Rosita Dwi Chrisnandari
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PENGARUH METODE EKSTRAKSI TERHADAP MUTU PEKTIN DARI KULIT PISANG RAJA NANGKA Vika Ayu Devianti; Rosita Dwi Chrisnandari; Rizky Darmawan
Jurnal Kimia Riset Vol. 4 No. 2 (2019): Desember
Publisher : Universitas Airlangga

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.20473/jkr.v4i2.15753

Abstract

Ekstraksi dengan microwave dan pemanasan langsung merupakan metode yang dapat digunakan untuk ekstraksi pektin dari kulit pisang raja nangka. Penelitian ini bertujuan untuk mengetahui mutu pektin menggunakan metode ekstraksi dengan bantuan microwave dan pemanasan langsung. Berdasar hasil penelitian, diketahui bahwa ekstraksi pektin dengan bantuan microwave memiliki rendemen yang lebih tinggi dibandingkan metode pemanasan langsung. Ekstraksi dengan bantuan microwave menghasilkan pektin dengan kadar air lebih rendah dibandingkan ekstraksi pemanasan langsung. Berat ekivalen berkurang dengan meningkatnya daya microwave. Pektin yang diperoleh dari hasil ekstraksi pemanasan langsung dan microwave tergolong pektin bermetoksil rendah (Derajat esterifikasi < 50%). Kesimpulan dari penelitian ini menunjukkan bahwa ekstraksi menggunakan daya 450 W dengan lama waktu ekstraksi lima menit merupakan kondisi ekstraksi yang terbaik untuk mengekstrak pektin dalam kulit Pisang Raja Nangka.
Efektifitas Reaksi Transesterifikasi Minyak Kelapa dan Sereh untuk Pembuatan Perisa Alami dengan Biokatalisator Lipase serta Penggunaan Ultrasonik Moentamaria, Dwina; Amalia, Nabila Rizki; Rosita Dwi Chrisnandari; Irfin, Zakijah; Wulan, Dyah Ratna
Jurnal Riset Kimia Vol. 15 No. 1 (2024): March
Publisher : Universitas Andalas

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.25077/jrk.v15i1.641

Abstract

In general, flavor are synthesis through enzymatic hydrolysis and esterification reactions (up to 20 hours) using commercial ingredients based on free fatty acids and alcohol. Efficient endeavors utilizing enzymatic transesterification to expedite reactions are necessary to acquire flavored products. Substrates may originate from commercial or natural sources abundant in fatty acids and alcohol. Commercial fatty acids and alcohol (geraniol) are readily available in pure forms. Alternatively, fatty acids can be sourced from coconut oil, while geraniol can be derived from lemongrass oil, which is more cost-effective compared to commercial ingredients. Ultrasonics have emerged as a means to expedite enzymatic. The objective of this study is to investigate the impact of ultrasonic power and transesterification reaction time between coconut oil and geraniol on geraniol conversion. Utilizing lipase (415.99 U/g), coconut oil was subjected to transesterification with commercially obtained pure geraniol in a 1:3 weight ratio, conducted in an ultrasonic tank filled with water. Reaction durations spanned 30, 60, 90, 120, and 150 minutes, with ultrasonic powers set at 50, 70, and 90 watts. The study findings elucidated that the highest geraniol conversion rate of 50.59% was achieved with 70 watts of ultrasonic power over a 90-minute period. These optimal conditions were subsequently applied to transesterify coconut oil with geraniol from lemongrass oil, yielding a conversion rate of 90.29%. This finding demonsttrate the posibility of employing coconut oil and lemongrass oil in a one-stage transesterification process to produce natural flavors via enzymatic lipase catalysis expedited by ultrasonic technology, facilitating swift reaction times.