Article Per Year (5 Year)
p-Index From 2020 - 2025
2.386
P-Index
This Author published in this journals
All Journal Jurnal Bahan Alam Terbarukan PROSIDING SEMINAR KIMIA JURNAL ATOMIK
Hiyahara, Irfan Ashari
Unknown Affiliation
Biochemistry, Genetics & Molecular Biology Chemical Engineering, Chemistry & Bioengineering Chemistry Energy Environmental Science Materials Science & Nanotechnology

Published : 14 Documents Claim Missing Document
Claim Missing Document
Check
Articles

Found 14 Documents
Search

 1   2 
Preparation of Dye-Sensitized Solar Cell (DSSC) Using TiO2 and Mahkota Dewa Fruit (Phaleria Macrocarpa (Scheff) Boerl.) Extract Hindryawati, Noor; Hiyahara, Irfan Ashari; Saputra, Herdian; Arief, M. Syaiful; Maniam, Gaanty Pragas
Jurnal Bahan Alam Terbarukan Vol 10, No 1 (2021): June 2021 [Nationally Accredited - SINTA 2]
Publisher : Universitas Negeri Semarang

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.15294/jbat.v10i1.32378

Abstract

A dye sensitized solar cell (DSSC) is a low-cost solar cell with attractive features. DSCC contains of photoelectrode, dye, electrolyte, and counter electrode with photoelectrochemical system. The aim of this research is to determine the percent efficiency produced by DSSC from the Mahkota Dewa extract. This was carried out in various stages, namely sample preparation and extraction, DSSC assembly, TiO2 characterization using Scanning Electron Microscopy (SEM), and testing its current and voltage. The results showed that the maximum wavelength of the Mahkota Dewa extract dye test using a UV-Vis spectrophotometer was 554 nm with an absorbance of 0.163, which was believed to be the wavelength of flavonoid and anthocyanin compounds. Based on the characterization results, surface morphology was spherical and agglomerated. However, after being soaked in the dye, the surface morphology of the TiO2 layer did not appear spherical on the surface that was expected to have been covered by the dye. The measurement using sunlight sources showed that the maximum current and voltage of DSSC with a concentration of 30% w/v was 21.8x10-4A and 58.86 V with an efficiency of 22.43x10-3 %. In addition, there was a 0.482% decrease in DSSC efficiency based on the storage time which lasted for a period of 6 days.
Preparation of Dye-Sensitized Solar Cell (DSSC) Using TiO2 and Mahkota Dewa Fruit (Phaleria Macrocarpa (Scheff) Boerl.) Extract Hindryawati, Noor; Hiyahara, Irfan Ashari; Saputra, Herdian; Arief, M. Syaiful; Maniam, Gaanty Pragas
Jurnal Bahan Alam Terbarukan Vol 10, No 1 (2021): June 2021 [Nationally Accredited - Sinta 2]
Publisher : Universitas Negeri Semarang

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.15294/jbat.v10i1.32378

Abstract

A dye sensitized solar cell (DSSC) is a low-cost solar cell with attractive features. DSCC contains of photoelectrode, dye, electrolyte, and counter electrode with photoelectrochemical system. The aim of this research is to determine the percent efficiency produced by DSSC from the Mahkota Dewa extract. This was carried out in various stages, namely sample preparation and extraction, DSSC assembly, TiO2 characterization using Scanning Electron Microscopy (SEM), and testing its current and voltage. The results showed that the maximum wavelength of the Mahkota Dewa extract dye test using a UV-Vis spectrophotometer was 554 nm with an absorbance of 0.163, which was believed to be the wavelength of flavonoid and anthocyanin compounds. Based on the characterization results, surface morphology was spherical and agglomerated. However, after being soaked in the dye, the surface morphology of the TiO2 layer did not appear spherical on the surface that was expected to have been covered by the dye. The measurement using sunlight sources showed that the maximum current and voltage of DSSC with a concentration of 30% w/v was 21.8x10-4A and 58.86 V with an efficiency of 22.43x10-3 %. In addition, there was a 0.482% decrease in DSSC efficiency based on the storage time which lasted for a period of 6 days.
REVIEW ARTICLE: UTILIZATION OF VARIOUS OF ADSORBENT FROM ACTIVATED CHARCOAL IN INCREASING THE QUALITY OF COOKING OIL Hasriani, Hasriani; Sitorus, Saibun; Hiyahara, Irfan Ashari
PROSIDING SEMINAR KIMIA Vol 2 No 1 (2023): Prosiding SNK 2023
Publisher : Jurusan Kimia Fakultas Matematika dan Ilmu Pengetahuan Alam Universitas Mulawarman

