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Reaktor
Published by Universitas Diponegoro
ISSN : 08520798     EISSN : 24075973     DOI : https://doi.org/10.14710/reaktor.xx.x.xx-xx
Core Subject : Science, Engineering,
Chemical Engineering, Chemistry & Bioengineering Control & Systems Engineering Energy Materials Science & Nanotechnology
Reaktor invites contributions of original and novel fundamental research. Reaktor publishes scientific study/ research papers, industrial problem solving related to Chemical Engineering field as well as review papers. The journal presents paper dealing with the topic related to Chemical Engineering including: Transport Phenomena and Chemical Engineering Operating Unit Chemical Reaction Technique, Chemical Kinetics, and Catalysis Designing, Modeling, and Process Optimization Energy and Conversion Technology Thermodynamics Process System Engineering and products Particulate and emulsion technologies Membrane Technology Material Development Food Technology and Bioprocess Waste Treatment Technology
Arjuna Subject : Teknik (semua kategori) - Teknik (Lain-Lain)
Articles 527 Documents
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Preparation and Identification of Local Microorganisms (LMOs) using Lake Toba Water and Their Utilization for Plastic Biodegradation Lumbantoruan, Chintya Sinar; Misran, Erni; Masyithah, Zuhrina
Reaktor Volume 24 No.2 August 2024
Publisher : Department of Chemical Engineering, Faculty of Engineering, Universitas Diponegoro

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.14710/reaktor.24.2.41-51

Abstract

Local microorganisms (LMOs) are solutions made from anaerobic fermentation of sugar and complex carbohydrate sources using a local microorganism source medium. Generally, LMO solution possesses the potential to perform plastic biodegradation. This research aims to analyse the variation of the volume of Lake Toba water as a source of microorganisms in the preparation of LMO and to identify plastic degrading local microorganisms. The research steps consisted of making standard curves and growth curves, LMO preparation, testing the biodegradation of low-density polyethylene (LDPE) plastic, isolating microorganisms, performing biochemical test, testing the clear zone for plastic degrading microorganisms, and identifying microorganisms. LMO was made by mixing raw materials according to the ratio of Lake Toba water volume to substrate, namely 20:80 (% v/v); 30:70 (% v/v); and 40:60 (% v/v) which were fermented for 99 hours at 37 °C. The results showed that LMO pH before and after fermentation changed from 4.75; 4.9; and 4.94. to 3.46; 3.45; and 3.48. The decrease in pH was likely due to the activity of microorganisms that produce organic acids. The LDPE plastic degradation percentage of the resulting LMOs were 2.353% w/w; 3.012% w/w; and 4.023% w/w, respectively. For that reason, five microbe isolates obtained from fermentation of Lake Toba water volume to substrate ratio of 40:60 (% v/v) were further screened to validate their potential in degrading LDPE, which 2 isolates produced clear zones and identified as Staphylococcus aureus and Streptococcus sp.
Preparation of Zirconia Catalyst from Zircon Sand and Catalytic Testing for Biodiesel Production Widayat, Widayat; Almaas Salwa, Diah Ayu; Hasanah, Alfi; Nisa, Khoirun; Saudale, Jeanette Mutiara Paula
Reaktor Volume 24 No.2 August 2024
Publisher : Department of Chemical Engineering, Faculty of Engineering, Universitas Diponegoro

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.14710/reaktor.24.2.36-40

Abstract

Heterogeneous catalyst in biodiesel production was developed to overcome the disadvantages of using homogeneous catalyst in the process. Zircon catalysts were known to have amphoteric properties which were suitable for simultaneous esterification-transesterification process in biodiesel production. This study aims to investigate the effect of NaCl impregnated zirconia catalyst for biodiesel production through esterification-transesterification process. Wet impregnation method with varying NaCl weight (10-30% w/w) was used to synthesize the zircon catalyst. The synthesized catalyst was analyzed for its crystallinity and surface morphology using XRD and SEM respectively. The effect of catalyst weight (0.5-2.5% w/w) and operation temperature (50-70oC) to biodiesel product were also investigated. The biodiesel composition, density and viscosity were analyzed using GCMS analysis, picnometry and viscosimetry. The XRD and SEM results showed the synthesized zircon catalyst with 20% w/w NaCl loading had a tetragonal structure. The density, viscosity and free fatty acid content (FFA) of the biodiesel product decreased along with increasing catalyst weight, while the fatty acid methyl ester content (FAME) increased. The increasing FAME content was attributed to increasing active sites which accelerated the esterification-transesterification reaction process, yielding more biodiesel product.
Preparation and Characterization Of (ZnO-TiO2) nanoparticles and studying their effect of Photo degradation Ampicillin Al Jurdh, Maisam
Reaktor Volume 24 No.2 August 2024
Publisher : Department of Chemical Engineering, Faculty of Engineering, Universitas Diponegoro

