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All Journal Jurnal Kimia Mulawarman Abdimas Talenta : Jurnal Pengabdian Kepada Masyarakat JURNAL PHOTON JOURNAL OF CHEMICAL NATURAL RESOURCES (JCNaR)

Zul Alfian

Program Studi Kimia, FMIPA, Universitas Sumatera Utara ,Medan.

Author-ID : 224358

Agriculture, Biological Sciences & Forestry Biochemistry, Genetics & Molecular Biology Chemistry Law, Crime, Criminology & Criminal Justice Materials Science & Nanotechnology Nursing Physics Social Sciences

Published : 12 Documents Claim Missing Document

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PEMANFAATAN KULIT UBI KAYU MENJADI KERUPUK DAN PENENTUAN KADAR NUTRIENNYA -, Yusbarina; Nst, Rumondang Bulan; Alfian, Zul
Sistem Informasi Vol 2 No 2 (2012): Jurnal Photon
Publisher : Fakultas MIPA dan Kesehatan Universitas Muhammadiyah Riau

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (642.84 KB)

Industri rumah tangga keripik ubi kayu Sanjai di Medan bahan bakunya 10 ton perhari dan 30% dari bahan baku tersebut dibuang yaitu kulitnya. Penelitian ini bertujuan untuk mengetahui berapa kadar HCN dalam kulit ubi kayu, bagaimana cara mengolah kulit ubi kayu menjadi kerupuk, berapa kadar nutrien (karbohidrat, protein, lemak, air dan abu), serta hasil uji organoleptik kerupuk. Hasil penelitian menunjukkan kadar HCN kulit ubi kayu: 22,14 mg/kg. Hal ini menunjukkan bahwa kulit ubi kayu aman untuk diolah menjadi bahan makanan. Kerupuk dibuat dengan mengolah kulit ubi kayu dengan tepung tapioka dengan perbandingan 1:2. Kadar karbohidrat, protein, air, abu, dan lemak kerupuk secara berturut âturut yaitu 82,90; 1,10; 13,00; 2,09; dan 0,10%. Hasil uji organoleptik menunjukkan skala 3 (suka).

STUDI PENGGUNAAN KITOSAN KOMPOSIT CuO SEBAGAI ADSORBEN UNTUK MENYERAP LOGAM BESI (Fe) MANGAN (Mn) DAN SENG (Zn) PADA AIR SUNGAI BELAWAN Mutia Khairuni; Zul Alfian; Harry Agusnar
JURNAL KIMIA MULAWARMAN Vol 14 No 2 (2017)
Publisher : Jurusan Kimia Fakultas Matematika dan Ilmu Pengetahuan Alam Universitas Mulawarman

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The synthesis of chitosan-CuO composite and its application as an adsorbent in the removal of Fe, Mn, and Zn in Belawan river water has been conducted. Chitosan-CuO composite is synthesized by addition the Cu(NO3)2 into the solution of chitosan and NaOH 2M. This adsorbent is characterized with FT-IR and its capability to adsorb heavy metals is measured with ICP-OES. The preliminary result of Fe, Mn, and Zn level in Belawan river water are 0,3032; 0,3251; and 0,06402 mg/L, respectively, those value levels are above the PP No. 82 Tahun 2004 safety limit. The optimum contact time of adsorbent to interact is found at 30 minutes, with Fe, Mn, and Zn adsorption is 69,71; 90,53; and 92,05%, respectively. The decrease of heavy metal levels in Belawan river water is influenced by the contact time of adsorbent to the sources of heavy metal.

Application of Biopesticide from Eucalyptus grandis on Mortality of Fruit Flies (Bactrocera sp.) on Sweet Citrus (Citrus X Sinensis) Plants Taufik, Muhammad; Zuhra, Cut Fatimah; Cahyady, Boby; Hardiyanti, Rini; Ardilla, Desi; Razali, Mariany; Alfian, Zul
ABDIMAS TALENTA: Jurnal Pengabdian Kepada Masyarakat Vol. 7 No. 1 (2022): ABDIMAS TALENTA: Jurnal Pengabdian Kepada Masyarakat
Publisher : Talenta Publisher

The application of biopesticides is one of the safest alternatives to realize organic agriculture that does not cause harmful impacts to both consumers and the environment. This activity aims to apply biopesticides in eradicating fruit flies (Bactrocera sp.) on Sweet Orange (Citrus X Sinensis) plants. The partner location is the Bukit Rumah Sendi Farmers Group in Karo Regency. Eucalyptus grandis leaves were extracted using steam distillation then the concentration of 1,8 Sineol was determined using GCMS and the concentration was 52%. Eucalyptus oil was mixed with kerosene and detergent then determined the LC50 value in fruit flies and observed for 24, 48, 72, and 96 hours and produced an LC50 value of 35%. This shows that biopesticides are quite effective in eradicating fruit flies.

