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Isolasi dan Karakterisasi Silika Dari Diatom Laut Ambon Navicula sp. TAD Menggunakan Variasi Larutan Asam Telussa, Ivon; Bandjar, Adriani; Baranyanan, Muhamad Faisal Adriyansah
JC-T (Journal Cis-Trans): Jurnal Kimia dan Terapannya Vol 7, No 2 (2023)
Publisher : State University of Malang or Universitas Negeri Malang (UM)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.17977/um0260v7i22023p016

Abstract

Diatom merupakan mikroalga yang memiliki dinding sel terbuat dari silika dengan pori-pori berukuran nano yang dikenal sebagai frustula. Silika dapat diaplikasi diberbagai bidang, antara lain yaitu penggunaan silika sebagai matriks katalis untuk pemurnian dan pemisahan zat, adsorpsi logam berat, biosensor maupun penghantar obat maupun fotokatalis. Penelitian ini bertujuan untuk mengisolasi dan mengkarakaterisasi silika melalui pencucian dengan larutan asam dari diatom perairan teluk Ambon dalam, yaitu Navicula sp. Kultivasi sel Navicula sp. TAD dilakukan untuk mendapatkan biomassa dikultivasi dalam medium modifikasi selama 7 hari. Pemanenan diperoleh Biomassa basah Navicula sp. TAD sebanyak 90,799 g dengan produktivitas biomassa basah adalah sebesar 1,090 g ml-1 hari-1. Isolasi silika dari biomassa Navicula sp. TAD dilakukan melalui pencucian asam nitrat, asam klorida, dan asam sulfat diperoleh silika -berturut-turut sebesar 7,650± 0,071, 4,550 ± 0,35, dan 6,800 ± 0,707 g. Karakteristik silika dikarakterisasi dengan SEM/EDX menunjukkan struktur nanopori dari permukaan biosilika frustul dapat terlihat jelas dan tersusun atas silikon dan oksigen yang menandakan bahwa biosilika telah dimurnikan dari pengontor-pengotor organik. Gugus fungsi karakteristik kimia silika diidentifikasi dengan spektroskopi inframerah transformasi fourier pada bilangan gelombang 1631, 1083, 960, 806, dan 462 cm-1 yang masing-masing berkorespondensi dengan gugus vibrasi tekuk dan ulur dari ikatan Si-O-Si.
The Utilitasion of Beef Tallow Into Biodiesel With Heterogenous Catalyst Bandjar, Adriani; Sutapa, I Wayan; Rosmawaty, Rosmawaty; Mahulau, Nurlina
Indonesian Journal of Chemical Research Vol 2 No 1 (2014): Edisi Bulan Juli (Edition For July)
Publisher : Jurusan Kimia, Fakultas Sains dan Teknologi, Universitas Pattimura

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.30598/ijcr.2014.2-adr

Abstract

The research of utilitasion of beef tallow into biodiesel with heterogenous (CaO) catalyst has been conducted. Biodiesel production initially by esterification reaction with catalyst H2SO4 1% (toward oil and methanol weight) with molar ratio oil : methanol (1:9). After esterification process, trygliceride separated from methanol and continued by transesterification step with molar ratio 1:12 (oils and methanol) and CaO catalyst 11% wt. Esterification and transesterification process carried out for 2 hours and 6 hours respectively at 65 ℃. Composition of the biodiesel was analyzed by 1HNMR, Gas Chromatography-Mass Spectrometry (GC-MS) and their physical properties analyzed by ASTM method. Result of biodiesel conversion is 93.99% while based on GC-MS analysis showed that mayor component of biodiesel were mixture of methyl esters with methyl octadecanoat as the major coumpound (40.65%). Based on data from ASTM, biodiesel produced from beef tallow have qualified as diesel fuel.
Kinetic Parameters Determination Of Glucoamylase On Hydrolysis Reaction Of Sagoo Starch (Metroxylon sp) Bandjar, Adriani; Tanasale, Matheis F.J.D.P.; Luhukay, Maher S.
Indonesian Journal of Chemical Research Vol 2 No 2 (2015): Edisi Bulan Januari (Edition For January)
Publisher : Jurusan Kimia, Fakultas Sains dan Teknologi, Universitas Pattimura