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.14710/reaktor.24.2.52-57

Abstract

In this research, the photodegradation of the ampicillin antibiotic (AMP) in an aqueous solution was studied by using ZnO–TiO2 nanoparticles prepared via the wet incipient impregnation method with TiO2 and Zn(NO3)2⋅6H2O as precursor materials using three different ratios of both oxides (1:1, 0.5:1, 1:0.5). The effects of different molar ratios of the prepared nanoparticles and ultraviolet radiation from sun rays and a UV lamp were studied. We utilized SEM, XRD, and EDX characterization techniques to study the structural features and morphology of the nanoprepared oxide. The removal of the antibiotic ampicillin was studied using an ultraviolet device at a wavelength of 254 nm in the presence of oxide nanoparticles and two radiation sources. The removal rate was 98% when using a composite oxide (ZnO-TiO2) in a proportion of 0.5:1 and applying solar radiation.
Extraction of Scandium and Removal of Iron from Bauxite Residue using Hydrochloric Acid Solution with/without Addition of EDTA Sitorus, Berlian; Reva, Mincen; Syahbanu, Intan
Reaktor Volume 24 No.3 December 2024
Publisher : Department of Chemical Engineering, Faculty of Engineering, Universitas Diponegoro

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.14710/reaktor.24.3.76-81

Abstract

Scandium (Sc) is a strategic metal for its increasing demand for advanced materials applications. As a by-product of alumina production, bauxite residues possess a potential source of Sc. However, its high iron content hinders the Sc extraction efficiency. This study investigated the feasibility of Sc extraction from bauxite residue using hydrochloric acid (HCl) leaching process, with and without the addition of ethylenediaminetetraacetic acid (EDTA) as a chelating agent. Bauxite residue samples were characterized for their elemental composition using the X-ray fluorescence (XRF) spectroscopy. Subsequently, leaching experiments were conducted using 6M and 9M HCl solutions. The effect of EDTA on Sc extraction yield and iron dissolution was assessed. The XRF analysis revealed a significant iron content in the bauxite residue, confirming the need for effective iron removal. Hydrochloric acid was found to be effective in leaching iron (Fe) from bauxite residue, as confirmed by the high Fe content in the leachate, and a higher HCl concentration led to a higher Sc2O3 concentration in the residue. Although the addition of EDTA was effective in chelating iron, it also reduced Sc extraction efficiency. The leaching results suggested the use of 9M HCl without the addition of EDTA as the best leaching solution for Sc extraction, yielding a higher Sc recovery compared to extractions using 6M HCl and EDTA. These findings contribute to the understanding of Sc extraction from bauxite residue and provide valuable insights for developing efficient and sustainable recovery processes.
Heterogeneous Polypropylene-Based Cation-Exchange Membrane Modified by Functionalized Zinc Oxide Particles for Vanadium Redox Flow Battery Khoiruddin, Khoiruddin; Firmansyah, Rizky W.; Yulanda, Nanda; Wardani, Anita K.; Wenten, I Gede
Reaktor Volume 24 No.2 August 2024
Publisher : Department of Chemical Engineering, Faculty of Engineering, Universitas Diponegoro

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.14710/reaktor.24.2.58-67

Abstract

This work presents the synthesis and characterization of heterogeneous cation-exchange membranes based on polypropylene (PP) and cation-exchange resin (IER) powder, developed via melt spinning. The membranes were modified with zinc oxide (ZnO) nanoparticles functionalized with polydopamine (PDA) to enhance their electrochemical properties. The effects of varying IER content and ZnO/PDA loading on key membrane properties, including ion-exchange capacity (IEC), water uptake (WU), water contact angle (WCA), proton conductivity, water permeability, and vanadium permeability, were systematically investigated. The results demonstrated that increasing IER content improved proton conductivity and IEC, but also increased vanadium permeability. The PP/ZnO-PDA (Z-2.5) membrane, with 2.5%-wt. ZnO/PDA, showed reduced water permeability (0.46 L·m⁻²·h⁻¹·bar⁻¹) and vanadium permeability (5.67 × 10⁻⁵ cm² min⁻¹), while maintaining moderate proton conductivity (13.17 mS/cm). However, increasing ZnO/PDA content beyond 2.5%-wt. led to declines in WU, IEC, and proton conductivity, likely due to nanoparticle aggregation reducing access to ion-exchange sites.
Application of Vertical Flow Constructed Wetland for Organic Pollutant Removal from Petroleum Refinery Wastewater Lestari, Amelia Eka; Widiasa, I Nyoman
Reaktor Volume 24 No.2 August 2024
Publisher : Department of Chemical Engineering, Faculty of Engineering, Universitas Diponegoro

