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Seminar Nasional Teknik Kimia Kejuangan
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Prosiding Seminar Nasional Teknik Kimia Kejuangan adalah media online dari makalah yang telah diseminarkan pada acara Seminar Nasional Teknik Kimia “Kejuangan” (SNTKK). SNTKK merupakan agenda tahunan yang diselenggarakan oleh Program Studi Teknik Kimia FTI UPN ”Veteran” Yogyakarta. Seminar ini merupakan sarana komunikasi bagi para peneliti dari perguruan tinggi, institusi pendidikan, serta lembaga penelitian maupun industri, dalam mengembangkan teknologi kimia untuk pengolahan sumber daya alam Indonesia.
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Alternatif Pra Rancangan Instalasi Pengolahan Air Limbah (Ipal) Industri Rumah Potong Hewan (Studi kasus rumah potong hewan Giwangan, Umbulharjo, Yogyakarta) Sri Hastutiningrum; Hadi Prasetyo Suseno; Anggita Ratnasari
Prosiding Seminar Nasional Teknik Kimia "Kejuangan" 2017: PROSIDING SNTKK
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The waste water treatment at slaughterhouse is very important as the effort for reducing the consentration of the waste water pollutant to the environment. The purpose of this study is to determine the system and design tocalculate the dimension of the waste water treatment plant (WWTP) in Giwangan slaughterhouse as a case study and to calculate its construction cost. The waste water treatment plant in Giwangan slaughterhouse use a biological treatment without standard operation. In the first stage, the research was conducted by calculating the water discharge and was tested the wastewater parameters (such as BOD, COD, TSS, N-Ammonia, Lipid and pH). After the data were collected, the system was determined. Then in the last stage, dimension and construction cost are calculated. The alternatives of pre redesign for Giwangan slaughterhouse WWTP system consist of bar screen, imhoff tank, preliminary sedimentation unit, anaerobic biofilter reactor, aerobic biofilter reactor, secondary sedimentation unit, bioindicator unit and sludge drying bed unit. The dimensions of these unit are imhoff tank (length = 4.6 m, width = 2.5 m, high = 4.0 m), preliminary sedimentation unit (length = 1.5 m, width = 1.3 m, high = 2.0 m), anaerobic biofilter reactor (length = 3.7; width = 2.0 m, high = 2.5 m), aerobic biofilter reactor (length = 2.0 m, width = 1.9 m, high = 2.5 m), secondary sedimentation unit (length = 1.0 m, width = 1.3 m, high = 1.0 m), bioindicator unit (length = 2.0 m, width = 1.5 m, high = 1.0 m) and 3 unit of sludge drying bed unit (length = 1.0 m, width = 1.0 m, high = 1.0 m). The total budget required for construction was Rp 717.129.718,10.
Pengaruh Jenis Ion Logam Berat Terhadap Daya Adsorpsi dan Desorpsi Thermosensitive NIPAM-co-DMAAPS Gel Eva Oktavia Ningrum; Toni Suharto; Agus Purwanto; Renna Febryanita; Muhammad Sai Firdaus; Sumarno Sumarno; Hikmatun Ni'mah
Prosiding Seminar Nasional Teknik Kimia "Kejuangan" 2017: PROSIDING SNTKK
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The development of industrial field causes increasing amount of heavy metal ions in the environment. A promising method to deal with the problem above is by utilizing reversible thermosensitive gel as an adsorbent to adsorb heavy metal ions in the environment. The purpose of this research is to develop a reversible thermosensitive gel that able to adsorb heavy metal ions from contaminated water. Copolymergel containing zwitterionic betaine N,N’-dimethyl(acrylamidopropyl) ammonium propane sulfonate (DMAAPS) and thermosensitive N-isopropylacrylamide (NIPAM) copolymer was employed as an adsorbent that able to adsorb and regenerate heavy metal ion in salt solutions. The effect of different ion in various salt solutions and temperature on the adsorption, desorption, and swelling degree of the gel were investigated in this research. The solution used in this experiment are Zn(NO3)2 and Pb(NO3)2 solutions. The gels were synthesized using free radical copolymerization. The synthesized gel showed higher adsorption and desorption ability in Pb(NO3)2 solution than that in Zn(NO3)2 solution. However, gel has a higher value of swelling degree in Zn(NO3)2 solution than that in Pb(NO3)2 solution. Other noticeable result is that swelling degree, desorption, and adsorption ability of the gels decreases in all solution as temperature rises.
