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All Journal Jurnal Natur Indonesia Jurnal Ilmu Kimia Universitas Brawijaya The Indonesian Green Technology Journal The Journal of Pure and Applied Chemistry Research JKPK (Jurnal Kimia dan Pendidikan Kimia) Acta Chimica Asiana
Danar Purwonugroho
Brawijaya University
Agriculture, Biological Sciences & Forestry Biochemistry, Genetics & Molecular Biology Chemical Engineering, Chemistry & Bioengineering Chemistry Earth & Planetary Sciences Materials Science & Nanotechnology Medicine & Pharmacology Other

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Journal : The Journal of Pure and Applied Chemistry Research

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The Adsorption of Cr(VI) Using Chitosan-Alumina Adsorbent Darjito, Darjito; Purwonugroho, Danar; Ningsih, Rumiati
The Journal of Pure and Applied Chemistry Research Vol. 3 No. 2 (2014)
Publisher : Chemistry Department, The University of Brawijaya

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (311.921 KB) | DOI: 10.21776/ub.jpacr.%y.03.02.139

Abstract

Chitosan as adsorbent has been used widely, however it was not effective yet for metal ions adsorption in industrial scale. In acidic condition, chitosan’s active site tends to decrease. This drawback can was solved by coating of chitosan active site on alumina. This paper discloses to overcome that limitation. The charateristic of the active side was analysed by FTIR spectrometry toward vibration N-H group at 1679.15 cm-1, C=O group of oxalate at 1703.30 cm-1, and Al-O group of alumina at 924.07 cm-1. The adsorption capacity of the developed adsorbent was tester to adsorb Cr(VI) ions under various of pH value such as 1, 2, 3, 4, 5, 6, and 7. The contact time affect toward the adsorption was also reported in 20, 30, 40 50, 60, 70, and 80 minute. In addition, the concentration effects (100, 200, 300, 400, 500, and 600 ppm) was also studied. Chromium (VI) was measured using spectronic-20. Adsorption capacity was obtained at 66.90 mg/g under optimum conditions pH 2, and contact time 60 minute, respectively.
Co-Authors A.A. Ketut Agung Cahyawan W Adiba, Naila Azmi Ani Mulyasuryani Arie Srihardyastutie Bambang Ismuyanto Damayanti, Christiana Adi Darjito Darjito Dzakwan, M. Naufal Tsaqif Falisca Amelinda Febrianti, Nufida Tri Felayati, Mifta Fauziah Ilham Pratomo Ira Mardiana Isnaini, Yulia Nur Karti'a, Galuh Wahyu Latifah Dwi Kartika Nurfitriningsih Mega Dona Indriana Mohammad Misbah Khunur Rachmat Triandi Tjahjanto Rosyida, Firdania Firdaus Rumiati Ningsih Sasmita Hanjaya Seruni Swasti Pundisari Sinaga, Ria Septiani Sri Wardhani Suhernadi, Arif Syarifah, Nidatul Tutik Setianingsih Wibisono, Gilang Kopa Yuniar Ponco Prananto