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Indonesian Journal of Chemistry

ijc
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Published by Universitas Gadjah Mada

ISSN : 14119420 EISSN : 24601578 DOI : -

Core Subject : Science, Engineering,

Chemical Engineering, Chemistry & Bioengineering Chemistry

Indonesian Journal of Chemistry is an International, peer-reviewed, open access journal that publishes original research articles, review articles, as well as short communication in all areas of chemistry including applied chemistry. The journal is accredited by The Ministry of Research, Technology and Higher Education (RISTEKDIKTI) No : 21/E/KPT/2018 (in First Rank) and indexed in Scopus since 2012. Since 2018 (Volume 18), Indonesian Journal of Chemistry publish four issues (numbers) annually (February, May, August and November).

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Articles 1,981 Documents

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EFFECT OF SCANDIUM ON HIDROGEN DISSOCIATION ENERGY AT MAGNESIUM SURFACE: AB INITIO DFT STUDY I Wayan Sutapa; Ria Armunanto; Karna Wijaya
Indonesian Journal of Chemistry Vol 10, No 2 (2010)
Publisher : Universitas Gadjah Mada

The dissociative chemisorption of hydrogen on both pure and Sc-incorporated Mg(0001) surfaces have been studied by ab initio density functional theory (DFT) calculation. The calculated dissociation energy of hydrogen molecule on a pure Mg(0001) surface (1.200 eV) is in good agreement with comparable theoretical studies. For the Sc-incorporated Mg(0001) surface, the activated barrier decreases to 0.780 eV due to the strong interaction between the molecular orbital of hydrogen and the d metal state of Sc. This could explain the experimentally observed improvement in absorption kinetics of hydrogen when transition metals have been introduced into the magnesium materials.

STUDY OF DOUBLE PROTONS MIGRATION MECHANISM IN SUPRAMOLECULAR STRUCTURES OF ACETIC ACID-WATER AND ACETIC ACID-AMMONIA BY AB INITIO METHOD Karna Wijaya; Iqmal Tahir; Harnowo Harnowo
Indonesian Journal of Chemistry Vol 3, No 2 (2003)
Publisher : Universitas Gadjah Mada

The theoretical study of double protons migration mechanism on acetic acid-water and acetic acid-ammonia associations has been carried out. The research covered determinations the reactant, transition state and product structures. To gain the goal, the research was conducted in three steps, i.e. (i) designing the reactant, transition state and product models, (ii) optimizing of structures, and (iii) calculating of their uncorrected total energy and frequencies with ab initio methods (basis set 6-31G**). All calculations were performed using Hyperchem ver 5.0 for Windows and Gaussian 94W package program. The computational study result showed that the calculated structures were in good agreement with the hypothetical structures.

THE ADDITION OF SOME COAGULANT AND VARIATION OF pH ON DEGRADATION OF TEXTILE WASTEWATER USING GAMMA RADIATION Agustin Sumartono; Winarti Andayani Lindu; Ermin K. Winarno
Indonesian Journal of Chemistry Vol 6, No 3 (2006)
Publisher : Universitas Gadjah Mada

The degradation and decolouration of textile waste water by gamma irradiation has been studied. Textile wastewater contain a mixture of dyes that difficult to degrade using conventional method, therefore it is necessary to find another method to degrade those dyes. Samples from effluent of textile industry were taken at certain time and have different in colour and condition. The addition of coagulant and radiation to remove the colour of the samples were demonstrated. Four kind of treatments were carried out in this experiment namely addition of coagulant, radiation, variation of pH and radiation, and combination of radiation with the addition of coagulant. The parameters examined were the change of spectra intensity, percentage of sedimentation after the addition of coagulant, and the percentage of the degradation. Combination of irradiation and the addition of coagulant induced decolouration and degradation of the waste.

EFFECT OF HIRA PROTEIN ON TRANSCRIPTIONAL REGULATIONS OF GENES IN VERTEBRATE CELLS Ahyar Ahmad
Indonesian Journal of Chemistry Vol 8, No 3 (2008)
Publisher : Universitas Gadjah Mada

For better understanding of DNA replicating-coupled chromatin assembly and transcription regulation in eukaryotes, we studied biochemical and genetic analysis of nuclear-related proteins from chicken DT40 cell lines. The genetic analysis of some nuclear proteins, such as HIRA and CAF-1, indicated that these proteins could play overlapping roles in chromatin dynamics and is consistent with the finding that HIRA protein exhibited binding ability to histones and ASF-1, as also ASF-1 bound directly with CAF-1p60. In this study, revealed not only that the N-terminal and C-terminal halves of HIRA mediate individually transcription repressions but also that even one of the seven WD dipeptide motifs and the LXXLL motif of HIRA are required for these mediations in vivo. Finally, we found that HIRA-mediated repression is sensitive to tricostatin TSA and it co-represses transcription together with HDAC-2. We believe our findings will contribute to a major break-through in future studies on the specific, individual roles of HIRA involved in numerous DNA-utilizing processes, through the formation and/or maintenance of the chromatin structure in vertebrate cells.

