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Indonesian Journal of Chemistry

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Published by Universitas Gadjah Mada

ISSN : 14119420 EISSN : 24601578 DOI : -

Core Subject : Science, Engineering,

Chemical Engineering, Chemistry & Bioengineering Chemistry

Indonesian Journal of Chemistry is an International, peer-reviewed, open access journal that publishes original research articles, review articles, as well as short communication in all areas of chemistry including applied chemistry. The journal is accredited by The Ministry of Research, Technology and Higher Education (RISTEKDIKTI) No : 21/E/KPT/2018 (in First Rank) and indexed in Scopus since 2012. Since 2018 (Volume 18), Indonesian Journal of Chemistry publish four issues (numbers) annually (February, May, August and November).

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Articles 25 Documents

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Search results for , issue "Vol 20, No 6 (2020)" : 25 Documents clear

An Investigation on the Effect of Solvent and Heat to Clay Minerals in Shaly Sandstone Wan Zairani Wan Bakar; Ismail Mohd Saaid; Mohd Riduan Ahmad; Husna Hayati Jarni; Siti Qurratu’ Aini Mahat
Indonesian Journal of Chemistry Vol 20, No 6 (2020)
Publisher : Universitas Gadjah Mada

Core cleaning could be complicated for samples that contain a high amount of clays. Some clays are delicate and exposure to solvent and heat would damage or alter its properties. In this study, we investigated the effect of direct exposure of solvent and heat to clay mineral properties based on petrographical data from X-Ray Diffraction (XRD), Fourier Transform Infrared Spectroscopy (FTIR), Field Emission Scanning Electron Microscope (FESEM) and Energy Dispersive X-Ray (EDX). Experiments were performed on sidewall core samples taken in a shaly sand zone. The FTIR data did not show any changes at the molecular level to the clay mineral after direct contact with the selected solvent. The FESEM images showed some illite floccules collapse in the samples exposed to oven-drying at 60 °C.

Metabolic Changes in the Trichomes of Cannabis sativa var. bedrobinol Analyzed by 1H-NMR-Based Metabolomics Nizar Happyana; Oliver Kayser
Indonesian Journal of Chemistry Vol 20, No 6 (2020)
Publisher : Universitas Gadjah Mada

Trichomes of Cannabis sativa are the main tissue for synthesizing and storing cannabinoids, the most interesting compounds in this plant. In this report, metabolic changes in the trichomes of C. sativa var. bedrobinol were investigated by 1H-NMR-based metabolomics over the flowering session. Three cannabinoids, including Δ9-tetrahydrocannabinolic acid (THCA), cannabichromenic acid (CBCA), and Δ9-tetrahydrocannabinol (THC), were successfully identified in the chloroform extracts of the Cannabis trichomes. Meanwhile, 20 non-cannabinoid compounds, including sugars, amino acids, and other acidic constituents, were detected in the water extracts. Metabolic changes of the Cannabis trichomes during the monitoring time were successfully revealed using the models of partial least squares discriminant analysis (PLSDA) and 1H-NMR quantitative analysis. Score plots of the PLSDA models classified metabolomes based on the harvest time. Discriminant metabolites for the differentiation were detected in the loading plots of the models. THCA was found as an important discriminant compound in the chloroform extracts, while all quantified water-soluble compounds were detected, contributing to the metabolic changes of the water extracts. The obtained results shed more light on the biosynthesis of metabolites in the Cannabis trichomes over the flowering season.

