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Journal : ASEAN Journal of Chemical Engineering

Second Generation of Biodiesel Production from Indonesian Jatropha Oil by Continuous Reactive Distillation Process Arief Budiman; Ratna D Kusumaningtyas; Sutijan Sutijan; Rochmadi Rochmadi; Suryo Purwono
ASEAN Journal of Chemical Engineering Vol 9, No 2 (2009)
Publisher : Department of Chemical Engineering, Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (324.709 KB) | DOI: 10.22146/ajche.50104

Abstract

The batch process of biodiesel production deals with problems related to the labor and separation cost since it is slow, entailing several separation steps, labor intensive, and not suitable for a very large-scale production. Therefore, a second generation process technology for biodiesel should be developed. In this work, a continuous transesterification using reactive distillation was proposed. The goal was to bring in a more efficient reactor system by combining chemical reactions and separation simultaneously in one unit. In this work, a laboratory-scale Reactive Distillation was applied for the biodiesel synthesis from the Indonesian refined jatropha oil in the presence of NaOH catalyst. The experimental investigation demonstrated the effects of the temperature, catalyst loading, and molar ratio of the reactants. The best result was achieved on the process conducted at the reaction temperature of 65 ºC with molar ratio of methanol to triglycerides of 10:1 and catalyst loading of 0.75% w/ w oil. The reaction conversion was 94.83% and methyl ester content of the product was 99.27%. The fuel characteristic of biodiesel agreed with the Indonesian national standard and ASTM specification.
Dynamic Cycling State of Nonadiabatic Catalytic Combustion of Propylene Suryo Purwono
ASEAN Journal of Chemical Engineering Vol 6, No 1 (2006)
Publisher : Department of Chemical Engineering, Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (6969.871 KB) | DOI: 10.22146/ajche.50149

Abstract

An experimental study of nonadiabatic fixed-bed reactor for controlling propylene gas was made under flow reversal operation. Temperature measurements were made within the catalyst and packing beds. The influence of the operating parameters on the shape of temperature profiles, conversion, and heat removal were studied. The experiments showed that the maximum measured reactor temperature and heat removal were rather insensitive to changes in cycle duration and sensitive to feed flow rate and reactant concentration. The simulation results for the variation of concentration, flow rate, and cycle time showed the experimentally observed behavior Further simulations showed that runaway can occur when concentration was high.
CO Oxidation over Metal Oxide CatalystSupported by Indonesian Natural Zeolite Suryo Purwono
ASEAN Journal of Chemical Engineering Vol 2, No 1 (2002)
Publisher : Department of Chemical Engineering, Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (617.127 KB) | DOI: 10.22146/ajche.50801

Abstract

The objectives of this study are to attempt to develop catalysts and to find the operating conditions under which combustible waste gases concentrations in the exhaust gases can be eventually reduced to satisfy air pollution standards. The results shows that using impregnation method, nickel and vanadium metals, as active components of the catalyst, can be dispersed on the natural zeolite as catalyst support. The reaction rate measurements of catalytic oxidation of CO was done in the temperature range between 300 and 550°C using a differential micro-reactor. The catalysts used for this experiment were vanadium pentoxide and nickel oxide on activated natural zeolite. To avoid fluidization, the reactant gases were flowed downward. The results show that the reaction rate depends strongly on the bed temperature and feed concentration and is not controlled by bulk phase mass transfer and pore diffusion.
Mathematical Model for Water Flooding and HPAM Polymer Flooding in Enhanced Oil Recovery Ahmad Tawfiequrahman Yuliansyah; Bardi Murachman; Suryo Purwono
ASEAN Journal of Chemical Engineering Vol 21, No 1 (2021)
Publisher : Department of Chemical Engineering, Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22146/ajche.65531

Abstract

The need for energy, especially the petroleum-based one, is steadily increasing along with population growth and technological advancement. Meanwhile, oil exploitation from oil reservoirs using primary and secondary techniques can only obtain about 30%-50 % out of the original oil in place. Enhanced Oil Recovery (EOR) is a method for increasing oil recovery from a reservoir by injecting materials that are not found in the reservoir, such as surfactant, polymer, etc. This research aims to develop a mathematical model representing two-phase flow through porous media in the EOR process. This model was extended from mass balance and fluid flow in porous media equations. The reliability of the model was then validated by water flooding and polymer flooding experiment. A porous media, constituted by a silica sand pack, was saturated with 2 % brine and sequentially flooded with HPAM polymer solution at various concentrations (5,000-15,000 ppm). The volume of the oil coming out from the media at any time intervals was measured. Validation of the model was carried out by optimizing the model parameters to obtain the best curve-fitting on the plot of the percentage of cumulative recovered oil against time. The results showed that the proposed mathematical model was reliable enough to express both water and polymer-flooding processes.
Co-Authors Ady Mara, Ady Ahmad Tawfiequrahman Yuliansyah Ahmad Tawfiequrrahman Yuliansyah Ana Lestari Anak Agung Gede Sugianthara Andriani, Anisa Novi Aprilia Siti Purwanti Arief Budiman Arief Budiman Arief Budiman Ariff Trisetia Anggara Arista Putranto Atika Dwi Farini Bambang Soehendro Bardi Murachman Bardi Murachman Bardi Murachman Budiyansah, Amsal Chitra Ria Ariska dan Suwati Danang Wahyuhono Desi Amalia Fenyka Dyah Mutiarin Dyah Tri Yulianti Eka Sari, Eka Eni Budiyati Fergie Febrina Fitri Trapsilawati Fitriani Fitriani Galuh Almas Darmawati Handayani, Destias Selly Handirofa Handirofa Hanum, Farrah Fadhillah Herni Hasifah Iga Maliga Ignesti Anindia Ikhsana, Mifta Aulia Indriana Kartini Indriana Kartini Jonas Kristanto Karna Wijaya Kartini, Indriyana Mohammad Fahrurrozi Muhamad Johar Ardany Muhammad Irsan B Muhammad Khoirul Anam Muhammad Kusumawan Herliansyah Muhammad Mufti Azis Muhammad Mufti Azis Nurcahyo Iman Prakoso Panut Mulyono Pasca Giffari Jusuf Prima Astuti Handayani Ratna D Kusumaningtyas Ratna Dewi Kusumaningtyas Rika Harini Rizki Purnaini Rochmadi Rochmadi Rochmadi Rochmadi Rochmadi Rochmadi Rochmadi Rochmadi Rochmadi Rochmadi Rodiansono Rukmana Rully Septria Rully Septria, Rully Sang Kompiang Wirawan Sarto Sarto Satriyo Dibyo Sumbogo Siti Salamah Siti Salamah Siti Syamsiah Siti Syamsiah Subagyo Sudarmadji Sudarmadji Sudarmadji Sudarmadji Sudarmadji Sudarmadji Supranto Supranto Supranto Sutijan Sutijan Teguh Ariyanto Triyono Triyono Triyono Triyono Triyono Wega Trisunaryanti Wega Trisunaryanti Wega Trisunaryanti Wega Trisunaryanti Wega Trisunaryanti Wega Trisunaryati, Wega Yelmira Zalfiatri Yundari, Yundari Yusmardhany Yusuf