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Synthesis and Characterization of UiO-66 as a Paracetamol Absorption Material Fery Eko Pujiono; Try Ana Mulyati
Al-Kimia Vol 7 No 2 (2019): DECEMBER
Publisher : Study Program of Chemistry - Alauddin State Islamic University of Makassar

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (523.755 KB) | DOI: 10.24252/al-kimia.v7i2.10485

Abstract

UiO-66 synthesis has been carried out by dissolving 0.53 grams of zirconium tetrachloride (ZrCl4) and 0.34 grams of Benzene-1,4-dicarboxylic Acid (H2BDC) in 30 mL Dimethylformamide (DMF). The solution is then distilled for 30 minutes and then heated in an oven at 140 ° C for 6 hours. The UiO-66 material produced was then characterized by an X-Ray Diffractometer (XRD) and Fourier Transform Infrared (FTIR). The results showed that the UiO-66 was successfully synthesized which supported the XRD results at 2θ 7.3o, 8.49o and 25.8o which were the peak characteristics of UiO-66. In addition, the FTIR results show a peak of around 1500 cm-1 showing vibrations of C = C on the benzene ring and a peak of about 1390 cm-1 indicating streching of O-C-O produced from the ligand. The peaks are around 750, and 660 cm-1 which indicates the presence of C-H vibrations from the ligand. UiO-66 was also approved as the adsorption agent of paracetamol which was approved with the highest adsorption of paracetamol at 72 hours immersion time which was 97.03%.
The Exposure of Pb to Hair and Nails in Children Around "X” Coal Mines Using Atomic Absorption Spectroscopy (AAS) Method Tri Ana Mulyati; Fery Eko Pujiono; Indah Indah
JURNAL KESEHATAN LINGKUNGAN Vol. 13 No. 3 (2021): JURNAL KESEHATAN LINGKUNGAN
Publisher : Universitas Airlangga

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.20473/jkl.v13i3.2021.174-179

Abstract

Introduction: The exposure of Pb from coal mining activity could be accumulated primarily in the hair and nails. It was a presence as a bioindicator of Pb contamination in the community. Children who lived around coal mining were also likely to experience contamination of Pb. The children could absorb up to 50% of Pb metal. Methods: This study used a cross-sectional design. The sample was taken using cluster sampling and classified based on the age group, namely 1-3 years, 4-6 years, and 7-9 years. Exposed respondents lived around 1-10 kilometers from the mining area, and the non-exposed respondents lived outside. Some hair and nails would be taken from all respondents, which were sent to a laboratory directly. Atomic Absorption Spectroscopy was used to measure the levels of Pb. Results and Discussion: This study showed that Pb levels in the hair of exposed respondents in all age categories were above the WHO threshold limits value (≤ 12µg/g). In addition, in nails, Pb levels exceed the threshold limits value in the exposed sample groups 4-6 years and 7-9 years. Differences in Pb levels in the hair and nails between exposed dan non-exposed respondents showed significantly by the statistical test. Conclusion: Communities living in coal mining areas are at greater risk of exposure to heavy metals than others. Pb is one type of heavy metal that accumulates in the body, specifically in hair and nails, because it did not release by metabolism. Hence, it becomes a bioindicator to ensure our entire body exposure to hazardous materials.
Uji Drug Loading Ibuprofen Pada Material UiO-66 (Zr-Metal Organic Framework) Tri Ana Mulyati; Fery Eko Pujiono
Jurnal Kimia Riset Vol. 4 No. 2 (2019): Desember
Publisher : Universitas Airlangga

