Willy Cahya Nugraha, Willy Cahya
Lab. Nano Proses Dan Membran Lembaga Ilmu Pengetahuan Indonesia

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Adsorpsi Cu2+ Menggunakan Nanofiber Polisulfon-FeOOH Yang Disintesis Dengan Metode Elektrospinning Adam, Dini Hariyati; Suyani, Hamzar; Nasir, Muhamad; Safni, Safni; Nugraha, Willy Cahya
Jurnal Litbang Industri Vol 3, No 2 (2013)
Publisher : Institution for Industrial Research and Standardization of Industry - Padang

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (1725.154 KB) | DOI: 10.24960/jli.v3i2.629.101-108

Abstract

It had been done a research about adsorption of Cu2+ using polysulfone-FeOOH nanofiber prepared by elektrospinning method. Polysulfone-FeOOH nanofiber was synthesized by dissolving polysulfone pellets in 30 mL dimethylacetamide (DMAc). The effects of process conditions such as concentration, distance between the nozzle and collector, voltage and flow rate on the morphology and diameter of nanofibers were investigated. The optimum conditions of polysulfone nanofiber synthesizing was obtained with concentration 25%, distance 12 cm, voltage 25 kV, and flow rate  0.05 mL/min with average diameters of fibers was 762.927 nm. Polysulfone nanofiber was coated with FeOOH to increase the adsorbtion capacity of Cu2+. The results showed that optimum condition for removal of Cu2+ used polysulfone-FeOOH nanofiber was obtained in 2 hours contact time, pH 6, adsorbent dosage 25 mg, and concentration of Cu2+ 10 mg/L with adsorbstion capacity was 9.79 mg/g, while for polysulfone nanofiber the adsorption capacity was 8.34 mg/g. The adsorbtion pattern of Cu2+ by the both of adsorbent followed the Freundlich isotherm pattern.ABSTRAK Penelitian mengenai pemisahan ion Cu2+menggunakan nanofiber polisulfon-FeOOH yang disintesis dengan metode elektrospinning telah dilakukan. Nanofiber polisulfon P-3500 disintesis dengan cara melarutkan pelet polisulfon ke dalam 30 mL dimethylacetamide (DMAc). Pengaruh kondisi seperti konsentrasi, jarak nozzle dengan kolektor, tegangan dan laju alir terhadap morfologi dan diameter serat dipelajari. Kondisi optimum pembuatan nanofiber polisulfon diperoleh dengan konsentrasi 23 %, jarak 12 cm, tegangan 25 kV, dan laju alir 0,05 mL/min dengan ukuran diameter serat rata-rata 762,927 nm. Nanofiber yang terbentuk dilapisi dengan FeOOH untuk meningkatkan kapasitas penyerapannya terhadap ion Cu2+. Dari hasil penelitian didapatkan kondisi optimum untuk pemisahan ion Cu2+ menggunakan nanofiber polisulfon-FeOOH yaitu waktu kontak 2 jam, pH 6, bobot adsorben 25 mg, dan konsentrasi Cu2+10 mg/L dengan kapasitas penyerapan 9,79 mg/g, sedangkan untuk nanofiber polisulfon kapasitas penyerapan 8,34 mg/g. Pola penyerapan Cu2+ untuk kedua jenis adsorben lebih sesuai dengan pola isoterm Freundlich 
Traceable Value for Proficiency Test of Natural Gas Ridwan, Yohanes Susanto; Supriadi, Supriadi; Nugraha, Willy Cahya
Indonesian Journal of Science and Technology Vol 4, No 2 (2019): IJOST: VOLUME 4, ISSUE 2, 2019
Publisher : Universitas Pendidikan Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.17509/ijost.v4i2.18184

