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Indonesian Journal of Chemistry

ijc
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Published by Universitas Gadjah Mada

ISSN : 14119420 EISSN : 24601578 DOI : -

Core Subject : Science, Engineering,

Chemical Engineering, Chemistry & Bioengineering Chemistry

Indonesian Journal of Chemistry is an International, peer-reviewed, open access journal that publishes original research articles, review articles, as well as short communication in all areas of chemistry including applied chemistry. The journal is accredited by The Ministry of Research, Technology and Higher Education (RISTEKDIKTI) No : 21/E/KPT/2018 (in First Rank) and indexed in Scopus since 2012. Since 2018 (Volume 18), Indonesian Journal of Chemistry publish four issues (numbers) annually (February, May, August and November).

Arjuna Subject : -

Articles 1,981 Documents

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THE ANTIBACTERIAL COMPOUND COLLISMICIN A DERIVED FROM MARINE Streptomyces sp Q-629K Tutik Murniasih; Kyoko Adachi
Indonesian Journal of Chemistry Vol 8, No 3 (2008)
Publisher : Universitas Gadjah Mada

In our course of screening for secondary metabolite derived from marine bacterial, we isolate the antimicrobial compound collysmicin A from the ethyl acetate extract of Streptomyces sp Q-629K. Separation of this compound was carried out by silica gel open column chromatography. Purification of an active compound was done using HPLC C18 with acetonitril-water system. Determination of chemical structure was done by 1H, 13C NMR and LC-MS analysis. Collysmicin A was contained in fraction 3, fraction 7.2 and fraction 8.7. The antimicrobial assayed from purified compound Fr.8.7 gave diameter inhibition approximately 13 mm against S. aureus and 12 mm against B. subtilis.

CONTROLLING FACTOR IN ALUMINA PILLARED SAPONITE AND ALUMINA PILLARED MONTMORILLONITE SYNTHESIS Is Fatimah; Narsito Narsito; Karna Wijaya
Indonesian Journal of Chemistry Vol 9, No 1 (2009)
Publisher : Universitas Gadjah Mada

The effect of synthesis parameters to the physical properties of pillared saponite and pillared montmorillonite was examined. Mol ratio of Al to clay mass in the range 1.0 - 5.0 and two different calcination methods; conventional calcination and microwave irradiation method are evaluated as controlling factors to evolution of basal spacing d001 , surface acidity, specific surface area, pore distribution and catalytic activity in phenol hydroxylation reaction. XRD, FTIR, and N2-adsorption/desorption analysis were used to characterize the materials. Results showed that pillarization produced higher basal spacing d001 and surface acidity and crystalinity of materials in all Al/clay ratio and in both of the calcination methods. In general, Al to clay mass ratio and calcination method remarkably influence to the basal spacing d001, surface acidity and material crystallinity, but the effect of these factors to catalyst activity in phenol hydroxylation depends on nature of clay. It is concluded that the activity as catalyst is affected by the presence of ionic species and surface acidity in the minerals.

SYNTHESIS OF TERPINEOL FROM α-PINENE CATALYZED BY TCA/Y-ZEOLITE Nanik Wijayati; Harno Dwi Pranowo; Jumina Jumina; Triyono Triyono
Indonesian Journal of Chemistry Vol 11, No 3 (2011)
Publisher : Universitas Gadjah Mada

The hydration of a-pinene has been studied in the presence of TCA/Y-Zeolite catalyse. The catalyst was prepared by impregnating trichloroacetic acid (TCA) on support of Y-Zeolite. The TCA/Y-Zeolite catalyst converted a-pinene into hydrocarbons, while the TCA/Y-Zeolite catalyst was active and selective for producing alcohols, with a conversion of 66% and showed 55% selectivity for α-terpineol at 10 min. The reaction taken place in a solid-liquid mode and most of the α-terpineol is extracted out by the organic phase during the course of the reaction. TCA/Y-Zeolite was found as good catalyst for hydration of α-pinene to produce α-terpineol.

