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Effect of glyphosate contamination on surface charge change and nutrients of degraded Inceptisols ameliorated with sub-bituminous coal Herviyanti, Herviyanti; Maulana, Amsar; Harianti, Mimien; Lita, Arestha Leo; Prasetyo, Teguh Budi; Juwita, Pitri; Kurnianto, Reza Tri; Yasin, Syafrimen
Journal of Degraded and Mining Lands Management Vol. 11 No. 2 (2024)
Publisher : Brawijaya University

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.15243/jdmlm.2024.112.5135

The widespread use of glyphosate to eradicate weeds in agricultural areas has the potential for contamination and residues in the soil that must be carefully considered. This study aimed to elucidate the effect of glyphosate contamination on the chemical properties of an Inceptisol ameliorated with sub-bituminous coal. This study used a completely randomized design with three treatments and three replications, namely A = control (soil with no glyphosate and sub-bituminous coal), B = 5 kg soil + 100 mg glyphosate L-1, and C = 5 kg soil + 40 t sub-bituminous coal ha-1 + 100 mg glyphosate L-1. The results showed that glyphosate contamination significantly affected pH, electrical conductivity (EC), mineral and organic matter (OM) composition, cation exchange capacity (CEC), organic carbon (OC), total N, and available P of an Inceptisol ameliorated with sub-bituminous coal. The application of 40 t sub-bituminous coal ha-1 as an alternative ameliorant improved pH H2O by 0.30, EC by 0.05 dS m-1, OM by 1.03%, CEC by 18.08 cmol(+) kg-1, OC by 1.16%, total N by 0.20% and available P by 5.47 ppm of the soil compared to the control. The residual glyphosate concentration in the soil ameliorated with sub-bituminous coal was 0.04 mg kg-1 compared to the initial glyphosate concentration of 100 mg L-1. The correlation between glyphosate residue had no significant relationship with the chemical properties of an Inceptisol ameliorated with sub-bituminous coal.

Equilibrium study for mercury removal using sub-bituminous coal and its application on ex-gold mining soil contaminated with mercury Maulana, Amsar; Harianti, Mimien; Prasetyo , Teguh Budi; Herviyanti, Herviyanti
Journal of Degraded and Mining Lands Management Vol. 11 No. 3 (2024)
Publisher : Brawijaya University

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.15243/jdmlm.2024.113.5551

Optimizing the potential utilization of low-rank coal, such as sub-bituminous coal (SC), can improve and maintain soil quality and productivity through amelioration technology. This potential is especially in controlling heavy metals such as Hg. This study aimed to examine the geochemistry of SC and the adsorption mechanism of Hg with SC through an adsorption isotherm model approach developed for experimental equilibrium. The geochemical of SC has an atomic composition of C (43.60%), O (40.64%), N (11.96%), Si (1.57%), Al (1.06%), Ca (0.92%), Mg (0.14%) and K (0.11%) and oxide composition dominated by SiO2 (57.07%), as well as O-H and N-H functional groups, C-H C-H, C=C-H, C=O, and C=C-H and minerals (quartz, magnetite, mica and muscovite). Characteristics of SC have a proximate composition (16.99% moisture, 97.81% volatile matter, 69.63% ash, and 28.19% fixed carbon) and chemical properties of pH, EC, CEC, OC, and total N (5.23, 1.38 dS m-1, 35.33 cmol(+) kg-1, 9.81% C, and 0.16% N). The adsorption capacity and coefficient of Hg2+ by SC were 304.32 mg g-1 and 78.67 L kg-1 at pH 1.26 and Hg2+ concentration 100 mg L-1 with a removal efficiency of 76.08%. Hg2+ adsorption isotherms occurred in Langmuir (RL = 0.97 and R² = 1)>Freundlich (1/n = 1.05 and R² = 0.9999) models. The application of 40 t SC ha-1 on ex-gold mining soil contaminated with Hg significantly decreased the total Hg in the soil by 2.50 mg kg-1 and a removal efficiency of 36.37% with increased pH H2O (0.35), OC (0.041% C), and CEC 2.14 cmol(+) kg-1, compared to control.

