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Journal : Environmental and Materials

Preparation of boron-doped diamond microelectrodes to determine the distribution size of platinum nanoparticles using current transient method Aliyah; Reza Rizqi Nurhidayat; Afiten Rahmin Sanjaya; Rahmat Wibowo; Yasuaki Einaga; Endang Saepudin; Tribidasari Anggraningrum Ivandini
Environmental and Materials Vol. 1 No. 1: Juni (2023)
Publisher : Institute for Advanced Science, Social, and Sustainable Future

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.61511/eam.v1i1.2023.117

Abstract

Boron-doped diamond (BDD) microelectrodes were prepared to investigate the correlation of hydrazine oxidation current responses with Pt nanoparticle (Pt NP) size distribution. The BDD film was grown on the surface of a tungsten needle with a diameter of 25 µm. An average particle size of around 5 µm BDD crystalline was successfully synthesized using a microwave plasma-assisted chemical vapor deposition technique. The Raman spectrum confirmed the presence of diamond formation as indicated by peaks corresponding to C-C sp3 bonds, while X-ray photoelectron spectroscopy spectrum showed the presence of C-H and C-OH bonds on the surface of the BDD microelectrode. Meanwhile the Pt nanoparticles was synthesized through reduction reaction of  PtCl62- solution using NaBH4 with citric acid as the capping agent. Particles size between 4.46 to 4.78 nm were observed by using TEM measurements. The BDD microelectrodes were utilized to investigate the relationship between Pt nanoparticle size distribution and the current generated from the oxidation reaction of 15 mM hydrazine in a 50 mM phosphate buffer solution pH 7.4 in the presence of 1.0 mL nanoparticle solutions. A current range of 5 and 6 nA with a noise level of 0.15 nA was observed showing a good correlation with the particle sizes of Pt NPs. Comparison was also performed with the measurements using Au microelectrodes, indicated that the prepared BDD microelectrodes is promising for the measurements of nanoparticle sizes distribution, especially Pt NPs.
Preparation of boron-doped diamond microelectrodes to determine the distribution size of platinum nanoparticles using current transient method Aliyah; Nurhidayat , Reza Rizqi; Afiten Rahmin Sanjaya; Rahmat Wibowo; Einaga, Yasuaki; Saepudin, Endang; Ivandini, Tribidasari Anggraningrum
Environmental and Materials Vol. 1 No. 1: (June) 2023
Publisher : Institute for Advanced Science, Social, and Sustainable Future

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.61511/eam.v1i1.2023.117

Abstract

Boron-doped diamond (BDD) microelectrodes were prepared to investigate the correlation of hydrazine oxidation current responses with Pt nanoparticle (Pt NP) size distribution. The BDD film was grown on the surface of a tungsten needle with a diameter of 25 µm. An average particle size of around 5 µm BDD crystalline was successfully synthesized using a microwave plasma-assisted chemical vapor deposition technique. The Raman spectrum confirmed the presence of diamond formation as indicated by peaks corresponding to C-C sp3 bonds, while X-ray photoelectron spectroscopy spectrum showed the presence of C-H and C-OH bonds on the surface of the BDD microelectrode. Meanwhile the Pt nanoparticles was synthesized through reduction reaction of  PtCl62- solution using NaBH4 with citric acid as the capping agent. Particles size between 4.46 to 4.78 nm were observed by using TEM measurements. The BDD microelectrodes were utilized to investigate the relationship between Pt nanoparticle size distribution and the current generated from the oxidation reaction of 15 mM hydrazine in a 50 mM phosphate buffer solution pH 7.4 in the presence of 1.0 mL nanoparticle solutions. A current range of 5 and 6 nA with a noise level of 0.15 nA was observed showing a good correlation with the particle sizes of Pt NPs. Comparison was also performed with the measurements using Au microelectrodes, indicated that the prepared BDD microelectrodes is promising for the measurements of nanoparticle sizes distribution, especially Pt NPs.
Synthesis of gold nanoparticles with allicin to modify boron-doped diamond surface for oxygen sensor applications Raharto, Toto; Setiyanto, Cahya Mukti; Ariyanta, Harits Atika; Nahda, Dinda Prastika Nabila; Hani, Adinda Muthia; Yulizar, Yoki; Ivandini, Tribidasari Anggraningrum; Einaga, Yasuaki
Environmental and Materials Vol. 1 No. 2: (December) 2023
Publisher : Institute for Advanced Science, Social, and Sustainable Future

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.61511/eam.v1i2.2023.560

Abstract

Modification of surface of boron-doped diamond (BDD) film with gold nanoparticles (AuNPs) was carried out to increase its catalytic activity for an application as an oxygen sensor. Allicin was isolated from garlic by salting out extraction technique, and then used as the capping agent to synthesize AuNPs as it has a double bond structure that could be reacted to attach the BDD surface under UV light radiation. An average size of AuNPs at around 46,00 ± 9,06 nm was obtained, while the modification of the BDD surface by the synthesized AuNPs indicated that the surface of BDD could be covered by gold at around 0.6 % (w/w). Investigation of the AuNPs-modified BDD as a working electrode for the oxygen reduction by using cyclic voltammograms in 0.1 M phosphate buffer solution pH 7 observed a current peak at around -0.45 V (vs. Ag/AgCl). The current of this peak linearly increased proportionally to the dissolved oxygen concentrations (R2=0.9986). Moreover, a limit of detection of the dissolved oxygen of 0.12 ppm and limit of quantity 0.41 ppm could be achieved with excellent stability at 6.86% RSD with 6 repetitions and sensitivity at 19.086 μA/ppm indicated that the modified BDD is promising for applications as an oxygen sensor.