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.14710/reaktor.24.2.68-75

Abstract

This study examined the application of a pilot-scale Vertical Flow Constructed Wetland (VFCW) system for secondary oil refinery effluent treatment at PPSDM MIGAS, Indonesia. The VFCW technique, known for its simplicity, minimal operational cost, and environmental friendliness, was used to reduce organic pollutants (BOD and COD) to meet the standards and minimize pollutant levels. The system, constructed with a closed pond including gravel and sand substrates, and planted with Typha angustifolia, was evaluated under Hydraulic Retention Times (HRT) of 3, 4, and 5 days. The results showed BOD removal efficiencies of 52.9%, 54.4%, and 53.6%, and COD removal efficiencies of 35.7%, 49.1%, and 47.2% for hydraulic retention times of 3, 4, and 5 days, respectively. Statistical investigation (ANOVA) showed no significant difference (P > 0.05) in BOD removal efficiencies across HRTs and COD removal for 4 and 5 days. These findings implied diminishing benefits after 4 days for organic matter removal operations. The limited BOD and COD removal, in contrast to other investigations, was due to the short acclimatization time (7 days) for the Typha angustifolia to drive oxygen sufficiency and biofilm formation. These findings underlined the capability of the VFCW system to reduce wastewater contaminants sustainably and economically in tropical areas such as Indonesia. A 4-day HRT is recommended for practical applications in refinery wastewater treatment with pollutant loads up to complement. Extended acclimatization duration and improved operational settings are recommended to enhance the performance of the VFCW. This study illustrates the feasibility of VFCW as a scalable and environmentally sustainable solution for wastewater control in the petroleum industry sector. Keywords: VFCW, organic pollutants, retention time, removal efficiency, acclimatization.
Effect of Freeze-Drying Pre-treatment on the Properties of Activated Carbon Derived from Arabica Coffee Pulp Effendy, Ahmad Hidayat; Setiawan, Adi; Dewi, Rozanna; Hakim, Lukman; Hasibuan, Rizqon
Reaktor Volume 24 No.3 December 2024
Publisher : Department of Chemical Engineering, Faculty of Engineering, Universitas Diponegoro

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.14710/reaktor.24.3.82-93

Abstract

Activated carbon is a product that has many benefits since it has a high surface area and high fixed carbon content. Currently, there is still limited research that focuses on the use of coffee pulp biomass as raw material for activated carbon due to its natural properties which poses challanges. The aim of this research is to examine the influence of the pre-treatment process using the freeze-drying method on the properties of active carbon from coffee pulp waste. The best-activated carbon products can then be applied as energy storage materials. The steps taken in this study include stages (i) washing and soaking the raw materials; (ii) drying using the freeze-drying method; (iii) pyrolysis process; and (iv) activation process. Some samples were chemically activated using a KOH solution, some were physically activated using Nitrogen at a temperature of 800 °C, and the others were activated using a mixed chemical-physical method. The results of the activated carbon characteristic test show that samples dried using a freeze dryer have quite good thermal resistance with a surface morphology that has more pores. This is supported by functional group analysis which shows a reduction in unnecessary sample compounds. This research shows that freeze-drying pre-treatment affects the properties of activated carbon and indicates that the resulting activated carbon can be used as an energy storage material.
Effect of HPMC Concentration and Liquid Addition Method on granules properties using High-Shear Wet Granulator waleed, shahad qutaiba
Reaktor Volume 24 No.3 December 2024
Publisher : Department of Chemical Engineering, Faculty of Engineering, Universitas Diponegoro