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.30598/ijcr.2015.2-adr

Abstract

Sagoo plant (Metroxylon sp.) numerous in eastern Indonesia, such as Maluku and Papua. Sagoo starch containing amylose and amylopectin. Sagoo starch hydrolysis can be carried out by enzymes, such as glucoamylase or often called amiloglukosidase or α-1 ,4-glukanoglukohidrolase, an extracellular enzyme capable hydrolyzes α-1, 4 on amylose and α-1, 6 in amylopectin. The enzymatic hydrolysis of starch can be reviewed in the kinetics of the Michaelis-Menten equation and Lineweaver-Burk equation. The aims of this study to determine the kinetic parameters (Vmax and Km) of glucoamylase on hydrolysis of sagoo starch. Glucoamylase has an optimum temperature of 50 oC and pH optimum 6.5. At optimum conditions, based on Michaelis-Menten equation, the value of Vmax is 1.09 U/mL/min and Km value is 0.82. Based on Lineweaver-Burk equation, the value of Vmax was 1.03 U/ mL/min and Km value was 0.84%.
Optimation Transesterification Reaction Conditions on Biodiesel Production From Beef Tallow Rosmawaty, Rosmawaty; Bandjar, Adriani; Gunoroso, Suntoro
Indonesian Journal of Chemical Research Vol 2 No 2 (2015): Edisi Bulan Januari (Edition For January)
Publisher : Jurusan Kimia, Fakultas Sains dan Teknologi, Universitas Pattimura

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.30598/ijcr.2015.2-ros

Abstract

Biodiesel synthesis has been done from beef tallow through two step, esterification and transesterification reactions. Esterification process is done by using H2SO4 1M as a catalyst, methanol 1:9, temperature of 60-65°C, and for 3 hours. After separated between methanol and trigyceride, then proceed to the process of transesterification. To obtain the optimum reaction conditions then used some transesterification process variables, there are: the weight percentage catalyst of KOH between 0.1, 0.5, 1; 1.5, and 2%, the reaction time of 1-5 hours and the reaction temperature between 50 -70 oC. Optimum conditions of transesterification reaction for the synthesis of biodiesel derived from beef tallow with KOH catalyst is as follows: the weight percentage of 1% KOH catalyst, the reaction time of 3 hours and the reaction temperature of 65 oC. The results of physical testing of biodiesel fuel by ASTM method includes specific density of 0.8675 g/cm3, kinematic viscosity of 4.971 mm2/s, flash point of 134.5°C, pour point of 27°C, the Conradson carbon residue of 0.018%, and the copper corrosion-pieces of 1B.
Isolasi Kitosan Dari Tudung Jamur Merang (Vollvariella Volvaceae) Dan Aplikasinya Sebagai Absorben Logam Timbal (Pb) Tanasale, Matheis F.J.D.P.; Bandjar, Adriani; Sewit, Natasya
Indonesian Journal of Chemical Research Vol 6 No 1 (2018): Edisi Bulan Juli (Edition For July)
Publisher : Jurusan Kimia, Fakultas Sains dan Teknologi, Universitas Pattimura

