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IJFAC (Indonesian Journal of Fundamental and Applied Chemistry)
Published by Universitas Sriwijaya
ISSN : 25409395     EISSN : 25409409     DOI : -
Core Subject : Science, Social,
Indonesian Journal of Fundamental and Applied Chemistry (IJFAC) is an international research journal and invites contributions of original research articles as well as review articles in several areas of chemistry. The journal aims to publish refereed, high-quality research papers with significant novelty and short communications in all branches of chemistry. Papers which describe novel theory and its application to practice are welcome, as are those which illustrate the transfer of techniques from other disciplines. IJFAC calls for papers that cover the following fields: Biochemistry Inorganic chemistry Physical chemistry Organic chemistry Analytical chemistry Applied Chemistry All papers are peer reviewed by at least two referees. Papers presented at conferences are peer reviewed and selected with the same standards as individually submitted papers. They therefore have the same archival value. Article should be submitted by the Online Submission Module at www.ijfac.unsri.ac.id or email to ijfac@unsri.ac.id
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Articles 5 Documents
Search results for , issue "Vol 6, No 2 (2021): June 2021" : 5 Documents clear
Fixed-Bed Column for the Removal of Cd(II) from Aqueous by Hydroxyapatite from Red Snapper (Lutjanus campechanus) Fish Bone Widia Purwaningrum; Fahma Riyanti; Muhammad Said; Poedji Loekitowati Hariani; Aria Septi Handayani
IJFAC (Indonesian Journal of Fundamental and Applied Chemistry) Vol 6, No 2 (2021): June 2021
Publisher : IJFAC (Indonesian Journal of Fundamental and Applied Chemistry)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.24845/ijfac.v6.i2.46

Abstract

The Synthesis of hydroxyapatite from Red Snapper (Lutjanus campechanus) fish bone carried out. Hydroxyapatite is utilized for Cd(II) sorption from solution using a fixed-bed column. Hydroxyapatite was characterized using X-ray Diffraction, Fourier Transform Infra-Red, Scanning Electron Microscope-Electron Dispersive, and Thermogravimetric. In fixed-bed column, the influence of bed height (5, 10, 15 cm) and flow rate (6, 8 and 10 mL/min) were studied. The highest adsorption capacity is obtained at a bed height of 15 cm, and a flow rate of 6 mL/min with adsorption capacity is 47.027 mg/g. The predicted by Bed Depth Service Time (BDST) model obtained that value of R2 in the range 0.9964-0.9997. The adsorption capacity per unit volume ( is in the range 141.12-222.89 mg/L while  is in the range 0.0136-0.022 L/mg h. This indicates that BDST can be used to explain the performance of Cd(II) sorption onto hydroxyapatite by fix-bed column.
Waste-Cooking-Oil Free Fatty Acid Reduction Using Deep Eutectic Solvent as Raw Material of Biodiesel Mutiara Putri; Aida Syarif; Leila Kalsum
IJFAC (Indonesian Journal of Fundamental and Applied Chemistry) Vol 6, No 2 (2021): June 2021
Publisher : IJFAC (Indonesian Journal of Fundamental and Applied Chemistry)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.24845/ijfac.v6.i2.40

Abstract

The purpose of this study was to extract the free fatty acid (FFA) of waste-cooking-oil through liquid-to-liquid extraction using choline chloride as a raw material for Deep Eutectic Solvent (DES) as a waste-cooking-oil purifier. Waste-cooking-oil is obtained from the waste of a fast food factory located in Sukarame, South Sumatera. Making a Dep Eutectic Solvent (DES) using compounds of ethylene glycol as Hydrogen Bond Donor mixed with a choline chloride Hydrogen Bond Acceptor with five molar ratios, a reaction temperature of 60 °C and a stirring speed of 150 rpm and 200 rpm for 90 minutes. The extraction molar ratio of waste-cooking-oil and DES with four ratios of molar ratios, extraction time of 2 hours at 60 °C and retention time of separation between DES and used cooking oil was 24 hours. The decrease in FFA of waste-cooking-oil was the highest at 83.87% in the DES 2. Its proves that DES is able to purify waste-cooking-oil by extraction methods to reduce FFA and adsorb other materials
The Analysis of Manganese (Mn) in Waste Water Treatment (IPAL) of Coal Mine of PT Bukit Asam Indonesia Getari Kasmiarti; Rona Ayu Sakinah; Bambang Yudono
IJFAC (Indonesian Journal of Fundamental and Applied Chemistry) Vol 6, No 2 (2021): June 2021
Publisher : IJFAC (Indonesian Journal of Fundamental and Applied Chemistry)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.24845/ijfac.v6.i2.53