Cytotoxic Sesquiterpenoids from the Stem Bark of Aglaia harmsiana (Meliaceae) Hersa Milawati; Winda Sukmawati; Desi Harneti; Rani Maharani; Nurlelasari Nurlelasari; Ace Tatang Hidayat; Darwati Darwati; Unang Supratman; Yoshihito Shiono
Indonesian Journal of Chemistry Vol 20, No 6 (2020)
Publisher : Universitas Gadjah Mada

Three aromadendrane-type sesquiterpenoids, spathulenol (1), 4β,10α-dihydroxyaromadendrane (2), and 4α,10α-dihydroxyaromadendrane (3) were isolated from the stem bark of Aglaia harmsiana (Meliaceae). Compound 3 was isolated for the first time from Aglaia genus. The chemical structures of isolated compounds were elucidated by various spectroscopic methods, including one and two-dimensional NMR, as well as mass spectroscopy analysis. These sesquiterpenoids 1-3 were evaluated for their cytotoxic activity against MCF-7 breast cancer cell lines. The IC50 value of compound 1-3 were 31.65 ± 0.1, 8.41 ± 0.04 and 2.80 ± 0.02 µM, respectively. Among the aromadendrane-type sesquiterpenoids, compounds 2 and 3, which do not have a double bond, showed higher activity than compound 1. Whereas, compound 3 showed the strongest activity indicate that α configuration of hydroxyl group increases the cytotoxic activity.

Batik Wastewater Treatment Using Simultaneous Process of Electrocoagulation and Electro-Assisted Phytoremediation (EAPR) Rudy Syah Putra; Aprilia Dwi Annisa; Sigit Budiarjo
Indonesian Journal of Chemistry Vol 20, No 6 (2020)
Publisher : Universitas Gadjah Mada

The aims of the study are to identify the effectiveness of wastewater treatment from the Batik industry using a simultaneous of electrocoagulation (EC) and electro-assisted phytoremediation (EAPR). Rough horsetail (Equisetum hyemale) was used as an accumulator plant in the EAPR system. Electrocoagulation was conducted for 1 h at a constant voltage of 20 V in 10 L solution, while EAPR was processed for 7 day at a constant voltage of 5 V in 17 L solution. The chemical oxygen demand (COD) of water was determined by closed reflux of colorimetric methods and heavy metal concentration was determined by flame-atomic absorption spectrophotometer. The results showed that the COD decreased by 69.6% after 1 h of electrocoagulation process and up to 80.9% after the EAPR process. The concentration of Cr and Pb decreased as much as 25% and 8.52%, respectively in the similar process. The simultaneous process could extend the heavy metal removal up to 0.28 mg/L for Cr and 0.09 mg/L for Pb in liquid wastewater from the initial concentration. These results showed that the levels of COD and heavy metal concentration in Batik wastewater have reduced in accordance with the Ministry of Environment Decree No. 5/2014 Republic of Indonesia regarding various industries wastewater standard with the threshold limit of 150 mg/L for COD and 1.0 mg/L for Cr on textile industry and 0.1 mg/L for Pb on Class I for another wastewater standard. The estimated cost of operation was US$ 1.509 m–3 indicating the viability of Batik industry wastewater treatment.

The Effect of Red Palm Oil Concentration towards Characteristics and Biodegradability of PLA-Starch Film Siti Fatma Abd Karim; Nur Aliah Adilla Mohammad Asri; Rabiatul Adawiyah Abdol Aziz; Ummi Kalthum Ibrahim
Indonesian Journal of Chemistry Vol 20, No 6 (2020)
Publisher : Universitas Gadjah Mada

Polylactic acid (PLA) is a biodegradable polymer that had been used as a substitute for conventional petroleum based plastics. Plasticizers were added into the solution of PLA and starch (PLA/S) to increase the flexibility and degradability of the produced film. PLA/S films need plasticizers that able to improve the degradation process. Red palm oil (RPO) were incorporated into PLA/S blends. The films were casted into petri dish via casting method. The films were characterized based on the color, thickness and chemical composition (Fourier-transform infrared spectroscopy). The performance of the films was analyzed based on tensile strength and biodegradation percentage. The films were yellowish in color with the addition of RPO. The FTIR shows that the increment of RPO concentration modified the intermolecular interaction between the PLA/S molecules. The tensile strength of PLA decreased with the addition of starch. The biodegradability test was done by using soil burial method where the samples were buried in peaty soil for 12 days. The films produced from these combinations resulted in a good biodegradable activity. The films with high concentration of RPO and presence of starch degraded 100% within 12 days. RPO can be used as the plasticizer with further improvement.