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.20473/jkr.v4i2.16088

Abstract

Tujuan dari penelitian ini adalah untuk mengetahui nilai loading ibuprofen pada material UiO-66 (Zr-Metal Organic Framework). Pada penelitian ini, dilakukan variasi lama perendaman 12, 24, 36, 48, 60 dan 72 jam, sehingga didapatkan nilai drug loading yang optimal. Nilai drug loading ibuprofen diukur menggunakan spektrofotometer UV-VIS. Adapun penyimpanan ibuprofen dalam UiO-66 dikonfirmasi dengan XRD, FTIR, dan SEM-EDX. Hasil analisa gugus fungsi sampel dengan Fourier-Transform Infra Red (FTIR) dari Zr-MOF menunjukkan bahwa puncak khas dari UiO-66 juga muncul pada 663, 748 dan 547 cm-1 yang menunjukkan adanya interaksi Zirkonium (Zr) dengan ligan H2BDC, setelah UiO-66 digunakan untuk loading Ibuprofen tidak mengubah posisi dari puncak-puncak UiO-66. Namun, terjadi penurunan intensitas dan hilangnya puncak disekitar 1300 cm-1 yang dikarenakan interaksi antara UiO-66 dengan ibuprofen. Pola difraktogram UiO-66  sebelum dan sesudah loading ibuprofen yang  menunjukkan bahwa UiO-66 yang terbentuk memiliki puncak karakteristik UiO-66 pada 7,3o. Mikrograf UiO-66 sebelum dan setelah loading  ibuprofen memiliki morfologi kubus. Namun, setelah  loading  ibuprofen terdapat bagian seperti karang putih, ukuran yang terlihat lebih besar, serta pengurangan ruang kosong permukaan material. Uji Drug Loading Ibuprofen pada UiO-66 menunjukkan loading optimum ibuprofen dalam Zr-MOF mencapai 82,79% pada waktu pengadukan 72 jam.
PEMBERDAYAAN KELOMPOK UTARAN MELALUI PEMBUATAN SABUN HOMEMADE EKSTRAK KEDELAI DARI SISA PRODUKSI TAHU Tri Ana Mulyati; Fery Eko Pujiono; Munifatul Lailiyah
LOGISTA - Jurnal Ilmiah Pengabdian kepada Masyarakat Vol 5 No 2 (2021)
Publisher : Department of Agricultural Product Technology, Faculty of Agricultural Technology, Universitas Andalas Kampus Limau Manis - Padang, Sumatera Barat Indonesia-25163

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.25077/logista.5.2.1-7.2021

Abstract

Kediri dikenal sebagai Kota Tahu dimana banyak usaha kecil menengah yang memproduksi usaha tahu. Salah satu kelompok usaha tahu yang berada di Kediri adalah Kelompok Utaran (Usaha Tahu rumahan) yang berada di Desa Badal Pandean Kabupaten Kediri. Dalam keseharian, kelompok Utaran telah memproduksi tahu, menghasilkan bahan sampingan yang belum dimanfaatkan yaitu ekstrak kedelai. Sari kedelai memiliki beberapa manfaat seperti mencegah penuaan dini, melindungi kerusakan kulit dari sinar ultra violet, serta mencegah terbetuknya jerawat. Melihat besarnya manfaat sari kedelai, maka salah satu limbah produksi tahu kelompok Utaran, dapat pula dijadikan salah satu bahan tambahan pada produksi sabun. Hal ini dilakukan karena sabun menjadi kebutuhan yang penting terutama pada masa pandemi Covid-19 ini. Metode yang digunakan pada kegiatan ini adalah penyuluhan, pelatihan, dan pendampingan dalam produksi, pengemasan serta pemasaran produk sabun “Utaran”. Pengabdian masyarakat untuk memanfaatkan sisa tahu yang tidak terjual menjadi sabun ektrak tahu telah dilakukan. Hasil kegiatan ini menunjukkan bahwa pengetahuan mitra tentang pemanfaatan ektrak tahun menjadi sabun meningkat menjadi 100%. Disamping itu, pelatihan pembuatan tahu menghasilkan mitra mampu membuat sabun ekstrak tahu dengan sangat baik. Pelatihan pengemasan produk juga telah dilakukan untuk menjaga keberlanjutan program. Kata kunci: sabun, homemade, ektrak kedelai, kelompok usaha tahu, covid-19 ABSTRACT Kediri is understood because the City of Tofu where many small and medium businesses produce tofu businesses. one among the tofu business groups in Kediri is that the Utaran Group (home-based Tofu Business) located in Badal Pandean Village, Kediri Regency. In their lifestyle, the Utaran group has produced tofu, producing a by-product that has unused, namely soybean extract. Soybean juice has several benefits like preventing premature aging, protecting skin damage from ultraviolet rays, and preventing acne from forming. Seeing the good benefits of soybean juice, one among the assembly wastes of the Utara group also can be used as another ingredient in soap production. This soap-making program was administered because soap became a crucial necessity, especially during this Covid-19 pandemic. The methods used are counseling, training, and help within the production, packaging, and marketing of " Utaran" soap products. Community service to use the remaining tofu that's unsold into tofu extract soap has been administered. The results of this activity showed that the knowledge of partners about the utilization of year extract into soap increased to 100%. Additionally, the tofu-making training resulted in partners having the ability to form tofu extract soap all right. Training on product packaging and marketing has also been administered to take care of the sustainability of the program Keywords: soap, homemade, soybean extract, tofu business groups, covid-19
Activated Carbon of Coconut Shell Modified TiO2 as a Batik Waste Treatment Fery Eko Pujiono; Tri Ana Mulyati; Miftakhul Nor Fizakia
Jurnal Riset Teknologi Pencegahan Pencemaran Industri Vol. 11 No. 2 (2020)
Publisher : Balai Besar Standardisasi dan Pelayanan Jasa Pencegahan Pencemaran Industri

