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Indonesian Journal of Chemistry

ijc
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Published by Universitas Gadjah Mada

ISSN : 14119420 EISSN : 24601578 DOI : -

Core Subject : Science, Engineering,

Chemical Engineering, Chemistry & Bioengineering Chemistry

Indonesian Journal of Chemistry is an International, peer-reviewed, open access journal that publishes original research articles, review articles, as well as short communication in all areas of chemistry including applied chemistry. The journal is accredited by The Ministry of Research, Technology and Higher Education (RISTEKDIKTI) No : 21/E/KPT/2018 (in First Rank) and indexed in Scopus since 2012. Since 2018 (Volume 18), Indonesian Journal of Chemistry publish four issues (numbers) annually (February, May, August and November).

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Articles 30 Documents

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Search results for , issue "Vol 19, No 4 (2019)" : 30 Documents clear

Combined Computational and Experimental Study the Effect of Doped Magnesium into Betanine-sensitized TiO2 Photoanode for Dye-Sensitized Solar Cells Application Yuly Kusumawati; Nanik Ismi Oktavianti; Linda Wati Oktavia; Nurul Widiastuti; Lukman Atmaja; Nur Izzati Abu Bakar; Nur Hadi
Indonesian Journal of Chemistry Vol 19, No 4 (2019)
Publisher : Universitas Gadjah Mada

A preliminary study of the effect of magnesium-doped into betanine-sensitized TiO2 thin layers has been carried out computationally and experimentally. The computational calculation was performed to observe the effect of magnesium on the interaction molecular of betanine onto TiO2 surface, using Ti12O28H8 model cluster. It was found out that the distance of the oxygen on the anchoring site betanine with the Ti in TiO2/Mg cluster is shortercompare to that one in TiO2 cluster. This result confirms the bond between betanine and TiO2 is stronger in the case of Mg2+ incorporation. The Natural Population Calculation also confirms that the electron transport from betanine to the TiO2 is more facilitated after Mg2+ incorporation. These results are also supported by the HOMO-LUMO profile of TiO2-betanine and TiO2/Mg. The XRD and SEM measurement confirm those are no effect on the TiO2 structure and morphology with the incorporation of Mg2+. The thin-film UV-Vis measurement confirms there is a bandgap sift after the incorporation of Mg.

Solubility Enhancement of Simvastatin through Surfactant Addition for Development of Hydrophobic Drug-Loaded Gelatin Hydrogel Niswati Fathmah Rosyida; Pinandi Sri Pudyani; Akhmad Kharis Nugroho; Ika Dewi Ana; Teguh Ariyanto
Indonesian Journal of Chemistry Vol 19, No 4 (2019)
Publisher : Universitas Gadjah Mada

This study aims to synthesize simvastatin hydrogel as drug delivery system with surfactant addition for improving solubility of simvastatin. Surfactants used in the study were the zwitterionic amino acid of arginine and nonionic surface-active agent of polysorbate 80. The solubility study was conducted by pouring of an excess mass of simvastatin into the solution of a surfactant in a conical flask. The sample was shaken up to 72 h in a mechanical water bath shaker at a varied temperature of 25, 40, and 50 °C. The amount of drug dissolved in solution was analyzed by UV/Visible spectrophotometer at 238 nm. The results showed that the simvastatin solubility is profoundly influenced by the surfactant type, surfactant concentration, and temperature. Polysorbate 80 exhibited as a better surfactant than arginine and an enhancement up to 1400 times, in respect of without any addition of a surfactant, was observed. Based on the solubility study, simvastatin-loaded gelatin hydrogel composite was formulated and the characterization (FTIR and SEM) showed the successful impregnation. The hydrogel microparticles of featured swelling indexes in the range of 2–6 for every patch and presented a sustained release profile.

Optimization and Kinetics of Zirconium Oxychloride (ZOC) Dissolution Using HNO3 Maria Veronika Purwani; Muzakky Muzakky
Indonesian Journal of Chemistry Vol 19, No 4 (2019)
Publisher : Universitas Gadjah Mada

The design of chemical reactor can not be separated from the optimization data and reaction kinetics obtained from the experimental measurement. Through the idea of making the dissolution reactor design, the purpose of this research is to obtain optimization data and dissolution kinetics of Zirconium Oxide Chloride (ZOC) using HNO3. The design of the solvent reactor is required to make the feedstock in the liquid-liquid extraction process continuously. The extraction process is a mini-pilot plant unit as a nuclear-grade zirconia manufacture. The dissolution optimization was carried out by dissolving ZOC solids of zircon sand processed products using HNO3 in a container with some variation of contact time, HNO3 concentration and temperature. While the kinetics data was gained by extracting from the optimization data obtained based on the formula of reaction orders. The investigation result with 6 gr of ZOC and 6M HNO3 concentration obtained the best contact optimum time of 2 minutes and the conversion number (α) of 0.96. The dissolution reaction mechanism was estimated in accordance with the reaction of order 1 with the k value of 1.5879 minutes-1. It was predicted that the reaction mechanism of ZOC dissolution in HNO3 begins with diffuse control and is followed by chemical reaction control. With increasing conversion temperature, the conversion will increase to 0.98, while the reaction also follows the reaction order 1. The optimum temperature at 60 °C, and the correlation between temperature (T) with the calculated reaction rate constant (k) according to the Arrhenius formula yielded an equation of ln k = - 4191,6 / T + 13,903 or k = 13,903.e- 4191,6 / T, with the frequency factor A = 1091430 and the activation energy E = 34,848 kJ / mole.

