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Mohamad, Juliany Ningsih
Universitas Nusa Cendana
Astronomy Chemical Engineering, Chemistry & Bioengineering Earth & Planetary Sciences Education Electrical & Electronics Engineering Energy Engineering Environmental Science Industrial & Manufacturing Engineering Materials Science & Nanotechnology Physics Social Sciences

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PEMBUATAN SERAT NANO PVA/TIO2/Zat Warna MENGGUNAKAN ELEKTROSPINNING SEBAGAI SEL SURYA DSSC MENGGUNAKAN ELEKTRODA KAIN FIBERGLASS/TINTA KARBON Juan Prianto; Valentinus Galih Vidia Putra; Juliany Ningsih Mohamad
Jurnal Fisika : Fisika Sains dan Aplikasinya Vol 6 No 2 (2021): Jurnal Fisika : Fisika Sains dan Aplikasinya
Publisher : Universitas Nusa Cendana

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.35508/fisa.v6i2.6835

Abstract

Abstrak Sebagai wilayah tropis, Indonesia mempunyai banyak area yang disinari matahari dengan baik. Oleh karena itu energi terbarukan yang berasal dari energi matahari dapat dimafaatkan sebagai energi alternatif selain energi dari bahan bakar fosil. Salah satu energi alternatif yang mempunyai potensi sangat besar namun belum dimanfaatkan secara maksimal adalah sel surya (fotovoltaik) yang mampu mengkonversi sinar matahari secara langsung menjadi energi listrik tanpa menghasilkan emisi gas buang apapun. Salah satu bentuk umum dari sel surya adalah Dye Sensitized Solar Cells yang memanfaatkan zat warna sebagai photosensitizer. Agar DSSC dapat menghasilkan tegangan dan arus yang tinggi, diperlukan semikonduktor yang memiliki bandgap rendah. Cara untuk meningkatkan tegangan yang dihasilkan adalah dengan memperkecil ukuran molekul dengan memperkecil jarak antar atom semikonduktor ataupun dengan memperkecil jarak antar molekulnya. Penggunaan elektrospinning dalam pembuatan serat nano diharapkan dapat memperkecil jarak atau ukuran molekul dari semikonduktor yang digunakan. Pada penelitian ini digunakan campuran PVA/TiO2 sebagai semikonduktornya karena TiO2 memiliki bandgap yang rendah dan tersedia dengan harga murah secara komersil. Tahapan yang dilakukan pada penlitian ini adalah mulai dari pembuatan campuran zat PVA/TiO2 lalu proses elektrospinning pengujian menggunakan SEM dan pengujian tegangan serta arus pada susunan DSSC. Pada penelitian ini digunakan zat warna antosianin yang berasal dari wortel sebagai photosensitizer. Setelah direndam zat warna dilakukan proses curing lalu ditambahkan elektrolit dan DSSC disusun menyerupai sandwich. Elektrolit yang digunakan adalah campuran KI/I2 yang dibuat dalam bentuk gel sebagai variabel tetap. Pada penelitian ini dilakukan pengujian SEM untuk melihat morfologi dan ukuran dari serat PVA/TiO2. Dilakukan pengujian UV-Vis pada larutan PVA/TiO2 dan larutan zat warna. Dilihat dari pengujian SEM, lapisan tipis PVA/TiO2 dapat dibentuk menggunakan elektrospinning tegangan 20kV dan waktu 240 detik yang menghasilkan ukuran serat dengan rata – rata sebesar 177,6nm. Energi gap dari serat nano PVA/TiO2 yang dihasilkan sebesar 2,8eV. Tegangan yang dihasilkan pada saat sel surya terpapar sinar matahari sebesar 53mV sementara tegangan yang dihasilkan pada saat sel surya tidak terpapa sinar sebesar 8mV. Arus dihasilkan pada saat sel surya terpapar sinar matahari sebesar 26,5 sementara arus yang dihasilkan pada saat sel surya tida terpapar sinar matahari sebesar 4 . Abstract Indonesia as tropical islands have many areas that are exposed to sunlight therefore renewable energy from solar energy can be utilized as an alternative other than energy from fossil fuels. Alternative energy which has great potential but is not yet fully utilized are solar cells (photovoltaic) that can convert solar energy directly from sunlight into electrical energy without producing any emission gasses. One of the common forms of solar cells is Dye-Sensitized Solar Cells that utilize dyes to be used as photosensitizers. In order for DSSC to produce high voltage and current, a semiconductor with a low bandgap is needed. The way to increase the resulting voltage is to reduce the size of the molecule by reducing the distance between the semiconductor atoms or by reducing the distance between the molecules. The use of electrospinning in the manufacturing of thin-film nanofiber is expected to reduce the distance between molecules of the used semiconductor. In this study, the mixture of PVA/TiO2 is used as a semiconductor because of the low bandgap of TiO2, low price, and commercially available. The stages that are carried in this study are started from making a mixture solution of PVA/TiO2 then the electrospinning process, SEM test, and voltage and current measurement from the DSSC array. In this study, the dye used as a photosensitizer is anthocyanin dye from carrot. After the dipping of dyes, the fabric is then cured and the electrolyte is added and piled up like a sandwich. The electrolyte that used in this study is the mixture of KI/I2 in solid form as a fixed variable. SEM test is done to see the nanofiber morphology and fiber size of a thin film of PVA/TiO2. UV-Vis test was performed on PVA/TiO2 solution and dye solution. Judging from the SEM test, a thin layer of PVA/TiO2 can be formed using electrospinning with a voltage of 20kV and a time of 240 seconds which produces an average fiber size of 177.6nm. The energy gap of the PVA/TiO2 nanofibers produced is 2.8eV. The voltage generated when the solar cell is exposed to sunlight is 53mV while the voltage generated when the solar cell is not exposed to light is 8mV. The current generated when the solar cell is exposed to sunlight is 26.5μA. while the current generated when the solar cell is not exposed to sunlight is 4μA.
Novel Method for Fire Retardancy of Cotton Fabrics Coated by Spinach Leaf Extract Assisted by Corona Discharge Plasma Valentinus Galih Vidia Putra; Andrian Wijayono; Juliany Ningsih Mohamad
Dinamika Kerajinan dan Batik: Majalah Ilmiah Vol 37, No 2 (2020): DINAMIKA KERAJINAN DAN BATIK : MAJALAH ILMIAH
Publisher : Balai Besar Kerajinan dan Batik

