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Journal : International Journal of Eco-Innovation in Science and Engineering (IJEISE)

The Utilization of Lapindo Mud Waste for Aluminium Sulfate Production Lucky Indrati Utami; Tahan Simamora Rizaldi; Kindriari Nurma Wahyusi; Reva Edra Nugraha
International Journal of Eco-Innovation in Science and Engineering Vol. 2 No. 02 (2021): IJEISE
Publisher : Engineering Faculty, University of Pembangunan Nasional Jawa Timur

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.33005/ijeise.v2i02.40

Abstract

The Lapindo mudflow disaster in East Java Province, or also known as LUSI (LUmpur “mud”-SIdoarjo) has become spectacular longest ongoing disaster in recent memory since 2006. The utilization of volcanic Lapindo mud could be the promising solution to prevent further environmental damage. The chemical composition of Lapindo mud contained of 44.1% SiO2, 23.7% Fe2O3, 13% Al2O3, 7.02% CaO, 5.35% MoO3, 2.53% K2O, 1.84% TiO2 and 0.7% Na2O. Aluminium sulfate (Al2(SO4)3) or “alum” have been widely used as coagulation compound in water treatment, paper and textiles industry. Aluminium sulfate can be synthesized from aluminium oxide (Al2O3) from Lapindo mud with acidic solutions (H2SO4). The aim of this work was to synthesize aluminum sulfate from Lapindo mud by using extraction process. The impact of H2SO4 concentration and heating time to the production of aluminium sulfate have been investigated. The results showed that the aluminium sulfate can be synthesized from Lapindo mud by using H2SO4. Based on XRF analysis, the variation of heating time and H2SO4 concentration affect the aluminium sulfate conversion. The increasing of heating time and H2SO4 concentration directly enhance the conversion until reach the optimum condition. The optimum condition for aluminium sulfate synthesis from Lapindo mud (75.78% conversion) was found to be 90 min for heating time with H2SO4 concentration of 80%
The Effect of Resin and NH4OH Addition in The Making of Ammonium Silica Fertilizer from Geothermal Sludge Kindriari Nurma Wahyusi; Atika Nandini; Lucky Indrati Utami; Siswanto; Isni Utami; Nurul Mardhiyah; Dian Nofita
International Journal of Eco-Innovation in Science and Engineering (IJEISE) Vol. 2 No. 1 (2021): IJEISE
Publisher : International Journal of Eco-Innovation in Science and Engineering (IJEISE)

Show Abstract | Download Original | Original Source | Check in Google Scholar

Abstract

Geothermal sludge is a waste product from geothermal where it contains SiO2 which can be used as fertilizer. In this study, the making of silica ammonium fertilizer was carried out by taking salicy acid from geothermal sludge by extracting and adding resin which was then modified with NH4OH addition. Extraction was done using 1000 ml of KOH 1 N to dissolve 60 grams of Geothermal Sludge. Resins are added with variations in resin weight, namely, 5, 10, 20, 30, and 40 grams. NH4OH was added with variations in concentrations namely 3, 6, 9, 12 and 15% with a ratio of filtrate and NH4OH solution of 1: 1. The resulting ammonium silica inorganic liquid fertilizer products were analyzed for free silica and ammonia levels. The results of this study indicate that the levels of free silica and ammonia are influenced by the weight of the resin used and the concentration of ammonium hydroxide mixed. From the results of the research, it was found that inorganic silica liquid fertilizer with the highest SiO2 content in ammonium silica liquid fertilizer occurred when adding 20 grams of resin with the addition of NH4OH with a concentration of 15% which was 1,831.87 mg / L while the highest NH3 content in fertilizer liquid ammonium silica occurs when adding 40 grams of resin with the addition of NH4OH with a concentration of 15% which is equal to 252,312.80 mg / L.
The Effect of Resin and NH4OH Addition in The Making of Ammonium Silica Fertilizer from Geothermal Sludge Wahyusi, Kindriari Nurma; Nandini, Atika; Utami, Lucky Indrati; Siswanto; Utami, Isni; Mardhiyah, Nurul; Nofita, Dian
International Journal of Eco-Innovation in Science and Engineering (IJEISE) Vol. 2 No. 1 (2021): IJEISE
Publisher : UPN Veteran Jatim

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.33005/ijeise.v2i01.29

Abstract

Geothermal sludge is a waste product from geothermal where it contains SiO2 which can be used as fertilizer. In this study, the making of silica ammonium fertilizer was carried out by taking salicy acid from geothermal sludge by extracting and adding resin which was then modified with NH4OH addition. Extraction was done using 1000 ml of KOH 1 N to dissolve 60 grams of Geothermal Sludge. Resins are added with variations in resin weight, namely, 5, 10, 20, 30, and 40 grams. NH4OH was added with variations in concentrations namely 3, 6, 9, 12 and 15% with a ratio of filtrate and NH4OH solution of 1: 1. The resulting ammonium silica inorganic liquid fertilizer products were analyzed for free silica and ammonia levels. The results of this study indicate that the levels of free silica and ammonia are influenced by the weight of the resin used and the concentration of ammonium hydroxide mixed. From the results of the research, it was found that inorganic silica liquid fertilizer with the highest SiO2 content in ammonium silica liquid fertilizer occurred when adding 20 grams of resin with the addition of NH4OH with a concentration of 15% which was 1,831.87 mg / L while the highest NH3 content in fertilizer liquid ammonium silica occurs when adding 40 grams of resin with the addition of NH4OH with a concentration of 15% which is equal to 252,312.80 mg / L.
Synthesis of Hydrosiapatite from Muscle Shell Waste Using The Precipitation Method Puspitawati, Ika Nawang; Tauhid, Aziz Hafizh; M.N.K, Abdullah Tsani; Utami, Lucky Indrati; Wahyusi, Kindriari Nurma
International Journal of Eco-Innovation in Science and Engineering (IJEISE) Vol. 3 No. 2 (2022): IJEISE
Publisher : UPN Veteran Jatim

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.33005/ijeise.v3i02.72

Abstract

Hydroxyapatite is a calcium phosphate compound that is the main inorganic component of bones and teeth. Hydroxyapatite has a main role in the medical world because of its identical chemical properties and structure to human bone. Kupang shells have a high CaCO3 content of 95-99% by weight. So this concurrence, the mussel shells are to be used as good as an ingredient for making Hydroxyapatite. The variables used in this research are Temperature of the Furnace and Phosphoric Acid Concentration, which were 700ºC, 750 ºC, 800 ºC, 850 ºC, 900 ºC and Phosphate Acid Concentrations 0.4M, 0.6M, 0.8M, 1M, and 1.2M. The product results were tested with XRD analysis to determine the crystal structure contained in the product and the level of Hydroxyapatite in the product. The best research results in this study at a temperature of 900ºC at a concentration of 1.2M phosphoric acid with a Hydroxyapatite content of 100% with lattice parameters an (Aº)=b (Aº) = 9..422, c (Aº)=6.8835, and gamma = 120º.