Incorporation CdS with ZnS as Composite and Using in Photo-Decolorization of Congo Red Dye Faten Hadi Fakhri; Luma Majeed Ahmed
Indonesian Journal of Chemistry Vol 19, No 4 (2019)
Publisher : Universitas Gadjah Mada

The aim of this manuscript was to modify the ZnS surface by incorporating with CdS photocatalyst. This manner led to depressing the recombination process and increasing the activity. The X-ray Powder Diffraction (XRD) data were proved that the CdS incorporated with ZnS and formed ZnS-CdS nanocomposite by observing new peaks at 26.92, 28.62, 30.52, and 47.26°. Based on the Atomic Force Microscopy (AFM) analysis and Tauc equation, the particle sizes for all samples were raised with decreased the band gap values. The activation energy for decolorization of Congo red with the using ZnS is found to be more than that value for the using prepared ZnS-CdS composite. The percentage of efficiency was found to be increased with modified the ZnS surface.

Distribution Pattern of Volcanic Ash Essential Elements on the Top Layer of Agricultural Land Post Merapi Eruption in Sleman Sri Murniasih; Darsono Darsono; Sukirno Sukirno; Saefurrochman Saefurrochman
Indonesian Journal of Chemistry Vol 19, No 4 (2019)
Publisher : Universitas Gadjah Mada

Volcanic ash contains essential elements to the soil fertility of agricultural land which is important to be investigated. The aim of this study was to determine the distribution pattern of volcanic ash essential elements as a result of volcanic eruption disaster using Surfer software. To input, the Surfer software, soil samples of volcanic ash at 10 sampling locations in Sleman at a radius of 14 to 26 km towards the south from a peak of Merapi were collected. Data of wind direction, humidity and ground level at the time of sampling were also collected. The concentrations of the essential element in samples were measured using NAA (neutron activation analysis). The pH of volcanic ash samples in each sampling locations was also measured. The results showed that volcanic ash for all sampling locations contained, Al, Fe, Na, K, and Si as major elements and Zn, Co, and Se as trace elements. The concentration distribution pattern of the Zn, Si, Co and Fe elements tends to decrease towards the peak of Merapi, on the other hand, the Na, and K elements showed that their distribution concentration tends to decrease away from the peak of Merapi. The wind’s speed affects the distribution range of an element contained in volcanic ash samples. The pH of volcanic ash samples seemingly only affect the concentration of Zn elements in the distribution pattern of elements.

Preparation of Poly-(GMA-EDA-β-CD-co-TMPTMA) Monolith as High Performance Liquid Chromatography Chiral Stationary Phase Column Stevin Carolius Angga; Dias Septiana; Suci Amalia; Warsito Warsito; Elvina Dhiaul Iftitah; Akhmad Sabarudin
Indonesian Journal of Chemistry Vol 19, No 4 (2019)
Publisher : Universitas Gadjah Mada

An enantiomer molecule consisted of the chiral atom has different structure conformations, which exhibit different activities as well. Yet, its separation considerably difficult since ordinary separation could not separate both molecules. One of the popular enantioseparations which are often used was using organic polymer monolithic column modified by ethylenediamine-β-cyclodextrin (EDA-β-CD) as the enantioseparations site. The aim of this research was to produce chiral stationary phase column for enantioseparations of (±)-citronellal. It was conducted by preparing monolithic column using monomer glycidyl methacrylate (GMA), trimethylolpropane trimethacrylate (TMPTMA) as crosslinker, 1-propanol, 1,4-butanediol, and water as pore-forming agents (porogens) in the presence of α,α'-azoisobutyronitrile (AIBN) as radical initiator inside polyetheretherketone (PEEK) tubing. It was then modified with EDA-β-CD synthesized from β-CD. Finally, it was installed as a high-performance liquid chromatography column. The result shows the produced chiral stationary phase column could separate (±)-citronellal at a retention time of 44.76 and 45.71 min.

