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All Journal Journal of Degraded and Mining Lands Management AGRIVITA, Journal of Agricultural Science
Maulana, Amsar
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Agriculture, Biological Sciences & Forestry Biochemistry, Genetics & Molecular Biology

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Effect of glyphosate contamination on surface charge change and nutrients of degraded Inceptisols ameliorated with sub-bituminous coal Herviyanti, Herviyanti; Maulana, Amsar; Harianti, Mimien; Lita, Arestha Leo; Prasetyo, Teguh Budi; Juwita, Pitri; Kurnianto, Reza Tri; Yasin, Syafrimen
Journal of Degraded and Mining Lands Management Vol. 11 No. 2 (2024)
Publisher : Brawijaya University

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.15243/jdmlm.2024.112.5135

Abstract

The widespread use of glyphosate to eradicate weeds in agricultural areas has the potential for contamination and residues in the soil that must be carefully considered. This study aimed to elucidate the effect of glyphosate contamination on the chemical properties of an Inceptisol ameliorated with sub-bituminous coal. This study used a completely randomized design with three treatments and three replications, namely A = control (soil with no glyphosate and sub-bituminous coal), B = 5 kg soil + 100 mg glyphosate L-1, and C = 5 kg soil + 40 t sub-bituminous coal ha-1 + 100 mg glyphosate L-1. The results showed that glyphosate contamination significantly affected pH, electrical conductivity (EC), mineral and organic matter (OM) composition, cation exchange capacity (CEC), organic carbon (OC), total N, and available P of an Inceptisol ameliorated with sub-bituminous coal. The application of 40 t sub-bituminous coal ha-1 as an alternative ameliorant improved pH H2O by 0.30, EC by 0.05 dS m-1, OM by 1.03%, CEC by 18.08 cmol(+) kg-1,  OC by 1.16%,  total N by 0.20% and available P by 5.47 ppm of the soil compared to the control. The residual glyphosate concentration in the soil ameliorated with sub-bituminous coal was 0.04 mg kg-1 compared to the initial glyphosate concentration of 100 mg L-1. The correlation between glyphosate residue had no significant relationship with the chemical properties of an Inceptisol ameliorated with sub-bituminous coal.
Equilibrium study for mercury removal using sub-bituminous coal and its application on ex-gold mining soil contaminated with mercury Maulana, Amsar; Harianti, Mimien; Prasetyo , Teguh Budi; Herviyanti, Herviyanti
Journal of Degraded and Mining Lands Management Vol. 11 No. 3 (2024)
Publisher : Brawijaya University

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.15243/jdmlm.2024.113.5551

Abstract

Optimizing the potential utilization of low-rank coal, such as sub-bituminous coal (SC), can improve and maintain soil quality and productivity through amelioration technology. This potential is especially in controlling heavy metals such as Hg. This study aimed to examine the geochemistry of SC and the adsorption mechanism of Hg with SC through an adsorption isotherm model approach developed for experimental equilibrium. The geochemical of SC has an atomic composition of C (43.60%), O (40.64%), N (11.96%), Si (1.57%), Al (1.06%), Ca (0.92%), Mg (0.14%) and K (0.11%) and oxide composition dominated by SiO2 (57.07%), as well as O-H and N-H functional groups, C-H C-H, C=C-H, C=O, and C=C-H and minerals (quartz, magnetite, mica and muscovite). Characteristics of SC have a proximate composition (16.99% moisture, 97.81% volatile matter, 69.63% ash, and 28.19% fixed carbon) and chemical properties of pH, EC, CEC, OC, and total N (5.23, 1.38 dS m-1, 35.33 cmol(+) kg-1, 9.81% C,  and 0.16% N). The adsorption capacity and coefficient of Hg2+ by SC were 304.32 mg g-1 and 78.67 L kg-1 at pH 1.26 and Hg2+ concentration 100 mg L-1 with a removal efficiency of 76.08%. Hg2+ adsorption isotherms occurred in Langmuir (RL = 0.97 and R² = 1)>Freundlich (1/n = 1.05 and R² = 0.9999) models. The application of 40 t SC ha-1 on ex-gold mining soil contaminated with Hg significantly decreased the total Hg in the soil by 2.50 mg kg-1 and a removal efficiency of 36.37% with increased pH H2O (0.35), OC (0.041% C), and CEC 2.14 cmol(+) kg-1, compared to control.  
The implication of microplastic contamination on chemical properties of Inceptisols in the horticultural production center of Banuhampu, Agam, West Sumatra, Indonesia Herviyanti, Herviyanti; Tanjung, Ellsya Tatalia Augustin Putri; Rezki, Dewi; Maulana, Amsar; Darusman, Darusman; Darfis, Irwan; Purwanto, Benito Heru; Prasetyo, Teguh Budi
Journal of Degraded and Mining Lands Management Vol. 12 No. 1 (2024)
Publisher : Brawijaya University