Show Abstract | Download Original | Original Source | Check in Google Scholar

Abstract

Cooking oil is a type of vegetable oil derived from palm plants that has gone through various refining processes. Generally, cooking oil is used repeatedly at high temperatures until the oil is unfit for consumption This results in a decrease in the quality and nutritional value of fried food. In addition, the accumulation of used cooking oil (used cooking oil) can cause environmental pollution. Improving the quality and nutritional value of cooking oil can be done by using the adsorption method. The adsorption method is a method that is carried out by using a number of adsorbents from activated charcoal in the process of refining used cooking oil. Adsorbents from activated charcoal can be made from basic ingredients of agricultural waste such as activated charcoal from coconut shells, corn cobs, snack fruit and others. The adsorbent of activated charcoal can reduce the levels of fatty acids, water content, peroxide levels and acid numbers. The internal adsorption capacity depends on the different adsorbent types, contact time, amount of adsorbent, surface area and structure of the adsorbent and adsorbate concentration. Keywords: Adsorbent, Activated Charcoal, Adsorption Capacity, Used Cooking Oil
MINI REVIEW: FOTOKATALISIS NANOPARTIKEL CaO TERHADAP ZAT WARNA ORGANIK SINTETIK Salsabila, Aidilia Putri; Hiyahara, Irfan Ashari; Syaima, Husna
PROSIDING SEMINAR KIMIA Vol 2 No 2 (2024): Prosiding SNKT III 2023
Publisher : Jurusan Kimia Fakultas Matematika dan Ilmu Pengetahuan Alam Universitas Mulawarman

Show Abstract | Download Original | Original Source | Check in Google Scholar

Abstract

Nanoparticles of CaO (CaO-NP) are currently a frequently used material in research due to their excellent catalytic and antibacterial activities, low toxicity, abundant availability, and relatively affordable manufacturing cost. One of their applications is as a photocatalyst, commonly employed to degrade organic materials such as dyes. This review discusses the utilization of CaO nanoparticles as photocatalysts for both cationic and anionic organic dyes. Literature results indicate that CaO-NP can serve as a catalyst in the photocatalysis of dyes, whether they are cationic or anionic. The percentage of degradation achieved varies, ranging from as low as 60% to as high as 99.21%. These varying results are attributed to the different parameters used in the diverse photocatalysis processes. Keywords: CaO Nanoparticle, Organic Dye, Photocatalysis
SYNTHESIS OF SILVER NANOPARTICLES USING BIOREDUCTORS: MINI REVIEW Indriani, Isah Waliah; Hindryawati, Noor; Hiyahara, Irfan Ashari
PROSIDING SEMINAR KIMIA Vol 2 No 1 (2023): Prosiding SNK 2023
Publisher : Jurusan Kimia Fakultas Matematika dan Ilmu Pengetahuan Alam Universitas Mulawarman

Show Abstract | Download Original | Original Source | Check in Google Scholar

Abstract

Synthesis of silver nanoparticles can be carried out using bioreductors which are natural reducing agents from natural materials containing antioxidant compounds or polyols which can reduce silver due to the nucleophilic nature of phenolic compounds in plant secondary metabolites. The use of bioreductors in the manufacture of nanoparticles can reduce the adverse effects and hazardous waste generated due to reduced adsorption of the toxic properties of the solvent used. The content of organic compounds in bioreductors can be utilized, for example secondary metabolites such as terpenoids, flavonoids and tannins which act as antioxidants and capping agents, where Ag+ ions in AgNO3 can be reduced into silver nanoparticles, so bioreductors can replace the role of synthetic reducing agents. Based on the literature used, several plants whose extracts can be used as bioreductors, namely gambier, gotu kola leaves, water hyacinth leaves, bilimbi leaves, cempedak bark and bay leaves using variations in the concentration and composition of the AgNO3 solution. The results of silver nanoparticles were synthesized using bioreductors, namely various nano-sized particles and based on UV-Vis spectrophotometry data, silver nanoparticles appeared at wavelengths between 410 - 450 nm. Keywords: Secondary metabolites, Bioreductors, Silver Nanoparticles
MINI REVIEW: SINTESIS DAN KARAKTERISASI NANOPARTIKEL CaO DARI CANGKANG TELUR MENGGUNAKAN METODE KALSINASI Zahra, Marinda Afifatu; Hiyahara, Irfan Ashari; Syaima, Husna
PROSIDING SEMINAR KIMIA Vol 2 No 2 (2024): Prosiding SNKT III 2023
Publisher : Jurusan Kimia Fakultas Matematika dan Ilmu Pengetahuan Alam Universitas Mulawarman