Analysis of Copper (Cu), Chromium (Cr), and Manganese (Mn) Levels from Liquid Waste of The Steel Industry with Atomic Absorption Spectrophotometry (AAS) Method Aini, Syarifah; Alfian, Zul; Agusnar, Harry
Journal of Chemical Natural Resources Vol. 3 No. 1 (2021): Journal of Chemical Natural Resources
Publisher : Talenta Publisher

Liquid waste from the steel industry processing, washing machine, and kitchenware foundry contained the elements of copper (Cu), chromium (Cr), and manganese (Mn). The effluent samples were destructed using concentrated HNO3. Then determined the concentration of the elements copper (Cu), chromium (Cr), and manganese (Mn) using an Atomic Absorption Spectrophotometer with a calibration curve. The results obtained for the level of copper (Cu) on the sample inlet was 0.9714 mg/L to 0.9719 mg/L, and the sample outlet was 3.9990 mg/L to 4.0002 mg/L. Levels of the element chromium (Cr) on sample inlet was 0.0295 mg/L to 0.0297 mg/L, the sample outlet was 0.0399 mg/L to 0.0400 mg/L. Meanwhile, the level of manganese (Mn) in the sample inlet was 0.1269 mg/L to 0.1271 mg/L in a sample outlet was 2.9699 mg/L to 2.9701 mg/L. Then the steel industry wastewater for elemental copper (Cu) and manganese (Mn) exceeded the limits that have been instituted by the Minister of Environment Decree No. 51, 1995, regarding the Liquid Waste Quality Standard for Industrial Activity.

Fabrication and Characterization of Glucosamine Hydrochloride from Chitin of Horseshoe Crab Shell (Tachypleus gigas) Nasution, Aurora Khairani; Agusnar, Harry; Alfian, Zul
Journal of Chemical Natural Resources Vol. 3 No. 2 (2021): Journal of Chemical Natural Resources
Publisher : Talenta Publisher

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.32734/jcnar.v3i2.9350

Preparation of glucosamine hydrochloride from the chitin of horseshoe crab shells using the chemical hydrolysis method has been done using HCl concentration variation ratios of 7%, 9%, 11%,14 % with a ratio of 9:1 (v/w) for 4 hours at a temperature of 90ÂºC. Determination of glucosamine hydrochloride characteristics was characterized using Fourier transform-infra red (FT-IR) spectroscopy, in which the characteristics of glucosamine hydrochloride obtained in the OH group of glucosamine hydrochloride were 3446 cm-1 (s), 3448 cm-1 (s), 3450 cm-1 (s), 3448 cm-1 (s), respectively. For NH group of glucosamine hydrochloride were 1557 cm-1 (s), 1559 cm-1 (s), 1556 cm-1 (s), 1560 cm-1 (s), respectively. For CN group of glucosamine hydrochloride were 1379 cm-1 (m), 1379 cm-1 (m), 1379 cm-1 (m), 1379 cm-1 (m), respectively. While the glycoside bond of glucosamine hydrochloride 1073 cm-1 (w), 1074 cm-1 (w), 1074 cm-1 (w), 1074 cm-1 (w), respectively. Determination of the concentration of glucosamine hydrochloride with Ultraviolet Spectrophotometer analysis at a maximum wavelength of 197 nm with a standard solution of N-acetyl glucosamine in a solution of phosphate acid 0.005%, in which obtained the concentration of glucosamine hydrochloride 7% = 33.67 ppm, 9% = 36.35 ppm, 11% = 40.16 ppm, 14% = 43.97 ppm.