Sintesis Bio-nanosurfaktan sebagai Deterjen Ramah Lingkungan dari Kombinasi Ekstrak Getah Pepaya (Carica papaya L) dan Daun Sengon (Paraserianthes falcataria L. Nielsen) Tunjung Wahyu Widayati; Hendri Yudisai; I K Gary Devara
Prosiding Seminar Nasional Teknik Kimia "Kejuangan" 2018: PROSIDING SNTKK 2018
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The purpose of this research is to study formulations Bio-Nano Surfactant by combining papaya sap, Sengon leaf, and HCl to obtain the most efficient concentration in neutralizing calcium oxalate, determine the effect of detergency by Bio-Nano Surfactant and determine the level of contamination by Bio-Nano Surfactant". Detergent formulations using completely randomized design (CRD) with two factors of HCl (0.1%, 0.15%, 0.2%, 0.4%, 0.6%) and papaya sap- sengon leafs concentration (10%, 20%, 30%). The indicator of this research is based on the best combination of parameters to decrease calcium oxalate, protease enzyme levels, and the highest detergency effectiveness in cleaning the substrat. After detergency test, combination of 10% papaya sap - Sengon leafs and 0.2% HCL comes as the best combination. For nanofication, the best sample split into two samples with and without PEG 4000 as nanoparticles template. The samples after nanofication has nano size orde which are the sample with PEG 4000 is smaller (458-686nm) than the sample without PEG 4000 (703-897nm). The detergency of nanoficated samples are higher than before. The results of contaminant level "Bio-Nano Surfactant" is 165.2 ppm for COD and 21.6 ppm for BOD which is lower than COD and BOD limits.
Kata Pengantar dan Daftar Makalah Editor prosiding sntkk 2017
Prosiding Seminar Nasional Teknik Kimia "Kejuangan" 2017: PROSIDING SNTKK
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Kata Pengantar dan Daftar Makalah
Pengaruh Komposisi Kulit Durian Dan Kulit Pisang Terhadap Nilai Kalor Sebagai Briket Bioarang Erlinda Ningsih; Yustia Wulandari Mirzayanti2; Mochamad Agil Yogi Parama
Prosiding Seminar Nasional Teknik Kimia "Kejuangan" 2017: PROSIDING SNTKK
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The wastes of durian and bananas peel are used as bio charcoal briquettes whis is the alternative of waste agriculture treatment. This technology can improve the economic value and be environmentally friendly. The aim of this study is to determine the particle size of mixture composition between bio charcoal briquettes, banana peel, and durian peel towards the calory of briquettes. The pyrolysis takes place on the temperature 3000C for 2.5 hours. Proximate analysis consist of water level test, the percentage of bio charcoal dust, and the calory of briquettes test. The result of this study can be concluded that the higher 5348.50 kkal/kg, was obtained by 80:10 of durian and banana peel ratio using 100 mesh of particle size. This results indicate that the higher composition of durian peel produces high the calory of briquettes and the lower particle size causes high the calory of briquettes.