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22322/dkb.v37i2.6038

Abstract

The application of material physics in the functional textile field has been widely applied, one of which is plasma technology. In this research, the fire-retardant properties have been developed in the cotton fabric textile material using spinach leaf extract and comparison of fire-retardant resin on the market using plasma technology. The flame-retardant is applied to the cotton fabric using the atmospheric-pressure plasma method with a tip-cylinder electrode. The cotton fabric used is a cotton fabric that has undergone a process of bleaching and mercerization. In this research, two types of methods have been carried out, namely the immersion method on the fire-retardant resin substance with atmospheric pressure plasma pre-treatment and the immersion method on spinach leaf extract with atmospheric pressure plasma treatment. Research shows that there is an increase in the fire-retardant properties of cotton fabrics that have been given treatment. The assessment of fire-retardant properties was tested using the standard method of fire-retardant ASTM D6413-08 vertical method. In this research, atmospheric-pressure plasma treatment with a time variation of 2 minutes and 4 minutes has been carried out. The results showed that the cotton fabric treated with the immersion method on spinach leaf extract and atmospheric pressure plasma pre-treatment had better fire-retardant properties. It has also been found that the length of time the plasma treatment will affect the fire-retardant properties of cotton fabrics.
PROTOTIPE PAKAIAN ANTI RADIASI UNISEX SPORTSWEAR SMARTPHONE DENGAN PAPARAN RADIASI PLASMA PIJAR KORONA ELEKTRODA TIP- SILINDER Valentinus Galih Vidia Putra; Annisa Diyan Fitri; Ichsan Purnama; Juliany Ningsih Mohamad
Jurnal Kumparan Fisika Vol 3, No 1 April (2020): Jurnal Kumparan Fisika
Publisher : Unib Press, Universitas Bengkulu