QUANTITATIVE ELECTRONIC STRUCTURE - ACTIVITY RELATIONSHIPS ANALYSIS ANTIMUTAGENIC BENZALACETONE DERIVATIVES BY PRINCIPAL COMPONENT REGRESSION APPROACH Yuliana Yuliana; Harno Dwi Pranowo; Jumina Jumina; Iqmal Tahir
Indonesian Journal of Chemistry Vol 4, No 1 (2004)
Publisher : Universitas Gadjah Mada

Quantitative Electronic Structure Activity Relationship (QSAR) analysis of a series of benzalacetones has been investigated based on semi empirical PM3 calculation data using Principal Components Regression (PCR). Investigation has been done based on antimutagen activity from benzalacetone compounds (presented by log 1/IC50) and was studied as linear correlation with latent variables (Tx) resulted from transformation of atomic net charges using Principal Component Analysis (PCA). QSAR equation was determinated based on distribution of selected components and then was analysed with PCR. The result was described by the following QSAR equation :log 1/IC50 = 6.555 + (2.177).T1 + (2.284).T2 + (1.933).T3The equation was significant on the 95% level with statistical parameters : n = 28 r = 0.766 SE = 0.245 Fcalculation/Ftable = 3.780 and gave the PRESS result 0.002. It means that there were only a relatively few deviations between the experimental and theoretical data of antimutagenic activity. New types of benzalacetone derivative compounds were designed and their theoretical activity were predicted based on the best QSAR equation. It was found that compounds number 29, 30, 31, 32, 33, 35, 36, 37, 38, 40, 41, 42, 44, 47, 48, 49 and 50 have a relatively high antimutagenic activity.

FABRICATION AND CHARACTERIZATION OF CARBON COMPOSITE FROM COCONUT SHELL CARBON Meytij Jeanne Rampe; Bambang Setiaji; Wega Trisunaryanti; Triyono Triyono
Indonesian Journal of Chemistry Vol 11, No 2 (2011)
Publisher : Universitas Gadjah Mada

Structure and chemical composition of coconut shell carbon with polyvinyl alcohol (PVA) as the stimulant through the observation of TG-DTA, SEM-EDS and FTIR has been studied. The process was carried out by calcining coconut shell charcoal at the temperature of 873 and 1023 K under Nitrogen flow, then mixed with polyvinyl alcohol (PVA) under composition of 2.5 to 7.5% (wt) in water solvent. The growing of carbon composite structure was observed by heating the samples in Argon gas of 1673 K, the rate of temperature was 10 K/min in 3 h. The products were then analyzed by TG-DTA, SEM-EDS, FTIR and XRD. The result showed that the products were in uniform particle sizes of micrometer dimensions and spherical particles shape, with average content of C element was 97.44% (wt), aromatic character and semi-crystalline structure.

CHITOSAN PREPARATION WITH MULTISTAGE DEACETYLATION OF CHITIN AND INVESTIGATION OF ITS PHYSICOCHEMICAL PROPERTIES Ahmad Budi Junaidi; Indriana Kartini; Bambang Rusdiarso
Indonesian Journal of Chemistry Vol 9, No 3 (2009)
Publisher : Universitas Gadjah Mada

Study of chitosan prepared with chitin deacetylation by multistage alkali treatments has been done. Chitin was extracted from Lampung white shrimp's (Litophenaeus vannamei) shell. The FTIR spectroscopy was used to determine deacetylation degree of chitin/chitosan. Viscometry was used to determine molecular weight of chitosan. Effect of chitin deacetylation by multistage alkali treatments toward deacetylation degree and molecular weight was studied by comparingit with continuous alkali treatment. The results showed that chitosan prepared by multistage alkali treatment had higher deacetylation degree than those of obtained by continuous alkali treatment. Multistage alkali treatment does not influence the chitosan's molecular weight. Despite its significant effect on the deacetylation process, concentration of alkali does not significantly effect the process of depolimerization.

STUDY OF Cr(VI) PHOTOREDUCTION CATALYZED BY CDO-ZEOLITE Endang Tri Wahyuni; Mudasir Mudasir; Saudur Sinambela
Indonesian Journal of Chemistry Vol 2, No 2 (2002)
Publisher : Universitas Gadjah Mada

