%, respectively. It is found that the ability to give discrepant emission peaks under different excitation sources of the KBYS:Bi phosphor is attributed to the occupancy of Bi3+ in different cation hosts. Meanwhile, co doping the Eu3+ and Bi3+ into the KBYS host leads to red and cyan emission regions, enabling the emission tunability of the KBYS:Bi,Eu phosphor. KBYS:Bi,Eu phosphor was then used in combination with YAG:Ce3+ and blue chips to fabricate a white light emitting diode (LED) model. The particle sizes of KBYS:Bi,Eu phosphor are adjusted to examine its influences on the LED properties. With increasing particle sizes (≥12 µm), the KBYS:Bi,Eu phosphor can improve the scatter efficacy, transmission power, lumen output, and color performance (rendition and uniformity). Both KBYS:Bi and KBYS:Bi,Eu phosphors are promising luminescent phosphors that can be combined with other phosphor with different emission colors to obtain the full-spectrum or tunable white light for LEDs.
Optical Assessment of Titanium Oxide Employed in Phosphor-Transmuted WLED Devices Le, Phan Xuan; Loan, Nguyen Thi Phuong; Anh, Nguyen Doan Quoc
Science and Technology Indonesia Vol. 11 No. 1 (2026): January
Publisher : Research Center of Inorganic Materials and Coordination Complexes, FMIPA Universitas Sriwijaya

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.26554/sti.2026.11.1.345-355

Abstract

Utilizing inexpensive PbO-B2O3-SiO2-ZnO glass as the host, a new environmentally friendly method for phosphor-transformed WLED utilizing Ce:YAG-doped glass and Titanium oxide (TiO2) was effectively created for this study. This method demonstrated good sintering behavior and elevated visible transparency with a sintering heat level reaching 750oC while avoiding influence on phosphor samples. The optic characterization of WLED can be simply adjusted by only modifying the temperature, incorporating dosage, as well as sample breadth to suit the mucous sintering for phosphor within glass (PwG). The perfect sample amount is regulated, reaching 5 wt.% of the end combination, and the most suited thickness of samples is discovered to be 0.8 mm. As a consequence, the optimum heating condition is sintered at 700oC within 40 minutes. The built-in PwG WLED displays an elevated illuminating effectiveness of 134.33 lm/W, associated hue temperature of 4696 K, and hue rendering index of 68.5. PwG’s improved heat quenching ability when combined with traditional silicone resin and TiO2 makes it clear that the glass ceramic substance used today is highly practical for use in WLED apparatuses.
Enhancing Scattering Strength Improvement and Color Uniformity in White Light-Emitting Diodes Using High Concentration of Yttrium Oxide Cong, Pham Hong; Loan, Nguyen Thi Phuong; Tung, Ha Thanh
Science and Technology Indonesia Vol. 11 No. 1 (2026): January
Publisher : Research Center of Inorganic Materials and Coordination Complexes, FMIPA Universitas Sriwijaya

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.26554/sti.2026.11.1.174-181

Abstract

This study investigates the effect of yttrium oxide (Y2O3) doping on the phase evolution of barium titanate (BaTiO3), a key dielectric material used in multilayer ceramic capacitors (MSCCs). Two types of starting powders were examined: pure BaTiO3 and a commercial X7R composition containing 1 wt% Y2O3. Using the solid-state method under high temperature, Y2O3 was added in varying amounts, and the powders were processed under controlled sintering conditions to evaluate its influence on phase formation. The resulting ceramics were characterized to determine formational alterations as well as the potential generation of secondary phases. Increasing Y2O3 content led to a transmutation from the tetragon structure to a merger between tetragon as well as cubic phases. The commercial X7R powder exhibited greater densificating process, surpassing pure BaTiO3 and formed a cuboid formation under greater Y2O3 concentrations. Notably, the sample doped with 20 wt% Y2O3 produced the Ba6Ti17O40 phase, augmenting scattering capacity and color uniformity. These findings clarify the role of Y2O3 in phase evolution and highlight its implications for optimizing BaTiO3-based MSCC materials.