Show Abstract | Download Original | Original Source | Check in Google Scholar

Abstract

This review article aims to collect, compare and analyze the latest research on the synthesis and characterization of CaO nanoparticles from eggshells. CaO is a material in the form of white crystalline solids made from thermal decomposition of limestone or shells, which contains CaCO3 which has the potential to become CaO nanoparticles to be applied in various fields. Currently, various methods have been carried out to synthesize these materials, such as precipitation methods, hydrothermal methods, sol-gel methods, and so on. One of them is the calcination method. The calcination method itself is a commonly used thermal processing method involving heating at high temperatures. The advantages of the calcination method are that it is efficient, has a high level of purity, is economical and relatively simple and others. However, the calcination method itself has disadvantages, namely the process time is quite long, must be careful and can have a negative impact on the environment. In this review, we will discuss the synthesis of CaO nanoparticles characterized using X-Ray Diffraction (XRD), Fourier Transform InfraRed (FTIR), Scanning Electron Microscope (SEM), Transmission Electron Microscope (TEM). The literature results show that in XRD the main peak 2θ positions are 111 and 200 and the crystal size is 10-55 nm, in FTIR the functional groups that appear are the Ca-O stretch group and C-O stretch vibrations, in SEM and TEM the shape of the crystal. Keywords: Synthesis, CaO nanoparticles, Calcination
Green Synthesis Of Silver Nanoparticles Using Ketapang Leaf Extract (Terminalia Catappa L.) Assisted By Ultrasound Syaima, Husna; Hindryawati, Noor; Hiyahara, Irfan Ashari; Wirawan, Teguh; Arief, M. Syaiful; Widodo, Nanang Tri; Ahmad, Atika Aulia; Maniam, Gaanty Pragas
Jurnal Bahan Alam Terbarukan Vol 12, No 2 (2023): December 2023 [Nationally Accredited Sinta 2]
Publisher : Universitas Negeri Semarang

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.15294/jbat.v12i2.48809

Abstract

Green synthesis of silver nanoparticles using plants has been interesting in recent years. In the present study, the silver nanoparticles were synthesized using a bioreductor from ketapang leaf extract (Terminalia catappa L.) assisted by sonochemical methods. This green synthesis provides an economic, eco-friendly, and clean synthesis route for silver nanoparticles. Different concentrations of AgNO3 precursors (0.5; 1.0 and 1.5 mM) were initially reacted with ketapang leaf extract with PVA 1% solution as stabilizers that were sonicated for 30 minutes. Silver nanoparticle colloidal solutions were characterized using UV-Vis spectrophotometers, Particle Size Analyzers (PSA), and Transmission Electron Microscopes (TEM). Maximum absorption of silver nanoparticles was obtained at wavelength 420-450 nm. Based on UV data, the silver nanoparticles showed stability for up to 3 weeks. The XRD peaks indicated that the (111) crystallographic plane was more predominant than other planes. The average size of the silver nanoparticles was 79.7 nm from the PSA result. TEM imaging depicted that the nanoparticles were spherical. Finally, the result proved that the silver nanoparticles effectively removed the methylene blue up to 76.43% within optimum conditions (3 ppm of methylene blue, 15 minutes contact time, and 8% nanoparticle concentration).
Mini Review: Citrus sinensis Sebagai Bioreduktor Dalam Green Synthesis Nanopartikel Hiyahara, Irfan Ashari; Hindryawati, Noor; Syaima, Husna; Akbar, Muhammad Marion; Duratulhikmah, Nur Fadhilah; Putra, Narundana Perdana; Wulandari, Siti Aprilia; Larasati, Zarra Udyani; Rahayuningsih, Rahayuningsih; Indriani, Isah Waliah
JURNAL ATOMIK Vol 8 No 1 (2023)
Publisher : Jurusan Kimia FMIPA UNMUL

