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All Journal Jurnal IPTEK IJEMS (Indonesian Journal of Environmental Management and Sustainability) Makara Journal of Technology Advance Sustainable Science, Engineering and Technology (ASSET)
Subriyer Nasir
Chemical Engineering Department, Faculty of Engineering, Sriwijaya University,Inderalaya Ogan Ilir 30662, Sumatera Selatan
Agriculture, Biological Sciences & Forestry Chemical Engineering, Chemistry & Bioengineering Chemistry Civil Engineering, Building, Construction & Architecture Computer Science & IT Control & Systems Engineering Decision Sciences, Operations Research & Management Electrical & Electronics Engineering Energy Engineering Environmental Science Industrial & Manufacturing Engineering Materials Science & Nanotechnology Mechanical Engineering Public Health

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 1 
An Empirical Model for Build-Up of Sodium and Calcium Ions in Small Scale Reverse Osmosis Nasir, Subriyer
Makara Journal of Technology Vol. 14, No. 2
Publisher : UI Scholars Hub

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Abstract

A simple models for predicting build-up of solute on membrane surface were formulated in this paper. The experiments were conducted with secondary effluent, groundwater and simulated feed water in small-scale of RO with capacity of 2000 L/d. Feed water used in the experiments contained varying concentrations of sodium, calcium, combined sodium and calcium. In order to study the effect of sodium and calcium ions on membrane performance, experiments with ground water and secondary effluent wastewater were also performed. Build-up of salts on the membrane surface was calculated by measuring concentrations of sodium and calcium ions in feed water permeate and reject streams using Atomic Absorption Spectrophotometer (AAS). Multiple linear regression of natural logarithmic transformation was used to develop the model based on four main parameters that affect the build-up of solute in a small scale of RO namely applied pressure, permeate flux, membrane resistance, and feed concentration. Experimental data obtained in a small scale RO unit were used to develop the empirical model. The predicted values of theoretical build-up of sodium and calcium on membrane surface were found in agreement with experimental data. The deviation in the prediction of build-up of sodium and calcium were found to be 1.4 to 10.47 % and 1.12 to 4.46%, respectively.
Effective Ammonia Removal from Hospital Wastewater by Using a Combination of Filtrations and Bio-Adsorbent from Tea Waste Ariani, Shinta; Nasir, Subriyer; Melwita, Elda
Indonesian Journal of Environmental Management and Sustainability Vol. 8 No. 4 (2024): December
Publisher : Magister Program of Material Science, Graduate School of Universitas Sriwijaya

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.26554/ijems.2024.8.4.145-153

Abstract

Hospital wastewater contains a high concentration of ammonia that exceed the predetermined quality standards and can cause pollution to the environment. Therefore, the treatment of hospital wastewater is required prior to being released to the environment. Effective ammonia removal process has been developed by using a combination of sponge filtration pretreatment, followed by adsorption using activated carbon from waste of tea leaves, and nanofiltration using ceramic membrane as the final process. Experiment results show the highest effectiveness of ammonia removal of 70% by using filtration only. Effectiveness is increases up to 95% by a combination of filtration and adsorption. A maximum effectiveness of 100% is achieved when using a combination of filtration, adsorption, and nanofiltration. This combination produces an optimal condition for the ammonia removal by using 3 L/min flowrate, adsorbent mass 140 g, and operating time 15 minutes at which the ammonia concentration is 0.08 mg/L. This concentration is below the standard of allowable ammonia concentration of 0.1 mg/L.
Effectiveness of Reducing Ammonia Levels in Hospital Wastewater Using A Combination of Bagasse Bio Adsorbent and Nanofiltration Membrane Lestari, Laily Noor Fitri; Nasir, Subriyer; Komariah, Leily Nurul
Jurnal IPTEK Vol 29, No 1 (2025)
Publisher : LPPM Institut Teknologi Adhi Tama Surabaya (ITATS)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.31284/j.iptek.2025.v29i1.7691

Abstract

The increasing environmental impact caused by hospital wastewater, particularly due to its ammonia content, necessitates innovative treatment methods. This study investigates the effectiveness of a combination of sugarcane bagasse-based activated carbon bio-adsorbent and nanofiltration membrane technology to reduce ammonia concentrations in hospital wastewater. The activated carbon was produced through carbonization at 550°C and chemical activation using 10% H2SO4. Adsorption experiments were conducted by varying bed heights (5, 7.5, and 10 cm) and flow rates (2, 3, and 4 L/min), followed by nanofiltration at 25, 30, and 35 Psi pressures. Results showed that the combined treatment reduced the wastewater pH from 9.08 to 6.53 and ammonia concentration from 4.61 mg/L to 0.02 mg/L, successfully meeting regulatory standards. This indicates that the integrated method effectively decreases ammonia levels and improves wastewater quality before discharge.
Barium Removal from Produced Water Using RCC-Based Ceramic Adsorbent: Fixed-Bed Column Adsorption Herawati, Netty; Nasir, Subriyer; Roni, Kiagus Ahmad; Karim, Muhammad Arif
Advance Sustainable Science Engineering and Technology Vol. 7 No. 4 (2025): August-October
Publisher : Science and Technology Research Centre Universitas PGRI Semarang

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.26877/asset.v7i4.2399

Abstract

This study focuses on the removal of barium ions (Ba²⁺) from produced water, a common challenge in industrial wastewater treatment due to barium’s toxicity and scaling potential. To address this, the research introduces a novel ceramic composite adsorbent formulated from natural clay and residue catalytic cracking (RCC) spent catalyst, combining low cost, sustainability, and enhanced adsorption performance. The main objective is to evaluate the adsorption efficiency of this composite in a fixed-bed column system under varying operational conditions, while also modeling its dynamic behavior. Produced water with an initial barium concentration of 0.58 mg/L (pH 8.8) was fed in up-flow mode at flow rates of 6, 7, and 8 mL/min using a peristaltic pump. Effluent samples collected over 180 minutes were analyzed by UV- Vis. spectrophotometry. Results showed that lower flow rates increased contact time and improved adsorption efficiency, with breakthrough delayed to ~210 minutes at 6 mL/min compared to 160 minutes at 8 mL/min. Breakthrough modeling indicated that the Thomas model best represented the data (R² ≥ 0.95), while the Yoon–Nelson model reliably predicted 50% breakthrough time. This work demonstrates that clay–RCC ceramic composites are effective, low-cost, and sustainable adsorbents.
Co-Authors Agung Mataram Ariani, Shinta Farida Ali, Farida Gaol, Elsa Rama Lumban Hermansyah Hermansyah Karim, Muhammad Arif Kiagus Ahmad Roni Leily Nurul Komariah Lestari, Laily Noor Fitri Mediana, Meta Melwita, Elda Netty Herawati Roosdiana Muin, Roosdiana Susi Susanti