UTILIZATION OF MEMBRANE MICROFILTRATION IN PREPARATION OF HYDROLYZED VEGETABLE PROTEIN FROM FERMENTED RED BEAN (Phaseolus vulgaris L.) EXTRACT AS FORTIFICATION AGENT Sri Moerniati; Agustine Susilowati; Aspiyanto Aspiyanto
Indonesian Journal of Chemistry Vol 9, No 2 (2009)
Publisher : Universitas Gadjah Mada

Preparation of Hydrolyzed Vegetable Protein (HVP) as savory flavor from fermented red bean broth through stirred membrane cell using micro filtration membrane with pore size of 0.45 µm was performed to get fortified agent utilized in preparation of beans sauce. The objective of this work was to study an effect of pressure and kind of red bean broth extract on content of total protein, soluble protein and dry solid in the retentate and permeate as hydrolyzed vegetable protein used for fortified agent of red bean sauces. Preparation process of hydrolyzed vegetable protein was done using fixed rotary speed of 400 rpm, pressure of 20, 25 and 30 psi at room temperature. To investigate the effect of pressure on this separation, the feed were red bean broth extract fermented for 6, 8, 10 and 12 weeks, respectively. Fermentation process were conducted using salt fermentation with inoculum of Rhizopus-C1, salt and red bean ratios of 30:10:60%. The analysis of flux and contents of total protein, dissolved protein and dry solid in the retentate and permeate was carried out, and the result of experiment showed that interaction of Red bean broth extract with 6, 8, 10 and 12 weeks of fermentation and operation condition of microfiltration membrane separation tends to affect on flux and content of total protein, dissolved protein and dry solid in retentate and permeate. Red bean broth extract for 6 weeks fermentation resulted higher protein content in permeate as hydrolyzed vegetable protein than in retentate. Permeate at pressure of 25 psi gives flux value of 0.0217 mL/cm2.minute and contents of total protein of 1.31 %, dissolved protein of 6.9 mg/g, and dry solid of 2.6%, while retentate as hydrolyzed vegetable protein or fortified agent indicate contents of total protein of 1.52%, dissolved protein of 4.15 mg/g, and dry solid of 3.64%. It was found that micro filtration process was able to increase dissolved protein content of about 3 times.

EFFECT OF CROSSLINKING TO THE MECHANICAL PROPERTY OF APATITE GELATIN HYBRID FOR BONE SUBSTITUTION PURPOSES Sunarso Sunarso; Sutarno Sutarno; Kanji Tsuru; Ika Dewi Ana; Kunio Ishikawa
Indonesian Journal of Chemistry Vol 11, No 3 (2011)
Publisher : Universitas Gadjah Mada

The clinical success of current generation of synthetic bone substitute relies on bio-inspired design which has a performance level close to that of natural one. In this context, biomedical approaches are considered very important to result bio-functional hybrid for bone substitution purposes. In this study, effect of cross-linking to the mechanical properties of apatite gelatin hybrid has been investigated. Cross-linking was employed by 1-ethyl-3-3-dimethylaminopropyl carbodiimide (EDC) agent. The EDC agent creates a peptide bond between gelatin molecules inside the hybrid to the cross-linked structure. Cross-linked structure of gelatin increases physical property of the hybrid since it can hold the outer forces longer than that of without cross-linking.

CYTOTOXICITY IDENTIFICATION OF THE SUPERNATANT OF Manihot esculenta Crantz RHIZOME AS RIBOSOME-INACTIVATING PROTEIN TO NORMAL CELL Endang Astuti; Sabirin Matsjeh; Winarto Haryadi; Deni Pranowo; Nuning Sri Mulatsih
Indonesian Journal of Chemistry Vol 4, No 2 (2004)
Publisher : Universitas Gadjah Mada

The supernatant of Manihot esculenta Crantz rhizome has been used as an alternative remedy of infectious and cancer in Jogjakarta. Cytotoxicity assay showed that Manihot esculenta Crantz supernatant had cytotoxic effect to cancer cell line, namely Myeloma (LC50 = 180,24 μg/mL) and HeLa (LC50 = 415,55 μg/mL), but have a little cytotoxic effect to SiHa. This research was aimed to identify cytotoxic activity of Manihot esculenta Crantz's supernatant to normal cell, particularly to human mononuclear cell and Vero cell line, and to compare to the cancer cell lines. The result showed that supernatant of M. esculenta had cytotoxic effect to normal mononuclear cell (LC50 = 564,00 μg/mL) and Vero cell line (LC50 = 686,00 μg/mL). The supernatant of M. esculenta had the highest cytotoxic activity to myeloma and relatively toxic to cervix cancer HeLa and normal cell, but less to SiHa.