Abstract

The use of consensus values as the assign value for proficiency testing (PT) activities are currently a common practice in Indonesia, including the field of natural gas analysis. Hence, mostly the performance evaluation is based on consensus agreement. In this work, a PT was conducted using traceable values with respect  to ISO/IEC 17043 and ISO 13528. It was demonstrated that the chosen PT scheme has good capability to evaluate the performance of participating laboratories. And, in some cases, the selected PT scheme was not affected by extreme values and limited number of participants. Post analysis to the PT round has been conducted using the information of uncertainty of the traceable value and the uncertainty of robust average of participants’ results. It was demonstrated that there were no significance biases in the PT round. Moreover, it could be concluded that the participating laboratories have a good agreement with one to another. They also have a good agreement with traceable values, giving more additional confidence to the measurement quality in this field of analysis.
Zinc Oxide Nanoparticles for Enhancing Students’ View of the Nature of Science and Technology Priyand, Elza Rachman Panca; Sukmafitri, Ajeng; Mudzakir, Ahmad; Nandiyanto, Asep Bayu Dani; Nugraha, Willy Cahya; Ramdhani, Wahyu
Indonesian Journal of Science and Technology Vol 5, No 1 (2020): IJOST: VOLUME 5, ISSUE 1, 2020
Publisher : Universitas Pendidikan Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.17509/ijost.v5i1.22806

Abstract

This study aims to evaluate zinc oxide (ZnO) nanoparticles as a learning media to enhance students' understanding of View of Nature of Science and Technology (VNOST). The method used in this study: (i) understanding how to synthesize ZnO nanoparticles using a liquid-phase synthesis; (ii) implementation of ZnO nanoparticles to students and analysis their comprehension using Transcript Based Lesson Analysis (TBLA) on the Learning Video Recording and Adaptation Learning Transcript VNOST questionnaire, which is linked to the implementation and pattern of knowledge construction; and (iii) descriptive qualitative analysis to analyze the understanding of VNOST for each Category (Naïve, Has Merit and Realist). To support this study, several analyses were done, such as a scanning electron microscope and X-ray diffraction to characterize ZnO nanoparticles’ morphology and crystal structure, respectively, prior to giving this material for further learning to students. Experimental results showed that the use of ZnO nanoparticles is effective to improve the student comprehension. The understanding in the principle of nucleation and growth can be explained well since the reaction of ZnO is relatively fast. Students became more serious in listening during the learning process and more curious to study science and technology. Based on a comparative analysis of the initial and final ability of VNOST, it is proved that there was a change in students' views related to science and technology.
Identification of Heavy Metal Concentration in Citarum River Water Using the Heavy Metal Pollution Index Method Wardhani, Eka; Wulan, Diana Rahayuning; Velda, Nazla Amaliyah; Nugraha, Willy Cahya; Rohman, Oman; Irmansyah, Athaya Zahrani
Jurnal Presipitasi : Media Komunikasi dan Pengembangan Teknik Lingkungan Vol 21, No 3 (2024): November 2024
Publisher : Universitas Diponegoro

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.14710/presipitasi.v21i3.812-824

Abstract

The Citarum River is the largest and longest river in West Java Province. The basin in that location has influenced by human activities and the industrial sector. One of the hazardous pollutants contained in industrial wastewater is heavy metals. This study aims to identify the content of dissolved heavy metals (Fe, Cd, Cr, Cu, Hg, Pb, and Zn) in Citarum River water, Purwakarta Regency, at three observation points, namely Jatiluhur Reservoir Outlet, Cilalawak Bridge, and Cilele Bridge. The Atomic Absorption Spectrophotometry Method is used to analyze the dissolved heavy metals. Determination the level of metal contamination using the Heavy Metal Pollution Index (HPI) method. The study results that three metals exceeded the standard based on Government Regulation 22 of 2021 Class II, namely Fe, Hg, and Zn. Fe metal in the range between 0.277-1.179 mg/L, Hg metal between 0.011-0.100 mg/L, and Zn metal between 0.017-0.074 mg/L. HPI analysis showed that at three points in both sampling periods, it indicated that heavy metals highly polluted river water because the results obtained exceeded the HPI pollutant index, which was > 100. The biggest contribution of dissolved heavy metals in the Citarum River water body was dominated by the Hg parameter