The implication of microplastic contamination on chemical properties of Inceptisols in the horticultural production center of Banuhampu, Agam, West Sumatra, Indonesia Herviyanti, Herviyanti; Tanjung, Ellsya Tatalia Augustin Putri; Rezki, Dewi; Maulana, Amsar; Darusman, Darusman; Darfis, Irwan; Purwanto, Benito Heru; Prasetyo, Teguh Budi
Journal of Degraded and Mining Lands Management Vol. 12 No. 1 (2024)
Publisher : Brawijaya University

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.15243/jdmlm.2024.121.6545

The accumulation of microplastics (MPs) in agricultural land may threaten food security and farmers' health, which is of interest. This study examined the implication of MPs contamination/pollution on the chemical properties of an Inceptisol on different slopes in the horticultural production center of Banuhampu Subdistrict, Agam District, West Sumatra Province. The soil samples were determined by purposive random sampling with a quantitative survey method. Sample testing was carried out using a randomized completely block design with five treatments, i.e., 25-45% in forests, and 0-8%, 8-15%, 15-25%, and 25-45% in fields at a depth of 0-20 cm. The Inceptisol contaminated with MPs has the following characteristics: pH = 5.01, EC = 0.09 dS m-1, Eh = 92.97 mV, mineral = 68.81%, OM = 31.19%, CEC = 60.67 cmol(+) kg-1, C = 2.13%, N = 0.81%, P2O5 = 6.46 ppm, K = 0.48, Ca = 1.59 cmol(+) kg-1, Mg = 0.62 cmol(+) kg-1 , and SO4 = 98.98 ppm. The concentration of MPs on the Inceptisol was 438.33 particles kg-1 with filament shape, transparent color, and large size (1-5 mm) were the most commonly found. Polymer types included polyamide 6, polystyrene, and polyethylene. The effect of slope level on the surface change charger of Inceptisols contaminated with MPs was insignificant. However, the effect was significant in OC, total N, K-exch, and available S. The implications of microplastic contamination/pollution did not have a significant relationship with the chemical properties of the soil. However, it has a negative relationship to redox potential (Eh), mineral composition, and Ca-exch.

Effect of Sub-Bituminous Coal on Negative Charge Activity on Secondary Forest and Horticultural Land Contaminated with Pesticides in Sungai Pua, Agam Herviyanti, Herviyanti; Maulana, Amsar; Prasetyo, Teguh Budi; Lita, Arestha Leo; Ryswaldi, Ridho
AGRIVITA Journal of Agricultural Science Vol 46, No 1 (2024)
Publisher : Faculty of Agriculture University of Brawijaya in collaboration with PERAGI

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.17503/agrivita.v46i1.3616

Pesticides are increasingly used to deal with crop-disrupting organisms. However, only 1% are on target, and the rest threaten agricultural ecology. This research aims to study the effect of Sub-bituminous coal (SC) on the change of negative charge activity (NCA) on two types of land, namely secondary forest (SF) and pesticide-contaminated horticultural land (HL-P). Two studies respectively used a completely randomized design (CRD) with three replications on two land types and five doses, namely: A = control or 0 t/ha [0 g SC/500 g soil]; B = 10 t/ha [2.5 g SC/500 g soil]; C = 20 t/ha [5.0 g SC/500 g soil]; D = 30 t/ha [7.5 g SC/500 g soil]; and E = 40 t/ha [10 g SC/500 g soil]. The results show that the effect of 40 t/ha SC can increase NCA on the surface of soil colloids (ΔpH) by 43% in SF and 23% in HL-P. The effect of 40 t/ha SC on the two types of land has a significant effect on increasing pH H2O, EC, CEC, and OM composition, respectively, by 0.70; 0.04 dS/m; 44.30 cmol(+)/kg and 7.60% in SF and 0.33; 0.01 dS/m; 26.89 cmol(+)/kg and 3.00% in HL-P, compared to the control.

Interaksi Merkuri dengan Nitrogen (Hg-N) Pada Tanah Bekas Tambang Emas MAULANA, AMSAR
Jurnal Ilmu Pertanian Indonesia Vol. 0 No. 00 (2025): inpress
Publisher : Institut Pertanian Bogor

