Ridla Bakri
Department Of Chemistry, Faculty Of Mathematics And Natural Sciences, University Of Indonesia, Jl. Lingkar Kampus Raya, Pondok Cina, Beji, Depok, Jawa Barat 16424, Indonesia

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Journal : Makara Journal of Science

PREPARATION of [BzMe3N]2[Na2W4O12(OMe)4(MeOH)6].6MeOH Bakri, Ridla
Makara Journal of Science Vol. 7, No. 1
Publisher : UI Scholars Hub

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Abstract

An attempt to prepare trinuclear tungsten oxoalkoxides [BzMe3N]3 [W3O8 (OMe)5 ] from the reaction between WO2 (OMe)2 , [BzMe3N]2WO4 and [BzMe3N](OMe) in the ratio of 2:1:1 in MeOH produced [BzMe3N]2 [Na2W4O12(OMe)4 (MeOH)6 ].6MeOH. Suitable crystals for X-ray chrystallographic studies were obtained from hot mixture of methanol-acetonitrile solution. The I.R., 1H-NMR, and microanalysis data including crystal structure of [Na2W4O12(OMe)4 (MeOH)6 ] 2- anion are reported
THE SYNTHESES OF [BzMe3N]2[Mo4O10(OMe)6] Bakri, Ridla
Makara Journal of Science Vol. 6, No. 3
Publisher : UI Scholars Hub

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Abstract

In an attempt to synthesize [BzMe3N]2Mo2O5(OMe)5 from the reaction of [BzMe3N]2MoO4 and MoO(OMe)4 in the ratio of 1:1 in methanol has produced [BzMe3N]2Mo4O10(OMe)6. The formation of [Mo4O10(OMe)6]2- anion suggests that ligand dissociation has occured in solution. Suitable crystals for X-ray chrystallographic were obtained from hot methanol and the crystal structure of [BzMe3N]2Mo4O10(OMe)6 has been solved and reported here in.
THE SYNTHESES OF [BzMe3N]2[Mo4O10(OMe)6] Bakri, Ridla
Makara Journal of Science Vol. 6, No. 3
Publisher : UI Scholars Hub

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Abstract

In an attempt to synthesize [BzMe3N]2Mo2O5(OMe)5 from the reaction of [BzMe3N]2MoO4 and MoO(OMe)4 in the ratio of 1:1 in methanol has produced [BzMe3N]2Mo4O10(OMe)6. The formation of [Mo4O10(OMe)6]2- anion suggests that ligand dissociation has occured in solution. Suitable crystals for X-ray chrystallographic were obtained from hot methanol and the crystal structure of [BzMe3N]2Mo4O10(OMe)6 has been solved and reported here in.