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.33369/jkf.3.1.19-24

Abstract

ABSTRAK Pada penelitian ini telah dikembangkan sebuah produk pakaian anti radiasi unisex sports wear menggunakan teknologi plasma pijar korona elektroda tip-plane. Plasma pijar korona dibangkitkan dengan listrik tegangan tinggi serta menggunakan elektroda asimetri  (lancip dan plat).Pembuatan pakaian anti radiasi menggunakan bahan rajut yang telah diplasma sertadilapisi dengan tinta konduktif. Hasil studi memperlihatkan bahwa metode pembuatan pakaian dengan plasma pijar korona telah berhasil mengurangi radiasi gelombang elektromagnetik. Kata kunci: plasma pijar, pakaian unisex sportswear, elektroda tip-plane, anti radiasi ABSTRACT This paper describes the making of an anti-radiation smartphone unisex sportswear. The anti-radiation patch was developed by first modifiying the surface of the textile using atmospheric pressure plasma technology. The plasma corona discharge is generated by using a high voltage electricity withasymmetrical electrodes (tip and plane). The treated patch was than coated with graphite based conductive ink. The result of thisresearchindicates that an anti-radiation clothe patch was succesfully shield an electromagnetic radiation from a smartphone. Keywords: plasma discharge, unisex sportswear, tip-plane electrode, electromagnetic shielding
A New Model to Calculate Stress Relaxation of Viscoelastic Material for Polyester-Wool-Spandex Yarn with Analytical Mechanics Approach Valentinus Galih Vidia Putra; Juliany Ningsih Mohamad; Yusril Yusuf
Jurnal Penelitian Fisika dan Aplikasinya (JPFA) Vol. 11 No. 2 (2021)
Publisher : Universitas Negeri Surabaya

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.26740/jpfa.v11n2.p94-105

Abstract

Many researchers have studied the mechanical properties of yarn in textile science because mechanical properties are the essential parameter in determining yarn quality. This research aims to make a new model and prediction of the material properties of textile yarns, especially for stress relaxation of viscoelastic textile yarn for polyester-wool-spandex yarn cases. In this research, a new approximation of the analytical mechanics model of stress relaxation using a system of four springs and a dashpot to determine viscoelastic yarn properties as polyester-wool-spandex has been studied. A yarn movement equation for viscoelastic yarn as polyester-wool-spandex having 36 yarn count number (in unit tex or g/km) has been formulated using analytical mechanics, and the model has been validated experimentally. The coefficient of determination R2 ranges from 0.82, which shows the closeness between the experimental results and the theoretical predictions. In this research, it is found that this model can be implemented to determine the viscoelastic material of yarn based on the properties of yarn as stress relaxation using the analytical mechanics approach.  
FT-IR Spectral Model of Polyester-Cotton Fabrics with Corona Plasma Treatment using Artificial Neural Networks (ANNs) Irwan Irwan; Valentinus Galih Vidia utra; Juliany Ningsih Mohamad
INDONESIAN JOURNAL OF APPLIED PHYSICS Vol 13, No 1 (2023): April
Publisher : Department of Physics, Sebelas Maret University