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.21771/jrtppi.2020.v11.no2.p1-10

Abstract

Research about the modification of activated carbon of coconut shell with TiO2 as a waste treatment Batik has been done. The purpose of this study was to determine the effect of modified TiO2 on activated carbon characteristics and the effect of TiO2 concentration on the adsorption power of activated carbon in batik waste. The method utilized was activated carbon soaked in TiO2 with 5% and 10% concentrations in a ratio of 1: 5, then stirred with a magnetic stirrer for 2 hours. Next, the mixture was placed in an autoclave bottle and an oven (200°C for 30 minutes). The results were then washed with distilled water and dried (100°C for 5 hours), then the material was characterized by FTIR, XRD, SEM-EDX, and application to batik waste. FTIR results indicated the presence of Ti-O-Ti groups after modification at wave number 682 cm-1, XRD indicated the presence of a combination of amorphous KA and crystalline TiO2 at 25,2°; 37,7°; 48,1°; 53,8°; and 55°, and SEM results of TiO2 agglomeration on the surface of the railroad. Adsorption of batik waste showed KATiO2-10 (0,052) lower than KA (0,059) and KATiO2-5 (0,057), as well as the presence of COD KA results = 705,6 mg / L (pH = 8), KATiO2-5 = 504,0 mg / L (pH pH = 7) and KATiO2-10= 403,2 mg / L (pH = 7). Based on this research, the activated carbon modified TiO2 can be used as a material for processing batik waste with the most significant concentration of TiO2 represent 10%.
Pengaruh Pengolahan Buah Salak Pondoh (Salacca zalacca (Gaertn.) Voss) terhadap Kadar Vitamin C Fery Eko Pujiono; Tri Ana Mulyati
Jurnal Dunia Farmasi Vol 7, No 1 (2022): Edisi Desember
Publisher : Program Studi Farmasi, Fakultas Farmasi dan Kesehatan, Institut Kesehatan Helvetia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.33085/jdf.v7i1.5346

Abstract

Pendahuluan: Salak banyak diproduksi karena peningkatan jumlah konsumsi buah salak disetiap tahunnya. Hal ini dikarenakan salak memiliki kandungan gizi yang sangat tinggi. Kandungan karbohidrat dan air yang sangat tinggi ini menyebabkan salak lebih mudah busuk sehingga umumnya buah salak hanya dapat bertahan selama 7 hari pada suhu kamar. Disisi lain, Perubahan lain yang cukup merugikan adalah terjadinya perubahan warna daging buah secara 2 enzimatis karena kandungan tanin yang memberikan rasa sepat pada salak jika terkena udara maka akan menghasilkan perubahan warna coklat (reaksi browning enzymatic). Produk hasil pengolahan salak termasuk jus, selai, dodol, asinan, dan manisan salak. Namun, permasalahan yang terjadi adalah pengolahan buah ini dapat mempengaruhi kadar gizi terutama vitamin C. Hilangnya vitamin C selama proses pengolahan buah dapat terjadi karena proses oksidasi akibat pemanasan atau aktivitas enzimatik Tujuan: Mengetahui pengaruh pengolahan buah salak terhadap kadar vitamin C. Metode: Penelitian ini menggunakan UV-Vis untuk penentuan kadar Vitamin C sebelum dan sesudah diolah menjadi manisan salak. Pengolahan manisan salak dilakukan pada berbagai waktu yaitu 5 menit (Manisan A), 10 menit (Manisan B), 20 menit (Manisan C) dan 30 menit (Manisan D). Instrumen yang digunakan untuk mengukur kadar vitamin C adalah UV-Vis dan panjang gelombang maksimum yang digunakan adalah 265 nm. Hasil: Berdasarkan hasil penelitian dapat disimpulkan bahwa pengolahan salak pondoh menjadi manisan salak pondoh basah dapat menurunkan kadar vitamin C. Semakin lama waktu pengolahan salak pondoh maka kadar vitamin C semakin menurun. Kadar vitamin C tertinggi terdapat pada sampel buah salak pondoh segar (kontrol) yaitu 4,913 ± 0,076 mg/100 g. Adapun kadar vitamin C terendah terdapat pada sampel Manisa D (pengolahan 30 menit) yaitu 0,363 ± 0,031 mg/100 g. Simpulan: Semakin lama waktu pengolahan salak pondoh maka kadar vitamin C semakin menurun
Cotinine Analysis in Active Smoker's Urine by Immunochromatography Assay Method Fery Eko Pujiono; Putri Solikah; Tri Ana Mulyati
Jurnal Sintesis: Penelitian Sains, Terapan dan Analisisnya Vol 3 No 1 (2022): Juni 2022
Publisher : Fakultas Sains, Teknologi, dan Analsisi Institut ilmu Kesehatan Bhakti Wiyata

