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Karakterisasi Biochar dari Ampas Tebu dan Kemampuan Penyerapan Nitrogen Sebagai Amelioran Pada Tanah Gambut Secara In Vitro Warsidah Warsidah; Suparnawati Suparnawati; Anthoni Batahan Aritonang; Puji Ardiningsih; Asri Mulya Ashari; Mega Sari Juane Sofiana
Innofarm:Jurnal Inovasi Pertanian Vol. 23 No. 1 (2021): Innofarm : Jurnal Inovasi Pertanian
Publisher : FAKULTAS PERTANIAN UNIVERSITAS SLAMET RIYADI

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.33061/innofarm.v23i1.5604

Abstract

Research has been carried out on the characterization of biochar pores produced from bagasse through a pyrolysis process at a temperature of 110oC for 4 hours, using the Scaning Electron Microscopy-Energy Dispersive X-Ray (SEM-EDX) method. The biochar of sugarcane pulp produced is then tested for its ability to absorb nitrogen content (% N-total), with the source of N is urea fertilizer through the Kjedhal method based on SNI (2801: 2010), and the source of nitrogen from a solution of ammonium sulfate (NH4)2SO4 by the titrimetric method. The SEM measurement results showed that the biochar pores were uniform and micro-sized, while the peat pores were macro in size and irregular. EDX results show that biochar is composed of 100% carbon, while peat soil consists of carbon compounds (C), Oxygen (O) Silica (Si) and Aluminum (Al). Both of biochar and peat have moisture content of 0.38% and 11.79%, ash content of 2.42% AND 24.44%, volatile content of 0.53% and 5.23% of bound or fixed carbon (cf) of 97.02% and 58.53%. The results of the biochar capacity test applied to peat soils can increase the pH of the peat from 5 to 6.5 with the ability to absorb N-total from urea (NH2)2CO and N-total fertilizer sources from ammonium sulfate (NH4)2SO4 solution of 38% - 66%, and 56.5% -84.5%.
Synthesis and Characterisation of B-CDs/TiO2 Composite Anthoni B. Aritonang; Ajuk Sapar; Uswatun Hasanah; Adhitiyawarman Adhitiyawarman; Puji Ardiningsih
Jurnal Akademika Kimia Vol. 11 No. 4 (2022)
Publisher : Universitas Tadulako

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Abstract

Synthesis of composite boron-doped carbon nanodots (B-CDs)/TiO2 using the sol-gel method performed with titanium tetraisopropoxide (TTIP) precursor and B-CDs prepared by the microwave method using citric acid monohydrate, urea, and boric acid as precursors. The optimum concentration of boron dopant (B) on B-CDs/TiO2 is 0.5% boron (w/w) which is then used as a composite on TiO2 resulting in a brown solid and has blue luminescent under UV light. The result with UV-Vis/DRS for variation in B-CDs concentration of 0.5%, 1.25%, and 2.5% showed Eg values of 2.34 eV, 2.00 eV, and 2.29 eV. B-CDs cause the maximum emission peak (λEm) to redshift and affect the intensity of photoluminescence TiO2. The characterization of FT-IR does not indicate a new peak, there is no bonding in the B-CDs/TiO2 composite. The TiO2 diffractogram was observed to shift towards a larger 2θ which caused the crystallinity of TiO2 to decrease. Based on the photocatalytic activity test on the degradation of methylene blue solution, it showed fairly good activity. It is expected that the B-CDs/TiO2 composite has the potential to be applied as a photocatalyst to degrade organic pollutants under visible light illumination.
Synthesis and Characterisation of B-CDs/TiO2 Composite Anthoni B. Aritonang; Ajuk Sapar; Uswatun Hasanah; Adhitiyawarman Adhitiyawarman; Puji Ardiningsih
Jurnal Akademika Kimia Vol. 11 No. 4 (2022)
Publisher : Universitas Tadulako

Show Abstract | Download Original | Original Source | Check in Google Scholar

Abstract

Synthesis of composite boron-doped carbon nanodots (B-CDs)/TiO2 using the sol-gel method performed with titanium tetraisopropoxide (TTIP) precursor and B-CDs prepared by the microwave method using citric acid monohydrate, urea, and boric acid as precursors. The optimum concentration of boron dopant (B) on B-CDs/TiO2 is 0.5% boron (w/w) which is then used as a composite on TiO2 resulting in a brown solid and has blue luminescent under UV light. The result with UV-Vis/DRS for variation in B-CDs concentration of 0.5%, 1.25%, and 2.5% showed Eg values of 2.34 eV, 2.00 eV, and 2.29 eV. B-CDs cause the maximum emission peak (λEm) to redshift and affect the intensity of photoluminescence TiO2. The characterization of FT-IR does not indicate a new peak, there is no bonding in the B-CDs/TiO2 composite. The TiO2 diffractogram was observed to shift towards a larger 2θ which caused the crystallinity of TiO2 to decrease. Based on the photocatalytic activity test on the degradation of methylene blue solution, it showed fairly good activity. It is expected that the B-CDs/TiO2 composite has the potential to be applied as a photocatalyst to degrade organic pollutants under visible light illumination.