Analysis of the Copper (Cu), Chromium (Cr), and Manganese (Mn) Levels from the Steel Industry Liquid Waste by Atomic Absorption Spectrophotometry Method Alfian, Zul; Aini, Syarifah; Agusnar, Harry
Journal of Chemical Natural Resources Vol. 4 No. 1 (2022): Journal of Chemical Natural Resources
Publisher : Talenta Publisher

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.32734/jcnar.v4i1.10502

Liquid waste from the steel industry processing, washing machine, and kitchenware foundry that is disposed containing copper (Cu), chromium (Cr) and manganese (Mn) elements which is harmful to enviromental. The levels of elemental copper (Cu), chromium (Cr), and manganese (Mn) were analyzed using Atomic Absorption Spectrophotometry (AAS) method. The effluent samples were destructed with the addition of concentrated HNO3. Then determining of the concentration of the element copper (Cu), chromium (Cr) and manganese (Mn) using Atomic Absorption Spectrophotometer with a calibration curve. The obtained results for the levels of copper (Cu) on the inlet samples were 0.9714 mg/L - 0.9719 mg/L, the outlet samples were 3.9990 mg/L - 4.0002 mg/L. Hence, the levels of the element chromium (Cr) on inlet samples were 0.0295 mg/L - 0.0297 mg/L, the outlet samples were 0.0399 mg/L - 0.0400 mg/L and the levels of manganese (Mn) in the inlet samples were 0.1269 mg/L - 0.1271 mg/L in a outlet samples were 2.9699 mg/L - 2.9701 mg/L. Then the steel industry wastewater for elemental copper (Cu) and manganese (Mn) has exceeded the limits that have been instituted by the Minister of Environment Decree No. 51, 1995, about the Liquid Waste Quality Standard for Industrial Activity

Effectiveness of Activated Zeolite in Reducing Iron (Fe) and Zink (Zn) Metal Levels in Borehole Water Zul Alfian; Ronaldo Sensini Siregar
Journal of Chemical Natural Resources Vol. 5 No. 2 (2023): Journal of Chemical Natural Resources
Publisher : Talenta Publisher

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.32734/jcnar.v5i2.13793

Research has been carried out on the adsorption of iron (Fe) and zinc (Zn) metal levels using activated zeolite with acid and base in healthy water. Characterization was carried out on activated zeolite using X-ray Fluorescence (XRF). Samples were taken from borehole water from Puji Mulyo area, Deli Serdang, and preserved with HNO3 until pH < 2, then digested. Determined the concentration of iron (Fe) and zinc (Zn) before and after the addition of activated zeolite by NaOH and HCl using an Atomic Absorption Spectrophotometer (AAS) with length-specific waves are 248.3 nm for iron (Fe) and 213.9 nm for zinc (Zn) metal. The results showed that the concentration of iron (Fe) and zinc (Zn) in the borehole water after the addition of activated zeolite decreased. Zeolite activated by NaOH absorbs iron (Fe) metal by 68.60% and absorbs zinc (Zn) metals by 37.91%. Meanwhile, Zeolite activated by HCl absorbs iron (Fe) by 42.37% and absorbs zinc (Zn) metal by 15.17%. This research shows that the effectiveness of percentage (%) decreasing the concentration of iron (Fe) and zinc (Zn) metal using activated zeolite with NaOH was more significant and more effective than activated zeolite with HCl.

Electrolysis of Metal Coating Industrial Waste Using Carbon Electrode to Reduce Metal Levels of Chromium (Cr), Zink (Zn), and Cadmium (Cd) Zul Alfian; Valentina Hutagalung
Journal of Chemical Natural Resources Vol. 6 No. 1 (2024): Journal of Chemical Natural Resources
Publisher : Talenta Publisher

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.32734/jcnar.v6i1.16208

The wastewater from the metal coating industry comprises hazardous and poisonous metals, necessitating the reduction of its concentration before its release into water. The typically employed chemical technique involves the addition of Poly Aluminium Chloride (PAC), which causes the hazardous element to accumulate due to the subsequent application of Poly Aluminium Chloride (PAC). Next, the metal content is measured and determined using the atomic absorption spectrophotometry. This study employed the electrolysis technique utilizing carbon electrodes. The liquid waste undergoes electrolysis with voltage changes of 8, 11, 14, and 17 volts for 2 hours. The investigation yielded the optimal voltage for minimizing the metal content. The voltage applied to the metal is 17 volts. The reduction in the concentrations of Cr, Zn, and Cd metals achieved with the optimal voltage is 63.02%, 70.02%, and 80.14%, respectively.