Abstract

Wastewater from the coal mining process containing heavy metal manganese is bad for water body and health of living things around it.  The South Sumatra Governor Regulation states that the content of iron (Fe) and manganese (Mn) must contain a maximum total of 7 mg/L and 4 mg/L before being released into the environment. This study aimed to verify the total dissolved Mn analysis method. Thirty-four (34) samples from the wastewater treatment plant pond were digested and measured by the Atomic Absorption Spectrophotometer (AAS) at a wavelength of 279.5 nm.  The analyzes performed were the precision, sensitivity, linearity, LOD detection limits and LOQ quantization limits. The measurement results showed the parameter value for a precision of 1.562%; linearity (coefficient of determination) standard curve 0.9939; sensitivity 0.0375; LOD 0.4287 g/mL; and LOQ 1.4291  g/mL. In conclusion, the measurement data for the total dissolved manganese met the quality standards for wastewater stated in the Regulation of the Governor of South Sumatra No.8 of 2012 by applying the predetermined method.
Hydrogen Adsorption/desorption on lithium Alanat Catalyzed by Ni/C for Sustainable Hydrogen Storage Icha Amelia; Dedi Rohendi; Addy Rachmat
IJFAC (Indonesian Journal of Fundamental and Applied Chemistry) Vol 6, No 2 (2021): June 2021
Publisher : IJFAC (Indonesian Journal of Fundamental and Applied Chemistry)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.24845/ijfac.v6.i2.59

Abstract

 LiAlH4 alloy has been believed to have the potential to become one of the hydrogen storages with high storage capacity. In this research, the formation of LiAlH4 alloys with dope and undope Ni/C catalysts and characterization and testing of hydrogen adsorption/desorption capacities using these alloys have been carried out. The alloy was made by the milling method and the resulting alloy was characterized using XRD analysis. The adsorption capacity test of the alloy was carried out by the gravimetric method at various pressures. The adsorption capacity of the LiAlH4 alloy by adding additives in the form of Ni/C as much as 5%w/w was proven to increase the hydrogen adsorption capacity compared to undope a catalyst with the highest storage capacity at a pressure of 3 bar of 13.06%w/w compared to undope a catalyst of 9.84%w/w at the same pressure. Meanwhile, the highest hydrogen desorption capacity was 53.56% w/w (dope catalyst) and 41.75% w/w (undope catalyst).
Characterization and Investigation on Photocatalytic Activities of TiO2/Coconut Shell-Based Activated Carbon Sheilatina Sheilatina; Surya Lubis; Fathurrahmi Fathurrahmi; Amalia Oktari
IJFAC (Indonesian Journal of Fundamental and Applied Chemistry) Vol 6, No 2 (2021): June 2021
Publisher : IJFAC (Indonesian Journal of Fundamental and Applied Chemistry)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.24845/ijfac.v6.i2.33

Abstract

Coconut shell-based activated carbon-supported TiO2 catalyst had been prepared with a sol-gel method using titanium tetraisopropoxide acting as TiO2 precursor. TiO2/activated carbon photocatalyst was characterized with X-Ray Diffraction (XRD), Fourier Transform-Infrared (FT-IR), Scanning Electron Microscopy-Energy Dispersive X-Ray (SEM-EDX), and surface area analysis using Brunauer–Emmett–Teller (BET) adsorption-desorption isotherm. Photocatalytic activities of TiO2/activated carbon were investigated through the degradation of indigo carmine using UV light. The highest degradation percentage (%D) obtained for the indigo carmine was 91.79% at pH 3 and an initial concentration of 5 mg L-1 after 25 min radiation. TiO2/activated carbon showed higher photocatalytic activities when sunlight was used, in comparison to that of UV light. 

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