Saviola, Aldino Javier
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Journal : Bulletin of Chemical Reaction Engineering

Performance of Hydrothermally Prepared NiMo Dispersed on Sulfated Zirconia Nano-Catalyst in The Conversion of Used Palm Cooking Oil into Jet Fuel Range Bio-Hydrocarbons Wijaya, Karna; Saviola, Aldino Javier; Amin, Amalia Kurnia; Vebryana, Marini Fairuz; Bhagaskara, Adyatma; Ekawati, Hilda Anggita; Ramadhani, Saffana; Saputra, Dita Adi; Agustanhakri, Agustanhakri
Bulletin of Chemical Reaction Engineering & Catalysis 2024: BCREC Volume 19 Issue 2 Year 2024 (August 2024)
Publisher : Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.9767/bcrec.20157

Abstract

Human efforts to overcome environmental problems from using fossil fuels continue, such as hydroconversion of biomass into bio-jet fuel. Research on producing a jet fuel range of bio-hydrocarbons from used palm cooking oil catalyzed by sulfated zirconia impregnated with nickel-molybdenum bimetal has been successfully conducted. The hydrothermal method synthesized the nano-catalyst material in the sulfation and impregnation processes. The hydroconversion process was carried out at atmospheric pressure and a temperature of 300–600 °C for 2 h with a hydrogen gas flow rate of 20 mL/min and a catalyst-to-feed ratio of 1:100 (wt%). Compared with zirconia and sulfated zirconia, NiMo-impregnated sulfated zirconia showed the best activity and selectivity in bio-jet fuel production with liquid product and selectivity of 61.07% and 43.49%, respectively. This catalyst also performed well in three consecutive runs, with bio-jet fuel selectivity in the second and third runs of 51.68% and 30.86%, respectively. Copyright © 2024 by Authors, Published by BCREC Publishing Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0).
Sonochemically Modified Lapindo Mud Using Sulfuric Acid for Efficient Adsorption of Phenol in Aqueous Media and Real Wastewater Samples Wijaya, Karna; Bhagaskara, Adyatma; Sani, Maria Francia Mirabella; Vebryana, Marini Fairuz; Pratama, Fernando Alvaro; Anggraeni, Widuri; Amin, Amalia Kurnia; Ramadhani, Faturrahman Al; Saviola, Aldino Javier
Bulletin of Chemical Reaction Engineering & Catalysis 2024: BCREC Volume 19 Issue 4 Year 2024 (December 2024)
Publisher : Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.9767/bcrec.20228

Abstract

Pharmaceutical industrial wastewater frequently contains high amounts of phenolic substances, which pose severe threats to the ecosystem and human health. Therefore, efficient removal of these pollutants is urgently needed. In the present work, sulfated Lapindo mud (SLM) was prepared using the sonochemical method and applied as an adsorbent for phenol removal in aqueous media and actual wastewater samples from Code River, Yogyakarta. Modification of Lapindo mud (LM) using sulfuric acid enables it to remove its impurities, resulting in a material containing 78.4% silica (SiO2) and 15.3% alumina (Al2O3). The SLM adsorbent demonstrated sufficient adsorption performance of 49.8% with an optimal initial phenol concentration of 120 mg/L with a contact time of 100 min at pH of 10. The maximum adsorption capacity (qmax) obtained by the Langmuir isotherm model was 27.2 mg/g. The adsorption process follows pseudo-second-order because it has two active sites, Brønsted acid sites (–SiOH and –SO3H) and Lewis acid sites (Si4+). Phenol in base condition undergoes a deprotonation reaction that is stabilized by the acid-active sites of the SLM adsorbent through intermolecular forces. Considering the large adsorption capacity and quick kinetic, the SLM adsorbent can be a promising cheap and green material to remove phenolic substances in wastewater, especially in the river near the medical facility. Copyright © 2024 by Authors, Published by BCREC Publishing Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0).
A Green and Sustainable Approach for Converting Laboratory Latex Glove Waste into Liquid Fuel via Microwave-assisted Pyrolysis Wangsa, Wangsa; Saviola, Aldino Javier; Hauli, Latifah; Trisunaryanti, Wega; Chandra, Patrik; Fitria, Riska Astin; Mahayuwati, Puspa Nindro; Wijaya, Karna
Bulletin of Chemical Reaction Engineering & Catalysis 2025: BCREC Volume 20 Issue 3 Year 2025 (October 2025)
Publisher : Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.9767/bcrec.20429

Abstract

The extensive use of chemical laboratories for experimental and research activities has resulted in the substantial accumulation of latex glove waste, a widely used form of personal protective equipment (PPE). This study presents a novel and sustainable approach for converting laboratory latex glove waste into liquid fuel using microwave-assisted pyrolysis (MAP), which aligns with the principles of green chemistry. Under optimal conditions, including a microwave power of 800 W and an irradiation time of 30 min, the process achieved a liquid product yield of 52.58 wt%, with 41.86 wt% consisting of gasoline-range hydrocarbons (C₅–C₁₂). The primary compound identified in the liquid product was D-limonene (C₁₀H₁₆), a valuable monocyclic terpene. Compared to conventional pyrolysis conducted in a semi-batch reactor, the MAP process exhibited superior performance in terms of liquid yield, gasoline-range hydrocarbon content, total hydrocarbon composition, and calorific value. This innovative waste-to-fuel conversion method demonstrates the strong potential of MAP as an efficient and environmentally responsible strategy for waste valorization and resource recovery. Copyright © 2025 by Authors, Published by BCREC Publishing Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0).