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A Review: Synthesis, Recent Application and Future Challenge of SiO2 Nanoparticles in Membrane Technology Widiyanti, Silvia; Iasha, Yurin Karunia Apsha Albaina; Ashfiya, Putri Sayyida; Khoerunnisa, Fitri; Nurhayati, Mita; Hendrawan, Hendrawan; Sonjaya, Yaya; Aziz, Hafiz Aji
Jurnal Kartika Kimia Vol 7 No 1 (2024): Jurnal Kartika Kimia
Publisher : Department of Chemistry, Faculty of Sciences and Informatics, University of Jenderal Achmad Yani

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.26874/jkk.v7i1.255

Abstract

Membrane processes are well-established methods in real water treatment, renowned for their compact size, exceptional treatment effectiveness, and substantial water permeation capacity. The emergence of nanomaterials has ushered in thrilling prospects and progress in the membrane technology. Silica nanoparticles (NPs SiO2), a high-purity amorphous silica powder, is a white fluffy material characterized by its small particle size, and it brings numerous benefits due to its distinctive attributes. With a large specific surface area, strong surface adsorption, considerable surface energy, high chemical purity, and excellent dispersion, it holds significant value in diverse areas like medicine, physics, chemistry, and biology. NPs-SiO2 can be categorized into hydrophilic and hydrophobic types, which offers difference application in the membrane technology. In this review, NPs-SiO2 contained membranes are specifically discussed. The main goal is to provide critical analysis on recent application of SiO2 in membrane technology. Apart from the introduction and conclusion, this review has three consecutive parts including The synthesis methods of NPs-SiO2 contained membrane including size of the NPs-SiO2 that is mostly used in membranes, the application of the hydrophobic and hydrophilic NPs-SiO2 in the membrane technology, and the future challenge of NPs-SiO2 used in membrane technology.
Review on Synthesis, Properties, and Performances of Polymer/ Metal Organic Framework (MOF) composites membranes for water filtration application Ashfiya, Putri Sayyida; Khoerunnisa, Fitri; Nurhayati, Mita; Kadarohman, Asep; Sanjaya, Eli Hendrik; Hendrawan, Hendrawan; Sonjaya, Yaya; Aziz, Hafiz Aji; Annifah, Riri Uswatun; Iasya, Yurin Karunia Apsha Albaina
Jurnal Kartika Kimia Vol 8 No 1 (2025): Jurnal Kartika Kimia
Publisher : Department of Chemistry, Faculty of Sciences and Informatics, University of Jenderal Achmad Yani

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.26874/jkk.v8i1.871

Abstract

Mixed matrix membranes (MMMs) have gained considerable attention as a cutting-edge filtration technology, leveraging the combined advantages of polymer and inorganic fillers. Metal-organic frameworks (MOFs), as a nanoporous materials, are regarded as highly effective fillers in MMM, significantly enhancing molecular separation efficiency. This article provides a comprehensive review of the synthesis, properties, and performance of polymer/MOFs-based MMMs. A comprehensive literature search was conducted using ScienceDirect and Google Scholar with keywords such as metal-organic framework, MMMs, polymers, filler, and membrane filtration. Polymer/MOFs-based MMMs are synthesized using techniques including in situ and layer-by-layer assembly methods. The MMMs exhibit porosity distribution ranges from57 to 78.3%, contact angle ranges from 45° to 75.27°. The MMMs have also demonstrated exceptional performance in water permeability and bovine serum albumin (BSA)/salts rejection reached up to 94.03 L/m2.h and 99.8%, respectively. These finding highlight the significant potential of polymer/MOFs-based MMMs for advanced water filtration application.
Cassava Peel Starch Edible Coating Enriched with Limonene EOs for Preservation of Grapes: A Sustainable Method Ashfiya, Putri Sayyida; Sholihin, Hayat; Kusrijadi, Ali; Khoerunnisa, Fitri
agriTECH Vol 46, No 1 (2026)
Publisher : Faculty of Agricultural Technology, Universitas Gadjah Mada, Yogyakarta, Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22146/agritech.100319

Abstract

Grapes are perishable fruits susceptible to damage during transportation and storage post-harvesting, due to moisture loss, microbial contamination, oxidative damage, and physical degradation. These problems lead to weight loss, reduced shelf life, and deterioration of appearance, which can be overcome by using edible coating for preserving post-harvest fruits due to simplicity, non-toxicity, and cost-effectiveness. Starch is an excellent material for edible coating, with cassava peel serving as a suitable source because of good film-forming ability, biodegradability, and non-toxicity. Cassava peel starch also has the capacity to form a semi-permeable barrier that can reduce moisture and gas exchange for edible coating. However, starch is less resistant to pathogenic microbes, showing the need to incorporate limonene essential oil (EO) extracted from sweet orange peel with good antibacterial properties. Therefore, this study aimed to determine the most effective formulation of cassava peel starch and sweet orange EO in edible coating. Analysis was also carried out to evaluate the effect of coating on the quality of grapes based on weight loss, pH, antibacterial properties, and fruit organoleptic. The experiment was conducted by coating grapes using dip method and analyzed during 7 days of storage. Starch was successfully extracted from cassava peel with a facile method to obtain yield of 52.02%. The results showed that the most effective formulation of starch and EO in edible coating was 5% and 0.1%, respectively, indicating potential to significantly maintain the quality of grapes. The addition of orange peel-based EO also inhibited microbial growth during storage. At this formulation, grapes coated with EO-starch film showed an average weight loss of 5.94% and pH 4.21, with lower total microbes of 1.39x10 3 CFU/gram. This indicated that edible coating enriched limonene EO was effective in preserving grape quality and prolonging shelf life.