Synthesis and Characterization of Superabsorbent Polymer (SAP) based on Starch and Acrylic Acid Trias Ayu Laksanawati; Adhitiyan Basuki; Maulana Ma'ruf; Prida Novarita Trisanti; Sumarno Sumarno
Prosiding Seminar Nasional Teknik Kimia "Kejuangan" 2018: PROSIDING SNTKK 2018
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Sintesis Senyawa Bioaromat Melalui Proses Siklisasi Katalitik Gugus Asam Lemak α-eleostearat Dalam Minyak Kemiri Sunan Vincensia Michelle; Tedi Hudaya; Tatang Hernas Soerawidjaja
Prosiding Seminar Nasional Teknik Kimia "Kejuangan" 2017: PROSIDING SNTKK
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Kemiri sunan oil (Reutalis trisperma) is a non-edible vegetable oils which thrives in Indonesia, has α-eleostearic acid that can be processed into aromatic compound through isomerization-cyclizationdisproportionation.The purpose of this research was knowing kemiri sunan oil’s potency for synthesizingaromatic compound and the effects of the reaction’s condition and solvent : feed ratio to the yield of cycliccompound. This research was initiated by testing kemiri sunan oil quality by several tests: acid number,iodine number, and saponification number. Saponification was done using KOH at 60°C ; 3 hours. Then,Mg(NO3)2 was added as substituent for K in base soap and Cr(NO3)3 as a catalyst. Obtained Mg soap wasthen cleaned using aquadest before dried in the oven until its mass was constant at 60°C, then diluted inDiethanolamine. The reaction was held for 2 hours with the variations of temperature and ratio of solvent :feed (w/w). The product was then extracted using toluene in order to gain all of the aromatic compound.Then, the separation of the solvent from the product was done using simple distillation. Cyclic productpresence in the form of ortho-disubstituted benzene was tested qualitatively using FTIR, while thequantitative tests were conducted by Wijs test and aromatic product’s mass calculation.
Separasi Steviosida dan Rebaudiosida A dari Crude Glikosida Daun SteviaRebaudiana Bertoni Menggunakan Resin Makropori Eko Indra Permana; Judy Retti Witono; Andy Chandra
Prosiding Seminar Nasional Teknik Kimia "Kejuangan" 2017: PROSIDING SNTKK
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Sugar consumption in Indonesia always increase every year. The increase of sugar demand cannot be fulfilled by the increase of sugar production. Low calories and low prices make food industry attracted to artificial sweeteners. The consumption of artificial sweeteners in excessive amount can lead to health problem. Stevia sweeteners can be used as the solution. The content of stevioside and rebaudioside A in stevia leaf make stevia sweeteners have a sweet taste, low calories and classified as safe. The purpose of this research is to determine the effect of stevia leaves type, separation method using resin, and dilution of stevia extract to separation rate (in %) of stevioside and rebaudioside A. Leaves types used in this research are stevia leaf cultivated in Unpar (leaf A) which is dried with microwave and leaf cultivated in Central Java (leaf B) which is dried with sunlight. Mass of Stevia leaves used is 10 grams. Separation methods that used are batch and continuous. Dilution of stevia’s extract used are 0, 5, 10, 25, and 50 times. Analysis performed in this research are total sugar analysis using anthrone method, analysis of stevioside and rebaudioside A content using HPLC, turbidity analysis using turbiditimeter, color analysis using colorimeter, and gravimetry analysis. The results showed that leaf A with batch method and 50 times dilution give the highest separation rate.
Aplikasi Teknologi Air Subkritis untuk Formasi Partikel Firman Kurniawansyah; A Roesyadi
Prosiding Seminar Nasional Teknik Kimia "Kejuangan" 2018: PROSIDING SNTKK 2018
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The Effect of pH to Drying Process of Colloidal Silica Using Flame Spray Combusto Sugeng Winardi; A. Y. Retnaningtyas; R. R. Hidayat; Lailatul Qomariyah; Widiyastuti Widiyastuti; Kusdianto Kusdianto
Prosiding Seminar Nasional Teknik Kimia "Kejuangan" 2017: PROSIDING SNTKK
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Spray drying widely applied in industry for drying the material because it has many advantages including capable to produce particle up to nanometer size, having a continuous process, and high purity. The method that we used in this research is Flame Spray Combustor. This research has the objective to synthesize particles of silica from waterglass and determine the effect of pH on particle silica produced. Analysis of SEM, XRD, and BET was conducted to determine the morphology, crystallinity, particle’s size, surface area and pore size of the silica particles produced. Morphology of silica is small spherical and has an amorphous structure. At pH 8 to 10 the size of silica particles increases with increasing pH, and at pH 11 the size decreases. The higher pH, the smaller surface area of silica particles produced. Meanwhile, the greater pH, the greater pore size of silica particles produced.