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All Journal JURNAL KIMIA SAINS DAN APLIKASI Jurnal Riset Kimia Elkawnie Abdimas Talenta : Jurnal Pengabdian Kepada Masyarakat Jurnal Ilmu Fisika JKPK (Jurnal Kimia dan Pendidikan Kimia) Jurnal Akademika Kimia JOURNAL OF CHEMICAL NATURAL RESOURCES (JCNaR) Jurnal Natural Jurnal Akademika Kimia
Andriayani
Department Of Chemistry, Faculty Of Mathematics And Natural Sciences, Universitas Sumatera Utara, Jl. Bioteknologi No. 1, Medan 20155, Indonesia
Agriculture, Biological Sciences & Forestry Astronomy Biochemistry, Genetics & Molecular Biology Chemical Engineering, Chemistry & Bioengineering Chemistry Earth & Planetary Sciences Education Energy Engineering Immunology & microbiology Law, Crime, Criminology & Criminal Justice Materials Science & Nanotechnology Neuroscience Physics Social Sciences

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OKSIDASI SORBITOL MENGGUNAKAN MOLEKUL OKSIGEN YANG DIAKTIFASI KATALIS Pd/-Al2O3 DALAM PELARUT AIR -, Andriayani; Raja, Saur Lumban
Jurnal Riset Kimia Vol 1, No 1 (2007): September
Publisher : Universitas Andalas

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.25077/jrk.v1i1.31

Abstract

 ABSTRACT The sorbitol has been oxidized by molecular oxygen that activated by Pd/g-Al2O3 catalyst in water solvent at 70°C. The product was contained 1.3 g (26%) of the glucaric acid. The product was characterized by FT-IR and 1H-NMR spectrophotometer. The product oxidation was reacted with solution of sodium hydroxide methanol at 70°C during 5 hours produced sodium dicarboxylate in the form yellow gel about 0.3 g (30%). The product was characterized by FT-IR and 1H-NMR spectrophotometer. Keywords: sorbitol, oxidation, catalyst, Pd/g-Al2O3, oxygen molecular 
OKSIDASI SORBITOL MENGGUNAKAN MOLEKUL OKSIGEN YANG DIAKTIFASI KATALIS Pd/-Al2O3 DALAM PELARUT AIR Andriayani -; Saur Lumban Raja
Jurnal Riset Kimia Vol. 1 No. 1 (2007): September
Publisher : Universitas Andalas

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.25077/jrk.v1i1.31

Abstract

 ABSTRACT The sorbitol has been oxidized by molecular oxygen that activated by Pd/g-Al2O3 catalyst in water solvent at 70°C. The product was contained 1.3 g (26%) of the glucaric acid. The product was characterized by FT-IR and 1H-NMR spectrophotometer. The product oxidation was reacted with solution of sodium hydroxide methanol at 70°C during 5 hours produced sodium dicarboxylate in the form yellow gel about 0.3 g (30%). The product was characterized by FT-IR and 1H-NMR spectrophotometer. Keywords: sorbitol, oxidation, catalyst, Pd/g-Al2O3, oxygen molecular 
The Effect of Chemical Activation Using Base Solution With Various Concentrations Towards Sarulla Natural Zeolite Saharman Gea; Agus Haryono; Andriayani Andriayani; Junifa Layla Sihombing; Ahmad Nasir Pulungan; Tiamina Nasution; Rahayu Rahayu; Yasir Arafat Hutapea
Elkawnie: Journal of Islamic Science and Technology Vol 6, No 1 (2020)
Publisher : Universitas Islam Negeri Ar-Raniry Banda Aceh

