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Penentuan Kadar Karbon Organik pada Sampel Tanah Menggunakan Metode Walkley & Black Khusnah, Asma’ul; Pawestri, Niken; Utami, Maisari
INDONESIAN JOURNAL OF CHEMICAL RESEARCH Vol. 10 No. 2 (2025): Volume 10, ISSUE 2, 2025
Publisher : Chemistry Department, Universitas Islam Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.20885/ijcr.vol10.iss2.art2

Abstract

Determination of C-organic content in soil using the Walkley & Black method with a UV-Vis spectrophotometer was conducted at the Agricultural Instrument Standards Application Center in Yogyakarta. The samples used in this experiment were soil samples. The analysis method used was the Walkley & Black method with a UV-Vis spectrophotometer. This method works based on the principle of wet oxidation using potassium dichromate (K₂Cr₂O₇) and sulfuric acid (H₂SO₄), where the remaining unreacted dichromate ions are measured using a spectrophotometer at a wavelength of 587 nm. The analysis results showed that the organic C content in the five soil samples ranged from 1.096% to 3.866%, classified from low to high. The variation in organic C content was influenced by environmental factors such as depth, soil texture, and drainage conditions. This analysis is important for determining soil fertility levels and supporting sustainable agricultural land management.
Penetapan Fosfor Tersedia pada Sampel Tanah Menggunakan Metode Olsen & Bray I Nur Kholifah, Azzahra; Pawestri, Niken; Utami, Maisari
INDONESIAN JOURNAL OF CHEMICAL RESEARCH Vol. 10 No. 2 (2025): Volume 10, ISSUE 2, 2025
Publisher : Chemistry Department, Universitas Islam Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.20885/ijcr.vol10.iss2.art3

Abstract

Quantitative analysis was conducted on seven soil samples to determine available phosphorus (P), an essential macronutrient for plant growth and development. This study aimed to compare the effectiveness of two extraction methods, Olsen and Bray I, in measuring phosphorus availability in soils with different chemical characteristics, as well as to provide an overview of soil fertility levels based on the obtained results. The available P content was measured using the Olsen & Bray I methods with a single-beam UV-Visible spectrophotometer. Four soil samples (TH.2278, TH.2279, TH.2280, and TH.2281) were analyzed using the Olsen method, while three samples (TH.2267, TH.2268, and TH.2269) were analyzed using the Bray I method. Based on the Olsen method, samples TH.2278 and TH.2279 contained 34.8270 ppm and 50.5795 ppm P₂O₅, respectively, both classified as very high. In contrast, sample TH.2280 showed a concentration of 3.9325 ppm (very low category), and sample TH.2281 had 8.9920 ppm (low category). Using the Bray I method, sample TH.2267 contained 39.9138 ppm P₂O₅ (very high category), while TH.2268 and TH.2269 contained 1.7534 ppm and 5.3627 ppm, categorized as very low and low, respectively. Overall, three samples (TH.2278, TH.2279, and TH.2267) exhibited very high levels of available phosphorus, while samples TH.2280, TH.2281, TH.2268, and TH.2269 fell within the low to very low categories. These findings indicate that phosphorus availability is strongly influenced by soil chemical conditions, with the Olsen method being more suitable for neutral to alkaline soils and the Bray I method being more responsive to acidic soils. For soils with very high phosphorus levels, phosphate fertilization should be temporarily discontinued to prevent nutrient imbalance and environmental risks. Conversely, soils with low phosphorus levels require regular monitoring and periodic phosphate fertilization to maintain adequate soil fertility.