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.56399/jst.v3i1.52

Abstract

Cigarettes are the main product of tobacco processing. Cotinine is often used as a biomarker in the assessment of nicotine exposure because it has a half-life of 15-20 hours in the blood. This compound is easily detected in saliva, urine and blood. Cotinine in urine can be detected using an immunochromatography assay. The purpose of this study was to describe the results of cotinine examination in the urine of active smokers using the immunochromatography assay method in Sumuragung Village, Bojonegoro. This study used a descriptive research design that collected 26 smokers in the village of Sumuragung Bojonegoro who were selected using a purposive sampling technique. A total of 26 urine samples were detected using the immunochromatography assay method. The results of cotinine examination in the urine of active smokers showed that there were 25 people (96%) positive and 1 person (4%) negative. Based on the results of the study, it can be concluded that the urine of active smokers contains cotinine.
WORKSHOP PEMASARAN UBI LATA UNTUK PENINGKATAN EKONOMI MASYARAKAT LOKAL Reny Nugraheni; Tri Ana Mulyati; Dianti Ias Oktaviasari; Fery Eko Pujiono
JOURNAL OF COMMUNITY DEDICATION Vol. 4 No. 4 (2024): NOVEMBER
Publisher : CV. ADIBA AISHA AMIRA

Show Abstract | Download Original | Original Source | Check in Google Scholar

Abstract

Lata yam is one of the local commodities that has great potential to be developed as a superior product in the Badal Pandean Kediri area. Besides being rich in nutritional value, Lata yam has high flexibility to be processed into various value-added products, so that it can make a significant economic contribution to the local community. However, this potential has not been optimally utilised due to the community's limited understanding of marketing, especially digital marketing, which is now key in reaching a wider market and increasing the competitiveness of local products. This constraint has resulted in the low selling value of Lata yam and limited market reach, which in turn affects the income of farmers and small business actors in the region. Therefore, empowerment efforts are needed that can improve community marketing skills in processing and promoting Lata yam-based products. This community service programme aims to improve the marketing knowledge and skills of local communities through a Lata yam marketing workshop. This workshop includes training on basic marketing strategies, promotional content creation techniques, social media management, and simple digital marketing techniques that suit the capabilities and needs of the local community. The methods used included counselling, training, and intensive mentoring. Initial counselling focused on the importance of digital marketing for local products, followed by technical training in creating visual content and product descriptions that appeal to consumers. In addition, participants were taught how to manage social media such as Instagram and Facebook as effective yet cost-effective marketing tools. The results of this activity showed an increase in participants' understanding and skills in digital marketing. As many as 85% of participants who initially had not utilised social media for product marketing have now started to actively use the platform and demonstrated the ability to create more attractive and informative promotional content. In addition, there was an average sales increase of 15-20% in the three-month post-workshop period, indicating that digital marketing strategies have a positive impact on participants' competitiveness and income. Some participants were even able to develop Lata yam-based processed products, such as chips and yam flour, which have a higher selling value than raw products. This programme not only provides economic benefits for participants, but also has an impact on increasing community motivation and confidence in developing local products. This workshop is expected to be the first step in creating a sustainable marketing ecosystem, where communities can independently develop and market their local products more effectively. Through continued support and further training, it is hoped that Lata yam can become one of the leading commodities that is widely recognised, both in the national and international markets, so as to be able to make a long-term contribution to local economic development.
Identification of Pathogenic Bacteria in Liquid Waste from "X" Hospital in Kediri City Tri Ana Mulyati; Binti Mu’arofah; Fery Eko Pujiono; Reza Alrayan
Ad-Dawaa: Journal of Pharmaceutical Sciences
Publisher : Universitas Islam Negeri Alauddin Makassar