Show Abstract | Download Original | Original Source | Check in Google Scholar

Kontaminasi merkuri (Hg) telah menjadi ancaman serius bagi ekosistem karena mengakibatkan perubahan fisiologis, biokimia, dan metabolisme tanaman. Dampaknya adalah perebutan ruang penyerapan tanaman antara Hg dan unsur hara (misalnya Nitrogen) di dalam tanah dan sistem tanaman. Tujuan dari penelitian ini adalah untuk menganalisis secara kuantitatif interaksi merkuri dan nitrogen (Hg-N) pada tanah bekas tambang emas di Dharmasraya. Penelitian ini menggunakan metode survei pada tingkat keragaman area pertambangan emas yang dimiliki oleh masing-masing daerah (area dan titik penambangan), pada kedalaman 0-20 cm dan 20-40 cm. Sehingga terdapat tiga (3) sampai lima (5) ulangan, dengan total sampel sebanyak lima puluh empat (54) sampel. Interaksi Hg-N secara kuantitatif tidak signifikan pada tingkat 0,01 (2-tailed), yaitu r = 0,167 atau Hg Total = 3,2164 (N Total) + 3,8849; R² = 0,0276. Namun demikian, interaksi ini dapat menjelaskan beberapa proses biogeokimia Hg dalam siklus N, dimana tanah bekas tambang emas di Dharmasraya memiliki tingkat kesuburan yang rendah, dengan pH 4,03 unit, KTK 7,15 cmol kg-1 , SOC 0,04% dan N Total 0,09% N, serta Hg Total yang sangat tinggi yaitu 4,18 mg kg-1. Korelasi positif antara Hg dan SOC (r = 0,417**) juga menjelaskan bahwa pelepasan N oleh dekomposisi serasah dan N-OM juga berkaitan dengan mineralisasi C, sehingga pelepasan Hg yang terserap dari N-OM, di mana terdapat korelasi positif antara SOC dan N (r = 0,645**).

Synergistic impact of pollution from microplastics and glyphosate herbicides on the biophysics of horticultural land with different soil orders in Baso, West Sumatra, Indonesia Darfis, Irwan; Maulana, Amsar; Harianti, Mimien; Rezki, Dewi; Herviyanti, Herviyanti
Journal of Degraded and Mining Lands Management Vol. 13 No. 2 (2026)
Publisher : Brawijaya University

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.15243/jdmlm.2026.132.9963

Increased use of plastic mulch and glyphosate herbicides may lead to synergistic effects on soil properties, particularly in horticultural land. This study examined the synergistic effects of microplastics and glyphosate herbicides on the biophysics of horticultural land across different soil orders in Baso, West Sumatra, Indonesia. Soil sampling followed a quantitative, random survey approach. Sampling testing was conducted using a 2 x 4 factorial randomized block design with three groups. The first factor comprised two different land uses (forest land as a control and horticultural land), and the second factor comprised four soil orders (Entisols, Inceptisols, Ultisols, and Oxisols) at a depth of 0-20 cm. The transition of horticultural land significantly interacted with differences in soil orders in Baso, affecting bulk density, porosity, the sand fraction, and soil enzymatic activity through synergistic effects of microplastic pollution and glyphosate herbicide residues. The main effect of differences in land use between forest and horticultural land was not significant on biophysical properties, but was significant on pollutants. However, the main effect of different soil orders was insignificant for biophysical properties but significant for pollutants, particularly microplastics. The synergistic impact of microplastic pollution was positively related to glyphosate (r = 0.608**; y = 0.0162x + 2.4476; R² = 0.3697), which has the potential to increase pollutant persistence.

Removal of glyphosate on Inceptisols ameliorated with biochar derived from young coconut waste Monikasari, Moli; Lita, Arestha Leo; Prasetyo, Teguh Budi; Maulana, Amsar; Hidayat, Endar; Herviyanti, Herviyanti
SAINS TANAH - Journal of Soil Science and Agroclimatology Vol 22, No 2 (2025): December
Publisher : Universitas Sebelas Maret

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.20961/stjssa.v22i2.93091

Young Coconut Waste Biochar (YCWB) serves as an ameliorative agent that enhances soil quality and facilitates glyphosate removal, particularly in Inceptisols. This study aimed to evaluate the capacity of Inceptisols enhanced with YCWB to eliminate glyphosate, a commonly used herbicide. Inceptisols amended with 40 t ha⁻¹ YCWB demonstrated an increased surface charge, improving soil properties such as acidity (pH), electrical conductivity (EC), cation exchange capacity (CEC), and soil organic matter (SOM). The adsorption capacity was determined to be 0.87 mg g⁻¹ (or 870.27 mg kg⁻¹) at pH 5.07, under a glyphosate concentration of 100 mg L⁻¹. Glyphosate removal was facilitated by changes in functional groups, as indicated by Fourier-transform infrared spectroscopy (FT-IR), which showed reduced transmittance of O-H, C=C, C-O, C-H, and mineral groups. These modifications indicate an enhancement in the sorption capacity of Inceptisols treated with 40 t ha⁻¹ YCWB. The glyphosate adsorption isotherms followed the sequence: Langmuir > Freundlich model, with performance ranking as soil + 40 t ha⁻¹ YCWB > unamended soil (Inceptisols). The respective R² values were R² = 0.9889 > R² = 0.9739 for the Langmuir model and R² = 0.9953 > R² = 0.9099 for the Freundlich model, confirming a strong interaction relationship (R² > 0.9). This indicates that glyphosate removal occurs through simultaneous or alternating physical and chemical processes. Modifying the surface charge of Inceptisols using biochar-based amelioration technology derived from biomass waste, such as young coconut waste, is critical for improving glyphosate removal efficiency.

