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Akhmad Sabarudin
Jurusan Kimia Fakultas MIPA Universitas Brawijaya Malang
Environmental Science

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Production of Organic Polymer Based Monolithic Columns for Anion Separation using High Performance Liquid Chromatography Dewi Annisa’; Aprilia Nur Tasfiyati; Hermin Sulistyarti; Akhmad Sabarudin
Natural B, Journal of Health and Environmental Sciences Vol 3, No 1 (2015)
Publisher : Natural B, Journal of Health and Environmental Sciences

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (710.309 KB) | DOI: 10.21776/ub.natural-b.2015.003.01.2

Abstract

Methacrylate-based monolithic columns have been prepared in silanized silicosteel column (100 ´ 0.5 mm id) by in situ polymerization reaction, using glycidyl methacrylate (GMA) as monomer, ethylene dimethacrylate (EDMA) as crosslinker, porogen (1-propanol, 1,4 butandiol, water) and initiator AIBN.  Monolith poly-(GMA-co-EDMA) was then modified with diethylamine and benzyl chloride to obtain ammonium quartener as strong anion exchanger. From the characterization of 4 monolith in this study, monolithic columns poly-(GMA-co-EDMA) with %T 40, %C 25 and polymerization time 24 h has good mechanical stability and permeability, adequate molecular recognition sites (indicated by binding capacity value of 10,119 mg/mL), and has good proportion of flow throughpore and mesopores (45,04% and 41,32% respectively). It can successfully separate the mixture sample of anion consisting of fluoride, bromide, sulfate and nitrate ions by indirect UV detection.
Cu (II) Recovery with Solid Phase Extraction Technique Using Silica Adsorbent from Rice Husk ash - Chitosan Nanang Tri Widodo; Ani Mulyasuryani; Akhmad Sabarudin
Natural B, Journal of Health and Environmental Sciences Vol 2, No 4 (2014)
Publisher : Natural B, Journal of Health and Environmental Sciences

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (558.526 KB) | DOI: 10.21776/ub.natural-b.2014.002.04.11

Abstract

Copper compounds are widely used in modern industry. Many of these compounds are dumped into the surrounding environment. Copper is toxic and able to cause some diseases. The aim of this study is to create solid phase from natural material that applied to the solid phase extraction method as an alternative method to decrease the level of copper from water bodies and able to preconcentrate Cu2+ ions, reaching the detectable level. Silica from rice husk ash modified with chitosan result in an adsorbent that can improve the adsorption of Cu2+. Interaction of Cu2+ with solid phase silica–chitosan is based on data of Fourier Transform Infrared (FTIR), Scanning Electron Microscope (SEM) and Transmission Electron Microscope (TEM). The percentage recovery of Cu2+ each the Cu2+ concentration of 0.05, 0.1 and 0.2 ppm is 55.32%, 54.35% and 71.94%. The adsorbent has ability to adsorb Cu2+ is 100%.
Co-Authors Ani Mulyasuryani Aprilia Nur Tasfiyati Dewi Annisa’ Hermin Sulistyarti Nanang Tri Widodo