Reduction of Metal Density of Iron (Fe) and Natrium Minerals (Na) in Boring Water Using Rubber Fruit Sheets Active Archoic Zul Alfian; Uly Ashari
Journal of Chemical Natural Resources Vol. 6 No. 1 (2024): Journal of Chemical Natural Resources
Publisher : Talenta Publisher

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.32734/jcnar.v6i1.16221

Activated carbon is a highly popular adsorbent for the absorption of metal ions. Lignocellulosic materials can be used to produce activated carbon, which is both renewable and abundant, as well as being cost-effective. The objective of this research is to investigate the reduction of iron (Fe) and sodium (Na) levels in the artesian well by utilizing activated carbon made from rubber shells. The materials utilized include rubber shells, a solution containing 10% H3PO4 (phosphoric acid), water from an artesian well, and distilled water (aquadest). The carbonization process was conducted at 300Âº C for 1 h, using an adsorbent size of 120 mesh. In addition, chemical activation was performed using a 10% H3PO4 solution for 24 h, followed by physical activation through heating in a furnace at a temperature of 500ÂºC for 1 hour. The acquired activated carbon is utilized for the absorption of Fe and Na. The activated carbon was characterized using X-ray diffraction (XRD), and the concentration of Fe and Na minerals was determined using an Atomic Adsorption Spectrophotometer (AAS). The results indicated a reduction of 97.9% in the concentration of iron (Fe) and a decrease of 90.01% in sodium (Na) levels.

Reduction of Metal Density of Iron (Fe) and Copper (Cu) Using Corn Active Archarge and Commercial Active Archarge on Water from a Bali Well Zul Alfian; Fristiwayuni Dara Silvia
Journal of Chemical Natural Resources Vol. 6 No. 1 (2024): Journal of Chemical Natural Resources
Publisher : Talenta Publisher

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.32734/jcnar.v6i1.16223

Through the use of commercial and cassava peel activated charcoal, research was done on how to lower the levels of iron (Fe) and copper (Cu) in well water that had been excavated. X-ray diffraction (XRD) was utilized to conduct the activated charcoal test. The samples were collected from the wells of individuals residing in Kelurahan Sumber Karya Binjai Timur. Water samples were treated with concentrated nitric acid (HNO3) and decomposed. The concentration of iron (Fe) and copper (Cu) was determined before and after adding activated charcoal made from cassava peel and commercially available activated charcoal, with masses of 1, 2, 3, 4, and 5 g. This was done using Atomic Absorption spectrophotometry (AAS) at specific wavelengths of 248.3 nm for Fe and 324.8 nm for Cu. The research findings indicate a decrease in iron (Fe) and copper (Cu) concentration before and after. The amount of activated charcoal made from cassava peel was varied from 1g to 5g. As the mass increased, the iron (Fe) concentration fell by 94.08%, 97.53%, 99.01%, 99.10%, and 99.07% respectively. The copper (Cu) content was reduced by 92.73%, 96.36%, 96.36%, 98.48%, and 97.12%. For commercial activated charcoal with varying masses of 1, 2, 3, 4, and 5 grams, the concentration of iron (Fe) was reduced by 0.27%, 52.41%, 72.70%, 98.85%, and 98.09%, respectively. The copper (Cu) content reduced by 32.22%, 71.25%, 95.31%, 98.18%, and 96.06%.

Co-Authors Cahyady, Boby Cut Fatimah Zuhra Desi Ardilla Fristiwayuni Dara Silvia Harry Agusnar Harry Agusnar Harry Agusnar Helen Gandaria Situmorang M. Arifin Siahaan MUHAMMAD TAUFIK Muhammad Taufik Mutia Khairuni Nasution, Aurora Khairani Nst, Rumondang Bulan Razali, Mariany Rini Hardiyanti Ronaldo Sensini Siregar Rumondang Bulan Nst Syarifah Aini Uly Ashari Valentina Hutagalung Yusbarina -

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