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22373/ekw.v6i1.6913

Abstract

Abstract : Material characteristics analysis of Sarulla natural zeolite (SNZ) with base activation has been carried out. The base used was NaOH at various concentrations; 0.2 M, 0.5 M, and 2 M. Base activated catalysts were characterized by X-ray Fluorescence (XRF), X-ray diffractometer (XRD), Fourier-transform Infrared (FTIR) Spectroscopy, Scanning Electron Microscopy (SEM) and gas adsorption analysis using BET method. The procedures applied have caused differences in adsorption and desorption rates as well as the crystallinity values of the catalytic materials. Moreover, the ratio of Si/Al contents has also changed at the lowest concentration. On the other hand, the crystallinity of catalysts has decreased at the highest concentration of base applied. The results are reinforced in FTIR characterization which shows the changes of silanol bonds to become silicate and aluminate. Furthermore, morphological analysis of the catalysts shows that homogenous surface was obtained at low concentration, while rough/lumpy surfaces was obtained at higher concentration.Abstrak : Analisis terhadap karakteristik material dari zeolit alam Sarulla (SNZ) dengan metode aktivasi basa telah dilakukan. Basa yang digunakan ialah NaOH dengan berbagai konsentrasi; 0,2 M; 0,5 M, dan 2 M. Katalis yang telah diaktivasi dengan basa kemudian dikarakterisasi dengan Analisis X-ray Fluorescence (XRF), X-ray diffractometer (XRD), Fourier-transform Infrared (FTIR) Spectroscopy, Scanning Electron Microscopy (SEM) dan Gas Adsorption menggunakan metode BET. Dari hasil penelitian, ditemukan perbedaan pada tingkat adsorpsi dan desorpsi, begitu juga dengan kristalinitas pada material katalis. Lebih jauh, rasio konten Si/Al juga berubah pada basa dengan konsentrasi terendah. Di sisi lain, tingkat kristalinitas dari katalis mengalami penurunan pada basa dengan konsentrasi tertinggi. Hasil ini diperkuat dengan data FTIR yang menunjukkan perubahan ikatan silanol menjadi silikat dan aluminat. Lebih jauh, analisis morfologi pada katalis menunjukkan bahwa permukaan yang homogen didapatkan dari penggunaan basa dengan konsentrasi rendah. Sebaliknya, basa dengan konsentrasi tinggi memberikan bentuk permukaan katalis yang tidak homogen serta kasar.
Mechanical and morphological characteristic investigations of deinked used newsprint paper via ultra-sonochemistry method SAHARMAN GEA; SRI RAHAYU; ANDRIAYANI ANDRIAYANI; AVERROES FAZLUR RAHMAN PILIANG; NONI OKTARI
Jurnal Natural Volume 20 Number 2, June 2020
Publisher : Universitas Syiah Kuala

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (561.913 KB) | DOI: 10.24815/jn.v20i2.16649

Abstract

Printed newspaper is one of the print-based media published daily in large quantities. The focus of this research is to remove the ink from used newsprint with alkaline treatment by using ultrasound sonochemistry method. Newsprint sheets collected were characterized by mechanical and morphology tests using FT-IR, XRD, tensile test and SEM. FT-IR spectra analysis shows the absorption of C=C functional groups as the main components of newspapers at 1427 and 1635 cm-1 wavelengths. The treatment with alkaline solution increased the mechanical strength properties of paper. SEM morphology analysis result shows that the surface of paper becomes more rough after ultrasound-alkaline treatment compared to paper without ultrasound treatment (conventional treatment). The crystallinity value decreased with alkaline treatment. The longer the ultrasound duration was, the lower the crystallinity degree became.
Enhancement Mechanical Properties of Simalambuo Wood (Loppophetalum spp) Delignified using NaOH in The Thermomechanical Densification Method Nur Azizah; Febri Sindika; Andriayani Andriayani; Saharman Gea
Jurnal Akademika Kimia Vol. 11 No. 4 (2022)
Publisher : Universitas Tadulako

Show Abstract | Download Original | Original Source | Check in Google Scholar

Abstract

One of the problems with fast-growing wood is the low density, which causes poor mechanical properties, so a densification process is carried out to increase the wood's density, surface hardness, and strength. In this study, the delignification process using NaOH was carried out at variations of 12.24, and 48 hours and then continued with the thermomechanical densification process. This study decreased lignin content in delignification simalambuo wood from 30% to 4%. The value of the Modulus of Rupture, Modulus of elasticity, and surface hardness increases with increasing immersion time during the delignification process. The highest values of Modulus of Rupture, Modulus of elasticity, and surface hardness were obtained by simalambuo wood soaked for 48 hours, namely, 2828.23 kg/cm2, 97.47 kg/cm2, and 256.73 kg/cm2.
Comparative Optimization of Cellulase and Laccase Enzymes in Deinking Process of Used Newspapers Saharman Gea; Noni Oktari; Andriayani Andriayani; Sri Rahayu; Averroes F Piliang
Jurnal Kimia Sains dan Aplikasi Vol 23, No 10 (2020): Volume 23 Issue 10 Year 2020
Publisher : Chemistry Department, Faculty of Sciences and Mathematics, Diponegoro University