New Potential Demulsifiers Obtained by Processing Gossypol Resin Nurlybek Shyrynbekuly Otarbaev; Vladimir Mikhailovich Kapustin; Kazim Sadykovich Nadirov; Gulmira Zhankabylovna Bimbetova; Manap Kurmanbekovich Zhantasov; Rashid Kazimovich Nadirov
Indonesian Journal of Chemistry Vol 19, No 4 (2019)
Publisher : Universitas Gadjah Mada

Water contained in crude oil, forms so-called water-in-oil emulsions, the presence of which negatively affects the transportation and processing of oil. Demulsifiers are the special mixtures that are used to remove water from emulsions. The present paper is devoted to obtaining the demulsifiers by catalytic acid esterification of fatty acids mixture extracted from gossypol resin with isopropanol. Fourteen mixtures, containing mainly fatty acids and their ethers, were obtained and tested for demulsifying performance by using the bottle test. The relationship of the following values with the demulsibility of final mixtures was determined: the conditions of fatty acids esterification, the content of fatty acids in the demulsifier, the relative solubility number of the demulsifier, the toluene/water dynamic interfacial tension. The following conditions of fatty acids mixture esterification provided 64.8% of water removal at the dosage of 20 ppm of demulsifier: 385 K; 4 h; H2SO4/fatty acids mixture ratio 2.5 wt.%.

Effect of Rice Husk Ash on the Physicochemical Properties of Compost Nur Ezyan Badrul Hisham; Nor Hanuni Ramli
Indonesian Journal of Chemistry Vol 19, No 4 (2019)
Publisher : Universitas Gadjah Mada

Recently, the increase in demand for rice has led to the numerous availabilities of rice husks (RH) in Malaysia. RH is being utilized as industrial fuel to generate electricity through incineration process in the boiler. During the incineration process, rice husk ash (RHA) is being produced as the by-product and caused environmental pollution. RHA has the potential of being utilized as organic fertilizer through a composting process to control environmental pollution. Thus, this study investigated the effect of different compositions on the duration of the composting process and physicochemical properties of compost. The raw materials and finished compost were analyzed in terms of elemental composition, pH, water holding capacity, and moisture content. The obtained results showed that addition of 7.5 wt.% of RHA can improve composting process due to the presence of silica which can maintain the moisture content within 50–60% and water holding capacity of compost at the range of 61-73%. The results of this study have clearly shown the potential of the compositing process in treating RHA. However, further studies are required to provide a deeper understanding of the mechanisms involved in facilitating the development of an optimum treatment system applicable to the industry.

Selective Hierarchical Aluminosilicates for Acetalization Reaction with Propylene Glycol Hartati Hartati; Mardi Santoso; Hadi Nur; Leaw Wai Loon; Hasliza Bahruji; Imroatul Qoniah; Didik Prasetyoko
Indonesian Journal of Chemistry Vol 19, No 4 (2019)
Publisher : Universitas Gadjah Mada

Hierarchical micro-mesoporous aluminosilicates nanoparticles were synthesized at different of Si/Al ratios and were directly used as a solid acid catalyst for acetalization reaction with propylene glycol. TEM and N2 adsorption analysis of the resulting aluminosilicates revealed the formation of the hierarchical structure occurs on the Si/Al ratio increases the formation of mesoporous within the structure of aluminosilicate. The aluminosilicates exhibit high selectivity towards acetalization reaction in comparison with the homogeneous PTSA. The presence of mesoporous structures is crucial for increased conversion and selectivity of the reaction which presumably due to the improved diffusion of substrate to reach acid sites.

Stabilization of Silicone Dioxide Nanoparticle Foam in Tertiary Petroleum Production Mohd Zulkifli bin Mohamad Noor; Wong Yi Teng; Sonny Irawan
Indonesian Journal of Chemistry Vol 19, No 4 (2019)
Publisher : Universitas Gadjah Mada

Nanoparticles have emerged with substantially to the end user and industrial applications. The applications initiated to enhance oil recovery (EOR) and also as alternative solution in increasing the rheological properties of fluids at difference condition. The study aims to evaluate the effects of various surfactant and nanoparticle concentration as well as hydrocarbons on foam stability. Series of static state experiments were conducted to investigate the foam development stability of five different concentrations for surfactant from 0.05 to 0.25 wt.% and nanoparticle from 0 to 1.00 wt.% in the presence of white mineral oil in synthetic brine suspension. By discussing to the Ross-Miles method - half-life capacities (t½), the foam stability of the aqueous foam was expected. Results suggested that the foam stability is increase with the present of nanoparticle. The 0.5 wt.% SiO2 nanoparticles enhanced foam formed the most lasting in the absence of white mineral oil as its t½ in presence of oil is 0.6 times smaller than in the absence of oil. It is concluded that the presence of nanoparticles for surfactant foam stability can be enhanced. The used of nanoparticles can be further study with different type of nanoparticles, only with small amount of nanoparticles used can further stabilize the foam.

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