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Journal : Aceh International Journal of Science and Technology

Electrochemistry Study on PVC-LiClO4 Polymer Electrolyte Supported by Bengkulu Natural Bentonite for Lithium Battery Ghufira Ghufira; Sal P Yudha; Eka Angasa; Jhoni Ariesta
Aceh International Journal of Science and Technology Vol 1, No 1 (2012): April 2012
Publisher : Graduate Program of Syiah Kuala University

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (1621.461 KB) | DOI: 10.13170/aijst.1.1.13

Abstract

Abstract – In this research bentonite was used as filler to produce polymer electrolyte (PVCLiClO4). Some weight variation of bentonite have been made by addition, such as 0% wt/wt; 5% wt/wt ; 10% wt/wt ; 15% wt/wt ; 20% wt/wt ; and 25% wt/wt of bentonite to the mixture of 0,5 gram of PVC and 0,125 gram of LiClO4. Ionic conductivity of polymer electrolyte was tested using impedance spectroscopy. The result of the research was showed that a mixture of PVCBentonite( 10% wt/wt)-LiClO4 gives the highest ionic conductivity (4,86 x 10-3 S.Cm-1). This result indicated that the presence of natural bentonite can be used as a filler in the current composite polymer electrolyte and can increase the ionic conductivity of the polymer electrolyte.
Preparation of Fe-intercalated Graphite Based on Coal Tailings, Dimensional Structure Irfan Gustian; Eka Angasa; Dwi Agustini; Evi Maryanti; Dyiah Fitriani
Aceh International Journal of Science and Technology Vol 4, No 3 (2015): December 2015
Publisher : Graduate Program of Syiah Kuala University

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (669.343 KB) | DOI: 10.13170/aijst.4.3.3017

Abstract

Intercalated graphite from coal tailings have been modified through the intercalation of iron. Coal tailings which is a byproduct of the destruction process and flakes washing results from mining coal. Intercalation of iron goal is to improve the physical properties of graphite and modifying sizes of crystal lattice structure with thermal method. Modification process begins with the carbonization of coal tailings at 500ºC and activated with phosphoric acid. Activation process has done by pyrolysis at 700ºC. The results of pyrolysis was soaked in mineral oil for 24 hours, then pyrolysis again with variations in temperature 800°C and 900ºC for 1 hour and subsequent intercalation iron at 1% and 2%. Material before activated, after activated, and the results of pyrolysis still indicates order nano: 29, 25 and 36 nm respectively. X-ray diffraction characterization results indicate that change in the structure, the sizes crystal lattice structure of the material The greater the concentration of iron was added, the resulting peak at 2θ = 33 and 35 also will be more sharply. The results of SEM showed different morphologies from each treatment.
Physico-chemical characteristics of Composites material Based on Sulfonated Cyclone Fibre Cellulose and Benzotriazole Irfan Gustian; Eka Angasa; Ghufira Ghufira
Aceh International Journal of Science and Technology Vol 6, No 2 (2017): August 2017
Publisher : Graduate Program of Syiah Kuala University

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (526.393 KB) | DOI: 10.13170/aijst.6.2.8438

Abstract

Composites material based on sulfonated cyclone fibre cellulose (SCFC) and benzotriazole (Btri) have been prepared. Cyclone fibre cellulose (CFC) was sulfonated with trimethylsilyl chlorosulfonate (TMSCS), with high degree of sulfonation (150%). The composites material, SCFC-Btri were prepared by doping of benzotriazole in various mole ratios (0.125, 0.25 and 0.5). FTIR spectrum has confirmed the ionic interaction between sulfonic acid from sulfonated cyclone fibre cellulose and benzotriazole units. Thermogravimetric analysis (TGA) showed that the composites material was thermally stable up to 150 °C. The results showed that methanol permeability of the composite material was lower than pristine Nafion112. Activation energy obtained for the materials are 0. 106 eV, 0.144 eV and 0.137 eV for SCFC-Btri mole ratios 0.125, 0.25 and 0.5 respectively, composites material was expected to be used as raw material in the fuel cell.