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.30598/ijcr.2018.6-mat

Abstract

Chitosan isolated from mushroom (Vollariella volvaceae) as adsorbent of lead (Pb) metal has been done. The isolation of chitosan was obtained 2.94% from total weight of mushroom. Fungtional groups of chitin and chitosan were indentified by using FTIR spectrophotometry. The chitosan had 74.66% degree of deacetylation and 2.09 x 104 g/mol viscosity molecular weight. The experimental data of the chitosan as adsorbent for Pb metal were correlated with the Langmuir and Freundlich isotherm model. The maximum adsorption capacity of Pb based on the Langmuir isotherm model was 2.66 mg/g.
Isoterm Adsorpsi Ion Cr(III) Oleh Kitosan Hasil Isolasi Limbah Kepiting Rajungan dan Kitosan Komersil Rahayu, Rahayu; Tanasale, Matheis F.J.D.P.; Bandjar, Adriani
Indonesian Journal of Chemical Research Vol 8 No 1 (2020): Edisi Bulan Mei (Edition for May)
Publisher : Jurusan Kimia, Fakultas Sains dan Teknologi, Universitas Pattimura

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.30598/ijcr.2020.8-ayu

Abstract

The chitin isolation from crab Rajungan (Portunus sanginolentus) and commercial chitin was done. The chitosan was made by deasetilation of chitin using alkaline solution with addition NaBH4. The chitin and chitosan were identified by related instrument. The identification by adsorption Cr(III) ion on chitosan was done by the Atomic Absorption Spectrofotometry. The result of the chitosan isolation was fitted to the Freundlisch isotherm, with KF = 1.18673 mg/g and 1/n= 0.2712.
Phytochemical Tests and Antioxidant Activities of the Rhips Ginger (Zingiber Officinale Var Amarum.) Hasanela, Nurani; Bandjar, Adriani; Yanyaan, Virenze K.; Hitijahubessy, Hendro
Indonesian Journal of Chemical Research Vol 11 No 2 (2023): Edition for September 2023
Publisher : Jurusan Kimia, Fakultas Sains dan Teknologi, Universitas Pattimura

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.30598//ijcr.2023.11-nur

Abstract

Ginger is a traditional plant that thrives and has essential functions, including an antioxidant. This study aimed to determine the phytochemical content and test the antioxidant activity of fresh white ginger and powdered ginger (Zingiber officinale var. Amarum.). Two methods are used in this research: the phytochemical test and the antioxidant activity test using DPPH. Phytochemical tests, such as flavonoid, phenolic, steroid, and saponin, were conducted qualitatively. The antioxidant activity test was carried out using a UV-Vis spectrophotometer. Fresh white ginger and powdered ginger were extracted using the maceration method with water solvent. The study results showed that the effects of fresh white ginger extract obtained a yield of 64.08%. Meanwhile, powdered ginger extract was 58.68%. Phytochemical test results of fresh white ginger extract and powdered ginger (commercial) showed positive results for flavonoid, phenolic, and saponin compounds while adverse effects for steroids. Antioxidant activity test on fresh white ginger extract with water solvent showed an IC50 value of 25.41 ppm. The powdered ginger extract (commercial) has an IC50 value of 36.70 ppm. The results showed fresh white ginger and powdered ginger had relatively high antioxidant activity.
Isolation of Na-alginate from Brown Seaweed (Padina sp.) and Synthesis of Na-alginate-chitosan Polyelectrolytecomplex (PEC) Film as Methylene Blue Adsorbent Rahayu, Rahayu; Bandjar, Adriani; Nurlete, Samsul; Sohilait, Mario Rowan; Baunsele, Anselmus Boy
Indonesian Journal of Chemical Research Vol 12 No 2 (2024): Edition for September 2024
Publisher : Jurusan Kimia, Fakultas Sains dan Teknologi, Universitas Pattimura

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.30598/ijcr.2024.12-rah

Abstract

Na-alginate has been isolated from brown seaweed (Padina sp.) and then used to make na-alginate-chitosan complex polyelectrolyte films as methylene blue adsorbent. Characteristics of na-alginate, chitosan, and PEC films before and after adsorption were carried out using an FT-IR spectrophotometer. Na-alginate-chitosan PEC film was made by mixing a 0.3% (w/v) Na-alginate solution with a 1% (w/v) chitosan solution with a chitosan-alginate volume ratio (1:3). The film formed was tested for its resistance in pH 3-11 for 7 days and showed that the film could survive in acidic or alkaline media. The adsorption study carried out resulted in maximum concentration data occurring at 75 mg/L with a capacity of 30.2768 mg/g.
Pembuatan Kecap sebagai Bahan Tambahan Makanan dari Limbah Air Kelapa di Negeri Kilang Rahayu, Rahayu; Fransina, Eirene Grace; Bandjar, Adriani; Pattiasina, Priska Marisa; Gaspersz, Nelson
Innovation for Community Service Journal Vol 1 No 1 (2023): April 2023
Publisher : Department of Chemistry