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.13057/ijap.v13i1.67837

Abstract

Corona plasma technology has been studied as a surface modification for the adhesive bonding of polymers. Although corona plasma (C.P.) is becoming more popular in nanotechnology, the influence of corona plasma treatment parameters on the FT-IR spectra is a problem that has yet to be addressed. The purpose of this study is to use an artificial neural network to study the influence of corona plasma (C.P.) treatment parameters on textile polymer and evaluate the ability of this model to predict FT-IR spectral information from FT-IR measurements. In this study, polymers were modified under various corona plasma treatment conditions. We investigated FT-IR spectra information of polymers from FT-IR measurements by varying corona plasma treatment variables. We used three input parameters in this study: wavenumber, voltage, and exposure time—two output parameters: fabric roughness with SEM according to the degree of smoothness and percent transmission with FT-IR. The novel aspect of this study is that we used ANN to model the plasma treatment on polyester-cotton fabrics and the FT-IR spectra accurately enough for the first time. According to this study, the model that used four nodes (neurons) in the hidden layer, three input parameters (x1,x2,x3), and 20 iterations is appropriate for determining fabric surface roughness (S.R.) and percent transmission (T%). Based on this research, the values of R2 for determining fabric surface roughness (S.R.) and percent transmission (T%) were 99.79 percent and 67.18 percent, respectively. The results showed that the developed ANNs could accurately predict the experimental data in detail. This study is significant because it uses artificial intelligence to calculate and simulate the FT-IR spectra and fabric surface roughness of plasma treatment on textile fabrics. This study's scientific application is that it will help experts, researchers, and engineers understand the implications of plasma on the chemical structure of textile materials.
Study of Surface Tension Properties looked on Contact Angle Value on 100% Nylon Textile Fabric Using Corona Discharge Plasma Technology Valentinus Galih Vidia Putra; Juliany Ningsih Mohamad; Yusril Yusuf
Wahana Fisika Vol 5, No 1 (2020): June
Publisher : Universitas Pendidikan Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.17509/wafi.v5i1.22382

Abstract

This paper provides an explanation of the application of corona discharge plasma in textile field specially for modification  of surface properties and wet ability of nylon 100% fabric. In this research, we have found that the properties of  wet ability of nylon 100% fabric with 70 / inch of weft density and 60/inch of warp density  is influenced by  corona discharged plasma analyzed by the contact angle of the fabric on capillarity phenomena under same test time for contact angle test.       Artikel ini menjabarkan  pemanfaatan aplikasi teknologi plasma pijar korona pada bidang tekstil dalam modifikasi sifat pembasahan pada permukaan kain nilon 100% ditinjau dari sifat fenomena kapilaritas. Hasil riset memperlihatkan bahwa dengan perlakuan plasma pada kain nilon 100% dengan tetal pakan dan lusi masing-masing 70 helai/inci dan 60 helai/inci didapatkan  bahwa terdapat perubahan sifat hidrofilik (dapat lebih mudah menyerap) kain melalui perubahan sudut kontak pada fenomena kapilaritas untuk waktu uji sudut kontak yang sama.
Tip-cylinder electrode plasma to enhance the coating of conductive yarn process Valentinus Galih Vidia Putra; Lutfi Zulfikar; Atin Sumihartanti; Juliany Ningsih Mohamad; Yusril yusuf
Jurnal Rekayasa Proses Vol 14 No 2 (2020): Volume 14, Number 2, 2020
Publisher : Jurnal Rekayasa Proses

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22146/jrekpros.54946

Abstract

This study aims to develop conductive textile materials using a polyester textile yarn by applying a knife coating method and pre-treatment of a tip-cylinder plasma electrode. In this research, carbon ink was coated on polyester staple yarn which was given a pre-treatment with a plasma generator and coated with the knife coating method. The electrical conductivity of conductive yarns produced from this study was divided into two types, as yarns without plasma treatment and with plasma treatment with a ratio of water and carbon ink concentrations of 1:1 and 2:1. The results of the electrical conductivity with plasma treatment and the concentration of carbon ink and water of 1:1 and 1:2 were 69005 (Ωm)-1 and 50144.25 (Ωm)-1, respectively, while the results of the electrical conductivity for threads with concentrations of carbon ink and water of 1:1 and 1:2 without plasma treatment were 18197.64 (Ωm)­‑1 and 8873.54 (Ωm)-1, respectively. The results showed that the concentration of carbon ink and water and plasma treatment affected the conductive value of the yarn. The results also showed that the presence of plasma pre-treatment improved the coating process of conductive ink on the yarn.
A Study of Anti-Radiation Weaving Fabric with Plasma Corona Treatment Valentinus Galih Vidia Putra; Irwan Irwan; Ichsan Purnama; Juliany Ningsih Mohamad; Yusril Yusuf
INDONESIAN JOURNAL OF APPLIED PHYSICS Vol 11, No 1 (2021): April
Publisher : Department of Physics, Sebelas Maret University

