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Purification and Characterization of Silica Rice Husk Ash (Oryza Sative L.) From Kupang Regency Lede, Mega O. L.; Wogo, Hermania Em; Lulan, Theodore Y. K.; Ledoh, Sherlly M. F.
Chemistry Notes Vol 3 No (1) (2021): Chem. Notes 2021, 3(1)
Publisher : Universitas Nusa Cendana

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.35508/cn.v3i(1).4745

Abstract

This research had been done to purify and characterize silica from rice husk ash for two varieties of rice from Kupang Regency. The purification method used is the extraction method with alkaline solution (NaOH) and precipitation with acid solution (H2SO4). The stages in this research were preparation of rice husk ash, purification of silica rice husk ash with NaOH and H2SO4 solutions, and characterization covered: determination of acidity and surface area and determination of composition using X-ray fluorescence spectrophotometer (XRF). The results of the surface acidity test showed that the highest acidity was in Ciherang silica from Tarus, which was 2.288 mmol/g. While the surface area test showed that the largest surface area was Inpari 46 silica from Pariti, which was 184.297 m2/g with an optimum contact time of 50 minutes. The results of characterization using XRF exhibited that the highest silica purity was Ciherang rice variety from Tarus, with initial silica content data, purification with NaOH and H2SO4 were 93.9%; 98.2% and 99.1%. So that the purification process with NaOH and H2SO4 is proven to increase the silica content in the sample.
Bioaktivitas Metabolit Sekunder dari Genus Dipterocarpus Nalle, Halena A.; Lulan, Theodore Y. K.; de Rozari, Philiphi; Ola, Antonius R. B.
Chemistry Notes Vol 4 No (1) (2022): Chem. Notes 2022, 4 (1)
Publisher : Universitas Nusa Cendana

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.35508/cn.v3i2.6078

Abstract

Research has been conducted with the title "Literature Study of Secondary Metabolites and Bioactivity of Plants Genus Dipterocarpus". The method used is a descriptive method with the aim of being to find out the active compounds in the genus plant dipterocarpus and to know the ability of the bioactivity of genus plants dipterocarpus. Based on the results of the study, bioactivity of secondary metabolites from planst of the genus dipterocarpus namely antidiabetic, antiplasmodial, antibacterial, antioxidant, anticlasses, cytotoxic, anticholinesterase, antiproliferation, anti-inflammatory and antimicrobial. Very strong biosaltivity indicated by the ethyl acetate faction plant D. Intricatus Sagai Antioxidant IC50 Nialial is 0.075 μg / mL. While very weak bioacchables are shown extract methanol stem plant D. Costatus as cytotoxic with ic50 value 973 ± 14.57 μg / mL.
Pengaruh Komposisi Daun Gamal (Gliricidia sepium Hbr.) dan Kotoran Sapi dengan Nutrisi Pisang terhadap Rasio C/N Kompos Sedo, Karolina M.; Tawa, Bibiana Dho; Lulan, Theodore Y. K.; Gauru, Imanuel; Cunha, Theodorus M. Da
Chemistry Notes Vol 3 No 2 (2021): Chem. Notes 2021, 3(2)
Publisher : Universitas Nusa Cendana

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.35508/cn.v3i2.6089

Abstract

It has been done a research on the effect of the composition of gliricidia sepium Hbr. And cow dung with banana nutrition on the composting process on the C/N ratio. This research was conducted with the aim of knowing the effect of the composition and the length of time required for fermentation. Composting was made with a variety of cow dung : gliricidia sepium Hbr. In a ratio of 1:9, 1:1, 3:2, 7:3, 9:1, and 2:3 in % by using 25% banana nutrition and 100% water from the total weight of the manure. On this research was found that the optimal time is on 14th day with characteristic of compost that was produced, equal with the the Indonesia National Standar (SNI Kompos 19-7030-2004). The conclusion is the compcsition of cow dung and Gliricidia sepium leaves did not significant affect to the C/N compost ratio.
Pemanfaatan Silika Gel Hasil Pengolahan Abu Tongkol Jagung Termodifikasi TiO2 untuk Mengurangi Kadar Nitrat dalam Limbah Cair Tahu Lulan, Theodore Y. K.; Ndolu, Intan C. M.; Nitti, Fidelis
Chemistry Notes Vol 5 No 2 (2023): Chem Notes, 5(2), 2023
Publisher : Universitas Nusa Cendana

Show Abstract | Download Original | Original Source | Check in Google Scholar

Abstract

Research has been conducted with the title Utilization of Silica Gel from the processing of TiO2-Modified Corn Cob Ash to Reduce Nitrate Levels in Tofu Liquid Waste. This study aims to determine the characteristics of silica gel from the processing of TiO2-modified corn cob ash in terms of functional groups and crystallinity and to determine the effectiveness of TiO2-modified silica gel to reduce nitrate levels in tofu liquid waste using pH, time and concentration parameters. The synthesis of silica gel from corn cob ash was carried out using the sol gel method. The results of FTIR characterization showed the successful synthesis of silica gel and TiO2 modified silica gel indicated by the presence of Si-O-Si and Si-OH absorption in silica gel and Ti-O-Ti absorption in TiO2 modified silica gel. The XRD data shows that silica gel has an amorphous structure and modified silica gel has an anatase structure. The results showed that the largest nitrate reduction occurred at pH 5 by 98.69%, contact time of 60 minutes by 97.39% and optimum concentration of 200 ppm by 98.94% with the largest silica adsorption capacity of 245.94 mg/g and the percentage of nitrate reduction in tofu liquid waste by 99.94%.