PHOTOSTABILITY OF BACTERIOCHLOROPHYLL a AND ITS DERIVATIVES AS POTENTIAL SENSITIZERS FOR PHOTODYNAMIC CANCER THERAPY: THE STUDY ON ACETONE-WATER AND METHANOL-WATER SOLVENTS Leenawaty Limantara; Heriyanto Heriyanto
Indonesian Journal of Chemistry Vol 11, No 2 (2011)
Publisher : Universitas Gadjah Mada

The determination of photostability for Mg-BChl a, Zn-BPheo a and Cu-BPheo a irradiated with red light (≥ 630 nm, 870 lux) and equilibrated with air for 20 min in acetone-water and methanol-water solvents at various percentages of water has been done. The presence of light and oxygen in the pigment solution cause the pigment instable. The pigment stability toward photooxidation is extremely influenced by solvent properties, including oxidation potential value and solvent abilities to form coordination and aggregate. Degradation products of pigment during irradiation treatment can be detected by increment of absorption at the absorption spectrum or occurrence of new positive absorption bands at the different absorption spectra. Cu-BPheo a is a promising photosensitizer based on its stability toward photooxidation in acetone-water solvents.

FERROELECTRIC PROPERTIES OF BaBi4Ti4O15 DOPED WITH Pb2+, Al3+, Ga3+, In3+, Ta5+ AURIVILLIUS PHASES Afifah Rosyidah; Djulia Onggo; Khairurrijal Khairurrijal; Ismunandar Ismunandar
Indonesian Journal of Chemistry Vol 9, No 3 (2009)
Publisher : Universitas Gadjah Mada

In recent years, the ferroelectric properties of aurivillius oxides have attracted interest and an extensive amount of work has been done toward the realization of their potential application in nonvolatile memories (FeRAM: ferroelectric random access memory). Recently, we have carried out computer simulation in atomic scale in order to predict the energies associated with the accommodation of aliovalent and isovalent dopants (Pb2+, Al3+, Ga3+, In3+, Ta5+) in the aurivillius structure of BaBi4Ti4O15. In this work, the predicted stable phases were synthesized using solid state reactions and their products then were characterized using powder X-ray diffraction method. The cell parameters were determined using Rietveld refinement in orthorhombic system with space group of A21am. Results from the ferroelectric properties measurement of BaBi4Ti4O15 were also presented. The cell parameters for BaBi4Ti4O15 doped with Pb2+, Al3+, Ga3+,In3+, Ta5+ were a = 5.47116(4) b = 5.45636(5) c = 41.8649(3) Å; a = 5.47104(4) b = 5.45634(4) c = 41.8640(3) Å; a = 5.47112(4) b = 5.45648(4) c = 41.8643(3) Å; a = 5.47111(4) b = 5.45645(5) c = 41.8649(3) Å; and a = 5.47134(4) b = 5.45588(4) c = 41.8639(5) Å. The ferroelectric properties measurement for BaBi4Ti4O15 doped with Pb2+, Al3+, Ga3+,In3+, Ta5+ showed that the Pr = 15.225 mC/cm2, Ec = 33.96 kV/cm; Pr = 15.925 mC/cm2, Ec = 35.724 kV/cm; Pr = 16.625 mC/cm2, Ec = 36.504 kV/cm; Pr = 15.57 mC/cm2, Ec = 32.925 kV/cm; Pr = 17.2827 mC/cm2, Ec = 37.44 kV/cm.

SPECTROPHOTOMETRIC DETERMINATION OF PYROCATHECOL AND PYROGALLOL BASED ON THEIR REDOX REACTION WITH IRON(III)/PHENANTHROLINE SYSTEM Mudasir Mudasir; Mugiyanti Mugiyanti; Ngatidjo Hadipranoto
Indonesian Journal of Chemistry Vol 2, No 3 (2002)
Publisher : Universitas Gadjah Mada

An analytical method for the spectrophotometric determination of some phenolic compounds, i.e.: pyrocathecol and pyrogallol based on their redox reaction with iron(III)-phenanthroline complex has been developed. These two compounds, in appropriate conditions, reduce iron(III)-phenanthroline complex to yield very stable and color-intense complex of iron(II)-phenanthroline, [Fe(phen)2]2+, whose concentration is equivalent to the amount of pyrocathecol or pyrogallol in the solution, and is easily detected by spectrophotometric method. Some parameters influencing the sensitivity of the determination were optimized. These included maximum absorption wavelength, pH of the solution, time and temperature of heatingand reagent to analyte minimum mole-ratio. Using the optimum conditions obtained, the analytical performance of the method was examined and the developed method was then applied to analyzed pyrocathecol and pyrogallol contents in several river water of Yogyakarta, Indonesia. Result of the study showed that the optimum conditions for the determination of pyrocathecol are as follows: maximum absorption wavelength (lmax) at 510 nm, pH of the solution = 4, heating time = 120 min, heating temperature = 70 0C and the minimum mole ratio of reagent to analyte is 8. On the other hand, the optimum conditions for the determination of pyrogallol are as follows: maximum absorption wavelength (lmax) at 510 nm, pH of the solution = 5, heating time = 90 min, heating temperature = 90 0C and the minimum mole ratio of reagent to analyte is 7. At the corresponding conditions of analysis, calibration curves for pyrocathecol and pyrogallol are linear in the range concentration of 0.00 - 0.16 ppm and 0.00 - 0.24 ppm, respectively. The correlation coefficients for both compounds were found to be higher than 0.998 and the detection limits went down below 0.07 ppm. It has been demonstrated that the developed method can be applied for the determination of pyrocathecol and pyrogallol contents in natural samples.

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