In-Situ Ionic Imprinted Membrane (IIM) Synthesis Based on Acetic Polyeugenoxy Acetyl Tiophen Methanolate for Gold(III) Metal Ion Transports Muhammad Cholid Djunaidi; Pardoyo Pardoyo; Didik Setiyo Widodo; Retno Ariadi Lusiana; Anggun Yuliani
Indonesian Journal of Chemistry Vol 20, No 6 (2020)
Publisher : Universitas Gadjah Mada

In this research, Polyeugenoxy Acetyl Tiophen Methanolate (PEATM)-Au ionic imprinted membrane (IIM) was synthesized. IIM is a PEATM based membrane that has Au(III) ion molds. The PEATM synthesis was analyzed using FTIR spectroscopy, and its relative molecular weight was determined by the viscometry method. To find out the presence of Au(III) templates on IIM, FTIR spectroscopy and SEM-EDX were used. The results of FTIR spectroscopy & SEM-EDX analysis prove the existence of Au(III) metal ion templates at IIM. Through FTIR spectra, it could be seen that the absorption area of the -OH group was widening. In the IIM, the CS group wave number (702.9 cm–1) also shifted to a larger wavenumber (848.68 cm–1), this is likely due to the presence of PEGDE as a crosslinker agent and PVA as a plasticizer on the membrane that interacts with PEATM-Au, which influences the shift of vibrational wavenumber of CS bonds. It was also found that the most effective pH of the feed phase for the transport was at pH 3, and the most optimum transport time was 24 h for IIM and 48 h for NIM. The transport of Au in binary mixture of Au/Cd, Au/Fe, and Au/Pb also proves that the presence of Au(III) ions in IIM makes IIM more selective to Au(III) metal ions than NIM when used for the transport process as it transports Au more than the other metals. These results were as expected by using the HSAB theory as its groundwork.

Hydrochemical Evolution in Ciliwung River – Java, Indonesia: Study of Sea Water Mixture and Mineral Dissolution Evarista Ristin Pujiindiyati; Paston Sidauruk; Tantowi Eko Prayogi; Faizal Abdillah
Indonesian Journal of Chemistry Vol 20, No 6 (2020)
Publisher : Universitas Gadjah Mada

The chemical characteristics of the Ciliwung River were analyzed to understand hydrochemical evolution. A fraction of sea water mixture and kinds of mineral controlling for chemicals were also determined. During three year investigations in 2015, 2016, and 2018, electrical conductivity increased with decreasing elevations. Two hydrochemical facies had been identified for the Ciliwung river water; those were Ca-Mg-HCO3 and Ca-Na-HCO3. The river water mixing with seawater was recognized in the Mangga Dua site in which its water type had shifted to Na-Ca-HCO3-Cl. Based on Na-Cl contents, the fraction of sea water into the Ciliwung River reached 2% in the Mangga Dua site during the dry season and decreased to 0.7% during the rainy season in 2015. The much higher monthly rainfall during the dry season in 2016 and 2018 had washed out invading seawater from the Mangga Dua site; its fraction of sea water was less than 0.4%. Saturation indexes with respect to calcite, dolomite, and gypsum minerals showed an increasing trend related to the decreasing elevations. All water samples were undersaturated with respect to gypsum. Meanwhile, saturation indexes with respect to calcite and dolomite mostly indicated undersaturated, except in the Mangga Dua site that was saturated (during the rainy season in 2015 and dry season in 2018) and supersaturated during the dry season in 2015.