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.30598/icsj.v1i1.8503

Abstract

Provinsi Maluku adalah provinsi kepulauan yang memiliki banyak desa yang secara geografis berada di pinggiran pantai. Negeri Kilang merupakan salah satu desa di Pulau Ambon, Sumber penghasilan rata-rata keluarga warga desa ini adalah nelayan dan petani. Salah satu tanaman yang dihasilkan masyarakat Kilang adalah tanaman kelapa. Sebagai bentuk pengabdian masyarakat yang merupakan bagian dari tugas Tri Dharma Perguruan Tinggi maka perlu adanya pemberian informasi berupa inovasi untuk memanfaatkan air kelapa menjadi sesuatu produk yang bermanfaat dan turut dapat menjadi sumber perekonomian yang dapat meningkatkan pendapatan masyarakat desa dalam bentuk pengabdian masyarakat. Hal ini dapat dilakukan dengan pelatihan yang ditujukan kepada masyarakat Negeri Kilang untuk dapat memanfaatkan air kelapa tersebut menjadi barang yang bernilai ekonomi. Limbah air kelapa yang dihasilkan tersebut dapat dijadikan bahan tambahan makanan sebagai penambah rasa atau bumbu pada makanan yakni kecap.
Inovasi Pengolahan Limbah Air Kelapa menjadi Cuka Kelapa sebagai Upaya Peningkatan Ekonomi Lokal di Desa Oma, Pulau Haruku, Maluku Tengah Gaspersz, Nelson; Male, Yusthinus Tobias; Bandjar, Adriani; Sekewael, Serly Jolanda; Fransina, Eirene Grace; Sohilait, Stephanie Pascal
Innovation for Community Service Journal Vol 3 No 2 (2025): Oktober 2025
Publisher : Department of Chemistry

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.30598/icsj.v3i2.22895

Abstract

Maluku memiliki potensi sumber daya alam yang melimpah, salah satunya kelapa yang banyak tumbuh di wilayah pesisir seperti Desa Oma, Kecamatan Pulau Haruku, Kabupaten Maluku Tengah. Selama ini, masyarakat hanya memanfaatkan daging buah kelapa untuk konsumsi rumah tangga, sedangkan air kelapa sering dibuang sebagai limbah. Padahal, air kelapa mengandung karbohidrat yang dapat diolah menjadi produk bernilai ekonomi seperti cuka kelapa melalui proses fermentasi. Kegiatan pengabdian kepada masyarakat ini bertujuan untuk memberdayakan masyarakat Desa Oma, khususnya kelompok ibu-ibu PKK, dalam meningkatkan nilai ekonomis limbah air kelapa melalui pelatihan pembuatan cuka kelapa dengan teknologi tepat guna. Metode pelaksanaan meliputi penyuluhan, diskusi kelompok (FGD), serta pelatihan teknis pembuatan cuka kelapa dengan fermentasi anaerob menggunakan ragi dan urea (food grade). Hasil kegiatan menunjukkan peningkatan pengetahuan dan keterampilan masyarakat dalam mengolah air kelapa menjadi produk cuka siap pakai dan bernilai jual. Produk yang dihasilkan dikemas dalam botol berlabel sebagai produk unggulan lokal. Kegiatan ini tidak hanya mendukung pengurangan limbah organik, tetapi juga membuka peluang ekonomi baru bagi masyarakat Desa Oma melalui penerapan konsep ekonomi sirkular berbasis potensi lokal.