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.15243/jdmlm.2024.121.6545

Abstract

The accumulation of microplastics (MPs) in agricultural land may threaten food security and farmers' health, which is of interest. This study examined the implication of MPs contamination/pollution on the chemical properties of an Inceptisol on different slopes in the horticultural production center of Banuhampu Subdistrict, Agam District, West Sumatra Province. The soil samples were determined by purposive random sampling with a quantitative survey method. Sample testing was carried out using a randomized completely block design with five treatments, i.e., 25-45% in forests, and 0-8%, 8-15%, 15-25%, and 25-45% in fields at a depth of 0-20 cm. The Inceptisol contaminated with MPs has the following characteristics: pH = 5.01, EC = 0.09 dS m-1, Eh = 92.97 mV, mineral = 68.81%, OM = 31.19%, CEC = 60.67 cmol(+) kg-1, C = 2.13%, N = 0.81%, P2O5 = 6.46 ppm, K = 0.48, Ca = 1.59 cmol(+) kg-1, Mg = 0.62 cmol(+) kg-1 , and SO4 = 98.98 ppm. The concentration of MPs on the Inceptisol was 438.33 particles kg-1 with filament shape, transparent color, and large size (1-5 mm) were the most commonly found. Polymer types included polyamide 6, polystyrene, and polyethylene. The effect of slope level on the surface change charger of Inceptisols contaminated with MPs was insignificant. However, the effect was significant in OC, total N, K-exch, and available S. The implications of microplastic contamination/pollution did not have a significant relationship with the chemical properties of the soil. However, it has a negative relationship to redox potential (Eh), mineral composition, and Ca-exch.
Effect of Sub-Bituminous Coal on Negative Charge Activity on Secondary Forest and Horticultural Land Contaminated with Pesticides in Sungai Pua, Agam Herviyanti, Herviyanti; Maulana, Amsar; Prasetyo, Teguh Budi; Lita, Arestha Leo; Ryswaldi, Ridho
AGRIVITA Journal of Agricultural Science Vol 46, No 1 (2024)
Publisher : Faculty of Agriculture University of Brawijaya in collaboration with PERAGI

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.17503/agrivita.v46i1.3616

Abstract

Pesticides are increasingly used to deal with crop-disrupting organisms. However, only 1% are on target, and the rest threaten agricultural ecology. This research aims to study the effect of Sub-bituminous coal (SC) on the change of negative charge activity (NCA) on two types of land, namely secondary forest (SF) and pesticide-contaminated horticultural land (HL-P). Two studies respectively used a completely randomized design (CRD) with three replications on two land types and five doses, namely: A = control or 0 t/ha [0 g SC/500 g soil]; B = 10 t/ha [2.5 g SC/500 g soil]; C = 20 t/ha [5.0 g SC/500 g soil]; D = 30 t/ha [7.5 g SC/500 g soil]; and E = 40 t/ha [10 g SC/500 g soil]. The results show that the effect of 40 t/ha SC can increase NCA on the surface of soil colloids (ΔpH) by 43% in SF and 23% in HL-P. The effect of 40 t/ha SC on the two types of land has a significant effect on increasing pH H2O, EC, CEC, and OM composition, respectively, by 0.70; 0.04 dS/m; 44.30 cmol(+)/kg and 7.60% in SF and 0.33; 0.01 dS/m; 26.89 cmol(+)/kg and 3.00% in HL-P, compared to the control.
Co-Authors Benito Heru Purwanto Darfis, Irwan Darusman Darusman Harianti, Mimien Herviyanti Herviyanti Juwita, Pitri Kurnianto, Reza Tri Lita, Arestha Leo Prasetyo , Teguh Budi Ryswaldi, Ridho Syafrimen Yasin Tanjung, Ellsya Tatalia Augustin Putri Teguh Budi Prasetyo