Zinc-Doped Titania Embedded on the Surface of Zirconia: A Potential Visible-Responsive Photocatalyst Material Azizia Alifi; Rian Kurniawan; Akhmad Syoufian
Indonesian Journal of Chemistry Vol 20, No 6 (2020)
Publisher : Universitas Gadjah Mada

The preparation and characterization of zirconia-supported titania with a zinc dopant had been studied. Zinc-doped titania was grown on the surface of zirconia by the sol-gel method. Various zinc contents and calcination temperatures were applied to investigate the zinc doping effect and crystal structure of the zirconia-titania composite. X-ray diffraction method, Fourier-transform infrared spectroscopy, and UV-Vis reflectance spectroscopy were performed to characterize the composite. The morphology of the composite was observed by using a scanning electron microscope, and its composition was analyzed by using energy dispersive spectroscopy. Among various zinc dopant contents and calcination temperatures investigated, doping with 5% zinc (Zn wt./Ti wt.) at 900 °C calcination shows the best result in response to visible light with a bandgap of 2.87 eV and absorption edge wavelength of 432.61 nm.

Synthesis and Certification of Lanthanum Oxide Extracted from Monazite Sand Samin Samin; Suyanti Suyanti; Susanna Tuning Sunanti; Wisnu Ari Adi
Indonesian Journal of Chemistry Vol 20, No 6 (2020)
Publisher : Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22146/ijc.44327

Synthesis and certification of lanthanum oxide extracted from monazite sand have been carried out. This research aimed to increase the added value of monazite sand and obtain the lanthanum oxide in-house certified reference material (CRM). Synthesis of lanthanum oxide consists of several stages, namely: monazite sand digestion, rare-earth elements hydroxide [REE(OH)3] precipitation, Ce separation, Nd separation, lanthanum oxalate precipitation, and calcination. Certification of lanthanum oxide was carried out by determining the average concentration of the oxides and its uncertainty from the seven accredited laboratories by the ISO 35-2006 statistical method. Two other minerals in the lanthanum oxide analyzed by the XRD method were cerium hydroxide [Ce(OH)3] and neodymium yttrium oxide fluoride (Nd2Y2O3F16). Lanthanum oxide certified contains ten oxides, with the two highest concentrations of La2O3 (91.662 ± 0.007)% and Nd2O3 (3.949 ± 0.002)%. Lanthanum oxide has met the qualification in-house CRM since it contained water less than 1%, was homogeneous, stable, and certified. La2O3 concentration in the lanthanum oxide in-house CRM from CSAT-BATAN, Indonesia was not significantly different in comparison to that from the Department of Chemical Engineering, Srinakharinwirot University, Thailand. Lanthanum oxide extracted from monazite sand can be used as reference material in determining the lanthanum oxide quality from the pilot plant process.

Design of Defect and Metallic Silver in Silver Phosphate Photocatalyst Using the Hydroxyapatite and Glucose Uyi Sulaeman; Suhendar Suhendar; Hartiwi Diastuti; Roy Andreas; Shu Yin
Indonesian Journal of Chemistry Vol 20, No 6 (2020)
Publisher : Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22146/ijc.48647

The defect and metallic silver (Ag) in silver phosphate (Ag3PO4) photocatalyst were successfully generated using hydroxyapatite (HA) and glucose. Two steps of synthesis were done in these experiments. Firstly, the Ag/HA powder was prepared by reacting AgNO3 and HA, followed by the addition of a glucose solution. Secondly, the suspension of Ag/HA was reacted with AgNO3 aqueous solution. The yellow product of Ag/Ag3PO4 photocatalyst was produced. The products were characterized using X-Ray Diffraction (XRD), Diffuse Reflectance Spectroscopy (DRS), Scanning Electron Microscope (SEM), Brunauer–Emmett–Teller (BET) and X-ray Photoelectron Spectroscopy (XPS). The decreased ratio of O/Ag and metallic Ag formation observed by the XPS was detected as the possible defect and Ag-doping in the photocatalyst. The enhanced photocatalytic activity might be caused by the oxygen vacancy and metallic Ag in Ag3PO4 that enables the separation of photo-generated electrons and holes.

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