Show Abstract | Download Original | Original Source | Check in Google Scholar

Abstract

Green synthesis is an eco-friendly approach that provides a viable alternative to traditional physical and chemical methods for the production of nanoparticles. This technique employs non-toxic and safe materials, such as plants, microorganisms, algae, bacteria, yeast, and fungi, to generate stable and less toxic nanoparticles. Citrus sinensis, commonly known as sweet orange, is a plant that contains various active compounds. These bioactive compounds can be extracted and used as bioreductants in green synthesis of nanoparticles. This mini review aimed to provide an overview of the current state of research on the utilization of Citrus sinensis as a bioreductant in the production of nanoparticles. A systematic search strategy was employed to identify research articles that met the criteria of discussing green synthesis of nanoparticles with Citrus sinensis as a bioreductant. The nanoparticles produced using Citrus sinensis extract can be either metal nanoparticles or metal oxide nanoparticles. The review highlights the distribution of nanoparticles produced with Citrus sinensis extract, their applications, and the extraction process of Citrus sinensis commonly employed in green synthesis of nanoparticles. Hopefully this review serves as a useful reference for researchers and practitioners who are interested in employing the Citrus sinensis plant as a bioreductant in the green synthesis of nanoparticles.
SINTESIS ASETIL ASKORBAT MELALUI ASETILASI TANPA PELARUT DAN KATALIS Nurhidayah, Annisa; Daniel, Daniel; Hiyahara, Irfan Ashari
JURNAL ATOMIK Vol 6 No 2 (2021)
Publisher : Jurusan Kimia FMIPA UNMUL

Show Abstract | Download Original | Original Source | Check in Google Scholar

Abstract

ABSTRACT The preparation of acetyl ascorbate by acetylation without solvent and catalyst has been carried out. The preparation of acetyl ascorbate is carried out by reacting ascorbic acid with anhydrous acetic acid using a 1:1 mole ratio without solvent and catalyst. The acetylation reaction was carried out using the reflux method at 700C for 5 hours. The result of acetyl ascorbate acetylation is a yellow powder with a yield percentage of 71.8182%. The functional groups of the synthesized compound in the form of acetyl ascorbate were analyzed using a FT-IR spectrophotometer. The FT-IR analysis results show the functional groups OH, CH sp3, C=C, C=O ester and C-O-C ester. Based on these results it can be seen that acetyl ascorbate has been formed.
ANALISIS NILAI TOTAL SULFUR (TS) DAN CALORIFIC VALUE (CV) DALAM BATUBARA MENGGUNAKAN METODE AMRERICAN STANDARD TESTING AND MATERIAL (ASTM) DI PT GEOSERVICES SAMARINDA KALIMANTAN TIMUR Novianti, Rina Lia; Sitorus, Saibun; Hiyahara, Irfan Ashari
PROSIDING SEMINAR KIMIA Vol 3 No 1 (2024): Prosiding SNK 2024
Publisher : Jurusan Kimia Fakultas Matematika dan Ilmu Pengetahuan Alam Universitas Mulawarman

Show Abstract | Download Original | Original Source | Check in Google Scholar

Abstract

Coal is a crucial energy source with varying quality levels. It is formed by the accumulation of organic sediments mixed with carbon, resulting from the diagenesis process of plant elements. This study aims to determine the Total Sulfur (TS) and Calorific Value (CV) of coal, which are essential factors in assessing coal quality and economic value. The American Standard Testing and Material (ASTM) method is employed to ensure consistency and standardization in the analysis. From an analysis of six samples, the total sulfur content was determined to be 1.98% for sample A, 1.88% for sample B, 2.06% for sample C, 0.14% for sample D, 0.70% for sample E and 0.18% for sample F. Additionally, the calorific value were determined to be 6267 Cal/g for sample A, 6126 Cal/g for sample B, 6234 Cal/g for sample C, 5189 Cal/g for sample D, 4986 Cal/g for sample E and 3917 Cal/g for sample F. Based on the total sulphur analysis sample D, sample E and sample F can be used in the cement burning process because their total sulphur content is less than 0.8%. Meanwhile, based on the calorific value analysis sample A, sample B and sample C can be used the cement burning process because their calorific value above 6000 Cal/g. Keywords : Coal, total sulphur, calorific value, American Standard Testing and Material.
Co-Authors Ahmad, Atika Aulia Akbar, Muhammad Marion Arief, M. Syaiful Bergita, Angela Daniel Daniel Duratulhikmah, Nur Fadhilah Gaanty Pragas Maniam, Gaanty Pragas Hasriani Hasriani, Hasriani Husna Syaima Indriani, Isah Waliah Larasati, Zarra Udyani Nanang Tri Widodo Noor Hindryawati, Noor Novianti, Rina Lia Nurhidayah, Annisa Putra, Narundana Perdana Rahayuningsih Rahayuningsih, Rahayuningsih Rahman, Kamaulana Adi Saibun Sitorus Salsabila, Aidilia Putri Sapira, Putri Abelia Saputra, Herdian Sari, Nadia Fellinda Wanda Solly Aryza Teguh Wirawan, Teguh Wulandari, Siti Aprilia Zahra, Marinda Afifatu