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.24252/djps.v7i2.50196

Abstract

Introdiction: Hospitals can not only be a place for people to seek treatment, but they can also get diseases, especially infectious diseases. One source of the spread of infectious diseases comes from hospital waste, so proper waste processing is needed. Hospital wastewater contains many pathogenic bacteria such as Enterobacter cloacae, Bacillus sp., Kluyvera sp., Enterobacter sakazaki, Klebsiella oxytoca and E.coli. This makes it necessary to manage hospital wastewater to prevent the spread of disease, especially by pathogenic bacteria. On the other hand, research is still needed on the specific types of bacteria found in wastewater, including hospitals in Kediri City. Aims: to determine the types of pathogenic bacteria at the "X" hospital in Kediri City. Result: the density of bacteria in the bottom waste was greater than in the top and middle parts, with an average of 1,830 bacteria/100 ml. The results of the identification test showed that pathogenic bacteria contained in the waste from hospital "X" in Kediri City included Klebsiella (25%), E.coli (50%) and Pseudomonas (25%). Conclusion: The waste from "X" Hospital Kediri City contains three types of pathogenic bacteria: Klebsiella, E. coli, and Pseudomonas.
PENINGKATAN KETAHANAN PANGAN KELUARGA MELALUI INOVASI SNACKBAR UBI JALAR UNGU Dianti Ias Oktaviasari; Tri Ana Mulyati; Reny Nugraheni; Fery Eko Pujiono
Jurnal Pengabdian Masyarakat Sapangambei Manoktok Hitei Vol. 4 No. 2 (2024): Jurnal Pengabdian Masyarakat SAPANGAMBEI MANOKTOK HITEI
Publisher : Universitas

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.36985/m07dyz76

Abstract

Perwujudan ketahanan pangan nasional salah satunya dengan pemanfaatan sumberdaya pangan lokal. Ubi jalar ungu (Ipomoea batatas L.) adalah salah satu jenis umbi yang banyak ditemui di Indonesia. Ubi jalar ungu merupakan bahan pangan lokal yang mudah tumbuh dan ditanam petani dan bahan makanan yang mengandung tinggi serat dan antioksidan. Ubi jalar ungu dapat dimanfaatkan sebagai diversifikasi pangan untuk mengurangi ketergantungan terigu namun pemanfaatan ubi jalar ungu selama ini terbatas sebagai bahan makanan tradisional dan memiliki nilai jual yang cukup rendah. Snack bar merupakan salah satu inovasi untuk dapat meningkatkan daya beli dan daya konsumsi terhadap ubi jalar ungu. Diharapkan kelompok tani dapat memanfaatkan ubi jalar ungu menjadi bahan pangan yang lebih disukai banyak orang dan meningkatkan harga jual. Sehingga dapat tercapai ketahanan pangan keluarga baik dari segi akses ekonomi juga dari konsumsi gizi. Kegiatan pengabdian masyarakat dilaksanakan di Desa Badal Pandean Kecamatan Ngadiluwih Kabupaten Kediri dengan sasaran Kelompok Wanita Tani (KWT). Metode pelaksanaan kegiatan pengabdian masyarakat dengan demo praktik pembuatan snackbar ubi jalar ungu dan pemberian media leaflet yang berisi langkah-langkah, bahan dan alat untuk pembuatan sanckbar ubi jalar ungu. Alat dan media yang digunakan adalah video pembuatan snackbar, leaflet, dan alat dan bahan baku pembuatan snackbar. Terdapat peningkatan pengetahuan peserta setelah mengikuti pelatihan dilihat dari hasil pretest dan postest peserta. Kegiatan praktik pembuatan snackbar ubi juga telah terlaksana sehingga diharapkan peserta mampu mengolah ubi jalar ungu menjadi pangan fungsional yang dapat meningkatkan kesejahteraan, meningkatkan perekonomian dan ketahanan pangan keluarga