Characteristics of inceptisol ameliorated with rice husk biochar to glyphosate adsorption Herviyanti, Herviyanti; Maulana, Amsar; Lita, Arestha Leo; Prasetyo, Teguh Budi; Monikasari, Moli; Ryswaldi, Ridho
SAINS TANAH - Journal of Soil Science and Agroclimatology Vol 19, No 2 (2022): December
Publisher : Universitas Sebelas Maret

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.20961/stjssa.v19i2.61614

As an ameliorant, rice husk biochar (RHB) can improve soil quality and long-term carbon absorption and interaction with glyphosate during adsorption. This study investigated the ability of Inceptisol ameliorated with RHB to absorb glyphosate. Inceptisol ameliorated with 40-t ha-1 RHB increased the soil surface charge (ΔpH) by improving soil pH H2O, electrical conductivity, cation exchange capacity, and soil organic matter. Linear and nonlinear models showed that fitting Langmuir and Freundlich isotherms is suitable for this study. The isotherm adsorption of glyphosate sequentially occurs in the Freundlich and Langmuir models (Inceptisol + 40-t ha-1 RHB > Inceptisol), where the Freundlich model (R2 = 0.938) is dominated by glyphosate adsorption on Inceptisol + 40-t ha-1 RHB with n of 0.46 and KF of 1.747 mg kg-1, whereas the Langmuir model (R2 = 0.8608) with Qm of 30.01 mg kg-1 and KL of 0.08 L mg-1 at a concentration level of 100 ppm and pH of the glyphosate solution 5.20 units. The glyphosate adsorption was also supported by changes in functional groups, where Fourier transform infrared spectroscopy shows a decrease in transmittance in the O-H; C=C; C-O; C-H, and mineral groups, indicating an increase in the adsorption capacity in Inceptisol ameliorated with 40-t ha-1 RHB. This study indicated that the physicochemical properties of Inceptisol are important in controlling the glyphosate adsorption ability of RHB in soils.

Biochar Quality During Slow Pyrolysis from Oil Palm Empty Fruit Bunches and Its Application as Soil Ameliorant Maulana, Amsar; Harianti, Mimien; Athiyya, Salma; Prasetyo, Teguh Budi; Monikasari, Moli; Darfis, Irwan; Rezki, Dewi; Herviyanti, Herviyanti
Caraka Tani: Journal of Sustainable Agriculture Vol 40, No 1 (2025): January
Publisher : Universitas Sebelas Maret

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.20961/carakatani.v40i1.93859

The optimal utilization of oil palm empty fruit bunch (OPEFB) waste holds significant potential for biomass bioconversion via slow pyrolysis, presenting a promising alternative for producing high-quality biochar as a soil ameliorant. This study investigates the effects of slow pyrolysis temperatures (≤ 300 °C) on the physicochemical properties of biochar derived from OPEFB and evaluates its efficacy as a soil ameliorant. This study utilized a completely randomized design (CRD) with three replications across two experiments. The first experiment assessed the effect of slow pyrolysis temperature on the quality of biochar derived from OPEFB, with treatments set at four temperatures (150, 200, 250, and 300 °C) levels. The second experiment evaluated the impact of the selected biochar on the surface charge of oil palm plantation soil, applying biochar at five different doses (0, 20, 40, 60, and 80 tons ha-¹). The potential temperature of 200 °C in slow pyrolysis had a significant effect on the quality of biochar from OPEFB with a yield ratio of 27.84% char; proximate (91.95% volatile matter and 0.81% fixed carbon), cation exchange capacity (CEC) [167.73 cmol(+) kg-1], and macro and micronutrients (e.g., C, N, P, K, Ca, Si, Fe, Cu, Zn, and Mn). The potential of O-H, N-H, C-H, and C=O functional groups of biochar from OPEFB for nutrient availability and absorption efficiency proven by the effect of 40 tons ha-1 biochar from OPEFB which significantly increased 80% of soil surface charge [pH by 0.80; organic matter (OM) composition by 19.8%, CEC by 11 cmol(+) kg-1] and nutrients [0.93% C; 0.04% N; 17.57 ppm P2O5; 0.65 cmol(+) kg-1 K] on Inceptisols.

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