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.13057/ijap.v11i1.40833

Abstract

In this research, Carbon black particles were applied on the woven fabric by the knife coating technique and pretreatment using plasma corona discharge to build-up conductive cotton-polyester (CVC 50%) fabric electromagnetic shielding material. This paper describes the making of anti-radiation weaving fabric using plasma technology. The anti-radiation patch was developed by first modifying the textile fabric's surface using atmospheric pressure plasma technology using tip-cylinder electrode configuration. The plasma corona discharge was generated using high voltage electricity with asymmetrical electrodes (tip and cylinder). The treated weaving fabric using plasma was then coated with carbon black ink. This research indicates that an anti-radiation weaving fabric was successfully shielded electromagnetic radiation from an electronic device.
Developing heat rate and heat capacity measurement instruments of textile waste solution in the textile dyeing process Putra, Valentinus Galih Vidia; Purnomosari, Endah; Mohamad, Juliany Ningsih
Jurnal Ilmiah Pendidikan Fisika Al-Biruni Vol 9 No 2 (2020): Jurnal Ilmiah Pendidikan Fisika Al-Biruni
Publisher : Universitas Islam Negeri Raden Intan Lampung, Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.24042/jipfalbiruni.v9i2.5951

Abstract

Heat rate and heat capacity are widely used to determine the thermal characteristics, especially for wastewater treatment using electro coagulant. This study aimed to determine the value of heat rate and heat capacity of the waste solution in the textile industry, especially in the dyeing waste, by using a microcontroller device. The method for measuring the specific heat capacity and the textile waste solution's heat rate is based on the principle of the first law of Thermodynamics. Temperature measurements were carried out using a digital temperature sensor type DS18B20. In this research, the heat rate and specific heat of the dyeing solution and mineral water used in the textile industry have been studied. This study uses five types of dyeing waste solution as test solutions, namely green waste solution, orange waste solution, blue waste solution, brown waste solution, and mineral water. This experiment's principle is applying Joule's law by using electrical properties with a microcontroller device used to obtain the rise of temperature data each time in real-time every 2 seconds. Based on this research, it can be concluded that the instrument can be used to measure the heat rate and heat capacity of a textile waste solution. Based on this research, we also found that the specific heat of hard water (Hard water is a kind of water with high mineral content, while soft water is water with low mineral content. Apart from calcium and magnesium ions, the cause of hardness can also be other metal ions as well as bicarbonate and sulfate salts) (4.19 ± 0.77) J/ gram ℃ and the specific heat of the four types of waste solution ranged from (3.20 ± 0.72) J/gram ℃ to (6.83 ± 1.71) J/gram ℃ and also it was found that the heat rate of hard water is 0,0471 ℃/s and the heat rate of the four types of waste solution is range from 0,0289 ℃/s to 0,0617 ℃/s.
Co-Authors Annisa Diyan Fitri Atin Sumihartanti Bernandus Bernandus Cahaya Rosyidan Endah Purnomosari Irwan Irwan Irwan Irwan Juan Prianto Lutfi Zulfikar Purnama, Ichsan Purnomosari, Endah Putra, Valentinus Galih Vidia Umbu Harti Mala Valentinus G. V. Putra Valentinus G. V. Putra Valentinus Galih Vidia Putra Valentinus Galih Vidia Putra Valentinus Galih Vidia Putra Valentinus Galih Vidia Putra Valentinus Galih Vidia Putra Valentinus Galih Vidia Putra Valentinus Galih Vidia utra Wijayono, Andrian Yusril Yusuf Yusril Yusuf Yusril Yusuf