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.14710/reaktor.24.3.102-108

Abstract

Enhancing the physical properties of medicinal powders is largely dependent on the granulation process. This study investigates how the concentration of hydroxypropyl methylcellulose (HPMC) and the liquid addition technique (pouring versus syringe) interact to affect the distribution of granule sizes and its porosity  in a high-shear mixer setup. Both a 5% HPMC solution and distilled water (0% HPMC) were used to granulate calcium carbonate powder. The results showed that while excessive liquid addition using the pouring method led to uneven growth and agglomeration, an increase in binder viscosity improved granule homogeneity. On the other hand, the syringe method provided more uniform granules, showing its effectiveness in achieving controlled nucleation and growth. The impact of these parameters on granule characteristics was further supported by the design of response surface plots and models made easier by statistical analysis using Design-Expert software. The study's findings provide important information for improving wet granulation methods in the manufacturing of pharmaceuticals, especially with regards to guaranteeing the stability and uniformity of the final product.
Synthesis of Poly(NIPAM) for Efficient Trypsin Purification Using Affinity Precipitation Technique Syaubari, Syaubari; Bachtiar, Dandi; Sabrina, Nur Irhamni; Adhi, M Furqan
Reaktor Volume 24 No.3 December 2024
Publisher : Department of Chemical Engineering, Faculty of Engineering, Universitas Diponegoro

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.14710/reaktor.24.3.109-115

Abstract

The method of bio specific affinity for separation has gained attention and continues to be developed today. The affinity precipitation technique is continuously being refined because it is simpler, less complex, and highly economical without reducing product purity. Moreover, the obtained polymers can be reused and easily scaled up. The polymer used for affinity precipitation has functional groups that can act specifically, making it known as a “smart polymer.” The hydrophilic polymer and soluble liquid can be replaced with hydrophobic ones, becoming insoluble under certain conditions such as changes in pH, temperature, ionic strength, or the addition of reagents. This study aims to utilize ligand pairs for soluble liquid polymers based on macro ligands that are easily developed for large-scale applications. The research was conducted in two stages and is ready for enzyme purification testing. First, the synthesis of NIPAM polymer was carried out, with NIPAM and AIBN as fixed variables, while MPA served as the variable. Second, PABA conjugation was performed, where the synthesized NIPAM polymer was conjugated with the PABA ligand, making PABA characterization the changing variable in this phase. The dry weight of carboxylated Poly(NIPAM) obtained was 91.3%, carboxylated Poly(NIPAM)-co MPA 0.4 was 90.4%, and carboxylated Poly(NIPAM)-co MPA 0.6 was 88.9%. In the SEM test, the morphological structure of Poly(NIPAM) showed relatively harder surfaces. In the FTIR test, a significant change was observed in the spectra at 3300-2500 cm-1, which became weaker due to the presence of carboxyl groups characterized in Poly(NIPAM). The spectrophotometer test revealed the LCST condition at a temperature of 40°C. The conjugation of PABA onto Poly(NIPAM)-co-MPA 0.6 with 50 mg PABA showed better conjugation efficiency, with a conjugation yield of 52.6%. Incorporation of PABA shows recovery of trypsin between 65-80 %.
Effect of Ni-Co Ratio on ZSM-5 Catalyst Performance in Palm Oil Hydrocracking for Biofuel Production Istadi, I.; Riyanto, Teguh; Permatasari, Astrid Eka; Dinara, Daniella Cipta
Reaktor Volume 25 No.1 April 2025
Publisher : Department of Chemical Engineering, Faculty of Engineering, Universitas Diponegoro

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.14710/reaktor.0.0.%p

Abstract

Biofuel derived from vegetable oil can be utilized as a vehicle fuel with various advantages, such as renewability, environmental friendliness, and sustainable availability. One of the methods for converting vegetable oil into biofuel is hydrocracking. This study investigates Ni-Co/ZSM-5 catalyst with Ni-Co metal ratios of 1:0.5, 1:1, and 1:1.5 to examine their effects on the catalyst characteristics and performance in the hydrocracking process of palm oil into biofuel. The catalyst synthesis was carried out using the co-impregnation method with ultrasound assistance, followed by characterization using XRD and XRF. The hydrocracking process was conducted at a temperature of 450℃ and a WHSV of 0.1 min-1, while the gas product was analyzed using GC and liquid product was distilled. XRF results showed that the actual Ni-Co ratio did not significantly differ from the designed ratio. XRD analysis indicated crystal agglomeration at a 1:1.5 ratio due to competition between Ni and Co metal particles diffusing into the zeolite pores, as well as the presence of dislocations and crystal defects. Differences in catalyst characteristics resulted in variations in yield, selectivity, and gas distribution in the hydrocracking process. The catalyst with a Ni-Co ratio of 1:1.5 exhibited the highest liquid product yield and biogasoline selectivity but also produced a higher concentration of CO, CO2, and C2 gases. It is associated with the breakdown of triglycerides into fatty acids, which subsequently fragment into shorter-chain biofuel components.

Page 52 of 53 | Total Record : 527

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