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Zulfansyah
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Automotive Engineering Biochemistry, Genetics & Molecular Biology Chemical Engineering, Chemistry & Bioengineering Civil Engineering, Building, Construction & Architecture Electrical & Electronics Engineering Engineering Industrial & Manufacturing Engineering Materials Science & Nanotechnology Mechanical Engineering

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UNJUK KERJA NaOH DALAM MEREDUKSI LOGAM BERAT PADA LIMBAH ABU BOILER Sembiring, Maria Peratenta; Sri Irianty, Rozanna; Zulfansyah; Chairul
JURNAL KIMIA SAINTEK DAN PENDIDIKAN Vol. 8 No. 1 (2024): JURNAL KIMIA SAINTEK DAN PENDIDIKAN
Publisher : Program Studi Kimia - Universitas Sari Mutiara Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.51544/kimia.v8i1.4950

Abstract

Proses pembakaran batu bara menghasilkan emisi berupa gas SO2, NO2, CO, CO2, volatile hydrocarbon (VHC), suspended particulate matter (SPM), serta residu padat berupa abu boiler. Abu boiler mengandung berbagai logam berat beracun, diantaranya tembaga (Cu), kobalt (Co), kromium (Cr), cadmium (Cd) dan timbal (Pb). Penelitian ini bertujuan untuk menentukan efisiensi reduksi logam berat Cu, Co, Cr, Pb, dan total dengan melakukan ekstraksi menggunakan pelarut kimia NaOH dan mengubah logam transisi menjadi kompleks dengan Ethylene diamine tetraacetic acid (EDTA) pada rasio EDTA: abu boiler sebesar 1:2, 1:1, 2:1; durasi pengadukan sebesar 2 dan 4 jam; serta suhu ekstraksi sebesar 25 dan 60 oC. Analisis Inductively Coupled Plasma (ICP) dilakukan untuk mengetahui penurunan kadar logam berat dari ekstrak abu boiler. Hasil penelitian menunjukkan bahwa kondisi ekstraksi berupa rasio EDTA: abu boiler sebesar 2:1, durasi pengadukan sebesar 4 jam, dan suhu ekstraksi sebesar 60 oC dapat menghasilkan persentase penurunan kadar logam berat total tertinggi yang mencapai 77,2% dengan persentase penurunan kadar Co, Cr, Cu, dan Pb secara berturut-turut sebesar 75,4%, 77,9%, 74,5%, dan 81,9%. Penelitian ini diharapkan dapat menjadi rekomendasi bagi penelitian selanjutnya dalam mengeksplor potensi pemanfaatan abu boiler yaitu sebagai bahan campuran aspal, pembuatan batako, dan sebagainya.
Potensi Tandan Kosong Sawit sebagai Bahan Bakar Padat: Analisis Degradasi Termal Maarasyid, Cici; Idayu, Ida; Zulfansyah; Israyandi; Legawati, Lisa; Ermal, Dini Aulia Sari; Rawadi, Raihan; Olivia, Cindy; Fitri, Suchy Arum; Aderiani, Suci
SURYA TEKNIKA Vol 10 No 2 (2023): JURNAL SURYA TEKNIKA
Publisher : Fakultas Teknik UMRI

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.37859/jst.v10i2.6422

Abstract

The availability of oil palm empty fruit bunches in Indonesia could be an important source of biomass to be utilized as a solid fuel feedstock. In this work, the thermal behavior and degradation of oil palm emty fruit bunches was investigated with a thermogravimetric analyzer in nitrogen atmosphere. The samples were heated from room temperature to 900 oC at heating rates of 20 oC min-1. The ultimate and proximate analysis revealed that oil palm empty fruit bunches contains high volatile matter, fixed carbon and ash content while the caliric value was 17.87 MJ/kg. Thermogravic analysis results indicated thermal degradation of samples occurs in three stages, namely drying and evaporation, active degradation and passive degradation. In addition, active degradation commenced at 148 oC with a peak of degradation temperature of 322.5 oC resulting in 68.32% weight loss.
Perancangan dan Pembuatan Program Simulasi Kesetimbangan Termodinamika untuk Proses Gasifikasi Biomassa Rionaldo, Hari; Zulfansyah; Mazlani
Jurnal Teknik: Media Pengembangan Ilmu dan Aplikasi Teknik Vol 20 No 1 (2021): Jurnal Teknik - Media Pengembangan Ilmu dan Aplikasi Teknik
Publisher : Fakultas Teknik - Universitas Jenderal Achmad Yani

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.26874/jt.vol20no1.416

Abstract

The non-stoichiometric thermodynamic equilibrium simulation program for the biomass gasification process was developed using the Python programming language. It is featured with a GUI (Graphical Users Interface), to facilitate user interaction. The program is designed to calculate the composition of gas producer with 6 components involved, they are CH4, CO, CO2, H2, N2, and H2O. The design of computational algorithms for calculating non-stoichiometric thermochemical equilibrium models is converted into Python code. The GUI consists of input and output facilities in form of tables and graphs of calculation results. The input facility is designed in such a way that the user can vary the gasification temperature and the equivalent ratio. The calculation results of the simulation program are verified with the calculated data manually to ensure that there are no errors in the algorithm or writing program code. It is also compared with the experimental data from previous studies to see the accuracy of the thermodynamic model in predicting the composition of gas producer. The non-stoichiometric thermodynamic equilibrium simulation program for the biomass gasification process can predict the composition of producer gas with a fairly good level of accuracy and can be used as a learning medium in studying thermodynamic equilibrium.
Co-Authors Aderiani, Suci Chairul Cici Maarasyid Dini Aulia Sari Ermal Fitri, Suchy Arum Hari Rionaldo Idayu, Ida Israyandi Israyandi Lisa Legawati Maria Peratenta Mazlani Olivia, Cindy Rawadi, Raihan Rozanna Sri Irianty