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (2847.472 KB) | DOI: 10.14710/jksa.23.10.353-359

Abstract

The use of enzymes in the bio-deinking process of newspaper waste has promising potential. However, investigations on the concentration of enzyme combinations need to be carried out to obtain the optimum ratio of cellulase and laccase enzymes for the bio-deinking process of recycled newspapers. The mixture of the two enzymes at various ratios was used to remove the ink on paper pulp from used newspapers by mechanical disintegration method treatment and followed by the bio-deinking process in an incubator shaker. The characterization of functional groups, structures, and thermal properties of bio-deinked pulp paper was carried out by FTIR, XRD, DTG/TGA, and an analysis of the degree of brightness to the prepared paper. FTIR results confirmed three main components of papers, such as cellulose, hemicellulose, and lignin. The XRD results showed that the equal ratio of cellulase and laccase enzymes had an effect on a higher crystallinity index, which was 78.8% compared to those obtained from the conventional methods with a crystallinity index of 69.7%. Thermal analysis showed that the optimum combination of both enzymes contributed the most at the highest temperature where the rate of degradation decreased. Brightness analysis showed that bio-deinking had met the quality requirements for newsprint paper in SNI 7273:2008. Our findings show that the combination of cellulase and laccase enzymes at the same ratio can produce optimal bio-deinked pulp for paper fabrication with excellent characteristics in brightness, thermal, and physical properties.
Effect of Addition of Oleic Acid as a Template with Tetraethylorthosilicate (TEOS) as Source of Silica on Porosity Mesoporous Silica Material Andriayani; Claresta Ingrid Telambanua; Hamonangan Nainggolan
Journal of Chemical Natural Resources Vol. 5 No. 1 (2023): Journal of Chemical Natural Resources
Publisher : Talenta Publisher

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.32734/jcnar.v5i1.11993

Abstract

Mesoporous silica material has been synthesized using tetraethylorthosilicate (TEOS) as a source of silica, oleic acid as a template, and 3-aminopropyltrimethoxysilane (APMS) as co-structure directing agents (CSDA). The synthesis of silica material was made with a variation in the mole ratio of TEOS: Oleic acid with a ratio of 1: 0.2; 1: 0.3; 1: 0.5; 1: 0.6; 1: 0.7; 1: 0.9, and 1: 1. A mixture between TEOS and APMS was added to a mixture of oleic acid, HCl 0.1N and demineralized water then stirred at room temperature for 2 hours. Then aging, the mix at 80oC for 48 hours until solids are formed. Product separation was used in the centrifugation method. The resulting solid was dried at 50oC, and to remove the template, calcined at 550oC for 6 hours. The product of XRD analysis has a wider diffraction peak that indicates an amorphous material. The FT-IR spectrum shows the Si-OH and Si-O-Si groups which area characteristic of silica material. The product of SEM analysis offers the presence of sheets and plates of particle forms with different sizes. Adsorption desorption isotherm (BET) shows an isotherm type IV curve, and dominant pore sizes are 1.945 and 4.588 nm.
Training in the Manufacture of Softener Fragrance Aroma Therapy in Tembung Village, District Percut Sei Tuan Marpongahtun; Andriayani; Agung Pratama; Helmina br Sembiring; Aniza Salviana Prayugo; Amru Daulay
ABDIMAS TALENTA: Jurnal Pengabdian Kepada Masyarakat Vol. 8 No. 1 (2023): ABDIMAS TALENTA: Jurnal Pengabdian Kepada Masyarakat
Publisher : Talenta Publisher

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.32734/abdimastalenta.v8i1.10326

Abstract

Tembung Village, Percut Sei Tuan District, Deli Serdang Regency, North Sumatra Province, is a densely populated area. There are more than 200 laundry businesses. The potential for laundry business actors to produce softener and aromatherapy fabric softener has been hit very hard. However, the villagers, especially laundry business actors, do not know how to make these products. Making aromatherapy softeners independent will provide added value to the laundry business actors and villagers regarding economic costs and the transfer of knowledge of technology (science and technology commercialization). Therefore, the University of North Sumatra community service team wants to commercialize science and technology in making aroma softening therapy. The method used in this activity is the selection of partner locations, training, monitoring, and evaluation. The results of the questionnaire gave a value of 95% Participants were interested in training to produce aromatherapy softeners independently and took the initiative to make the results of this training a new opportunity.
Training on Creating a Simple Composter for Producing Liquid Organic Fertilizer from Household Waste M. Zulham Efendi Sinaga; Sovia Lenny; Andriayani; Cut Fatimah Zuhra; Suharman
ABDIMAS TALENTA: Jurnal Pengabdian Kepada Masyarakat Vol. 8 No. 2 (2023): ABDIMAS TALENTA: Jurnal Pengabdian Kepada Masyarakat
Publisher : Talenta Publisher

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.32734/abdimastalenta.v8i2.13917

Abstract

Fertilizer is the main needed for farmers to support agricultural products. However, the availability of chemical fertilizers in the market was once scarce due to its limited availability. To avoid dependence on the need for chemical fertilizers is to look for other alternatives as plant fertilizers. One alternative to chemical fertilizers is compost produced from organic waste. Compost fertilizer is available in several forms, namely solid fertilizer and liquid fertilizer. In this community service, training was conducted on making a simple composter to make organic fertilizer. The composter produced in this activity is very easy to do and made by partners because it comes from materials that are easily obtained around partners. The advantage of this composter is that it can produce both solid fertilizer and liquid fertilizer at the same time, but the concern of the service team is a liquid fertilizer because its use is more practical and easier for plants to absorb. During the training process, the partners were very enthusiastic about participating in the activity and asking questions related to composting. In this composter, the waste used is organic waste resulting from household waste which is placed at the top of the composter. Then the composter is closed and allowed to ferment by microorganisms. The results of organic liquid fertilizer can be accommodated at the bottom of the composter and then applied to plants in a ratio of 1:10.
Mechanical and morphological characteristic investigations of deinked used newsprint paper via ultra-sonochemistry method SAHARMAN GEA; SRI RAHAYU; ANDRIAYANI ANDRIAYANI; AVERROES FAZLUR RAHMAN PILIANG; NONI OKTARI
Jurnal Natural Volume 20 Number 2, June 2020
Publisher : Universitas Syiah Kuala

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.24815/jn.v20i2.16649

Abstract

Printed newspaper is one of the print-based media published daily in large quantities. The focus of this research is to remove the ink from used newsprint with alkaline treatment by using ultrasound sonochemistry method. Newsprint sheets collected were characterized by mechanical and morphology tests using FT-IR, XRD, tensile test and SEM. FT-IR spectra analysis shows the absorption of C=C functional groups as the main components of newspapers at 1427 and 1635 cm-1 wavelengths. The treatment with alkaline solution increased the mechanical strength properties of paper. SEM morphology analysis result shows that the surface of paper becomes more rough after ultrasound-alkaline treatment compared to paper without ultrasound treatment (conventional treatment). The crystallinity value decreased with alkaline treatment. The longer the ultrasound duration was, the lower the crystallinity degree became.
Co-Authors Agung Pratama Agus Haryono Ahmad Nasir Pulungan Amru Daulay Aniza Salviana Prayugo Averroes F Piliang AVERROES FAZLUR RAHMAN PILIANG Averrous Fazlurrahman Piliang Claresta Ingrid Telambanua Cut Fatimah Zuhra Dinda G. Ayu Febri Sindika Hadi Kurniawan Hadi Kurniawan, Hadi Hamonangan Nainggolan Herlince Sihotang, Herlince Hidayani, Ega Hutapea, Henny Dumarta Junifa Layla Sihombing Khatarina Meldawati Pasaribu M. Zulham Efendi Sinaga Maghfirah, Awan Marpongahtun Maulida Yanti Miranda, R.A. Fani MUHAMMAD TAUFIK Nofrijon Sofyan, Nofrijon Noni Oktari NONI OKTARI Nur Azizah Purwoko, Agus Rahayu Rahayu Raja, Saur Lumban Rizky Kurniawan Rizky Kurniawan Ronn Goei Saharman Gea Saharman Gea Saharman Gea Saharman Gea Saur L. Raja, Saur Saur Lumban Raja Sembiring, Helmina Br. Sovia Lenny Sri Rahayu SRI RAHAYU Suharman Tiamina Nasution Yasir Arafat Hutapea