An attempt to decrease Cr(VI) ions in the solution which is more toxic than Cr(III) has performed by assisting the photoreduction of Cr(VI) ions catalysed by oxide Cd(II) supported in the zeolite pores (CdO-zeolite). The research consists of preparation, characterization, and photoactivity examination of CdO-zeolite. The preparation was carried out by ion-exchange method, which was followed by oxidation by flowing oxygen gas at 300oC. Analysis to determine the Cd adsorbed by zeolite and characterization to determine Eg as photocatalyst character was carried out by AAS and diffuses reflectance UV-Visible spectrophotometry (DRUV-Vis) methods, respectively. Photoreduction process was carried out in a closed reactor by radiating a suspension of Cr(VI) solution and CdO-zeolite with UV lamp for period of times. The concentration of unreduced Cr(VI) in the solution was determined by UV-Visible spectrophotometer as biphenyl carbacide complex. The results of the analysis and characterization indicated that the amount of Cd in CdO-zeolite is 46,832 mg/g and Eg of CdO-zeolite (3,26 eV) is larger than Eg of CdO (2,38 eV). Photocatalytic examination showed that the photoreduction results are proportional with the Eg values,i.e the results of Cr(VI) catalyzed by CdO-zeolit are higher than that of by CdO. Photoreduction of 50 mL solution Cr(VI) 25 ppm at pH = 7 catalyzed by 50 mg CdO- zeolite for 25 hours has given maximum result of 65,89 %.

CHARACTERISTIC OF ACRYLIC ACID GRAFTED POLYETHYLENE FILM PREPARED BY GAMMA IRRADIATION METHOD John Hendri; Irwan Ginting Suka; Wasinton Simanjuntak; Annisa Annisa; Gatot Gatot
Indonesian Journal of Chemistry Vol 8, No 1 (2008)
Publisher : Universitas Gadjah Mada

In this study, high density polyethylene (PE) film (thickness 80 μm) was modified by grafting of acrylic acid (AA) onto the film using 15 kGy of g irradiation as initiator, applied at different exposure times. In addition to irradiation dose, other variables investigated are concentration of AA, the type of solvent, and polymerization time carried out at 60 oC. The success of the graft copolymerization processes was confirmed by analysing the grafted film using FTIR spectroscopy, which revealed the existence of absorption band at wave number of 1721 cm-1(assigned to C=O), and that at 3385 cm-1 (assigned to -OH), and the physical endurance of the sample was evaluated by carrying out tensile strength measurement. The percent of grafting was determined according to the gravimetric method. The results indicated that the highest percent of grafting was obtained by application of 2-hour irradiation time, with monomer concentration of 30 % in water as a solvent, grafting temperature of 60 oC. Activity of grafted was evaluated by measurement of the absorption capacity toward water and Cu2+ ion, and revealed the increase of the absorption capacity with increased percent of grafting.

REACTION RESULT PREDICTION OF UO2 OXIDATION IN THERMOGRAVIMETRIC USE OF REGRESSION POLYNOMIAL Sahat Simbolon
Indonesian Journal of Chemistry Vol 5, No 2 (2005)
Publisher : Universitas Gadjah Mada

Thermogravimetric curve of UO2 oxidation reaction with oxygen from room temperature 25 oC to 425 oC had been depicted in three dimensions. The temperature oxidation reaction of UO2 sample was arranged 5 oC / minute and it was found that increasing of sample weight was 1.3 mg. Uranium dioxide (UO2) had not been reacted yet, reacted UO2, UO3 and U3O8 as the result of oxidation reaction were depicted in three dimensions. The nonlinear relationshps between temperature and time of oxidation reaction of UO2 were simulated in three dimensions using MATLAB Version 5.3 software version.

ANALYSIS AND IDENTIFICATION SPIKING CHEMICAL COMPOUNDS RELATED TO CHEMICAL WEAPON CONVENTION IN UNKNOWN WATER SAMPLES USING GAS CHROMATOGRAPHY AND GAS CHROMATOGRAPHY ELECTRON IONIZATION MASS SPECTROMETRY Harry Budiman
Indonesian Journal of Chemistry Vol 7, No 3 (2007)
Publisher : Universitas Gadjah Mada

The identification and analysis of chemical warfare agents and their degradation products is one of important component for the implementation of the convention. Nowadays, the analytical method for determination chemical warfare agent and their degradation products has been developing and improving. In order to get the sufficient analytical data as recommended by OPCW especially in Proficiency Testing, the spiking chemical compounds related to Chemical Weapon Convention in unknown water sample were determined using two different techniques such as gas chromatography and gas chromatography electron-impact ionization mass spectrometry. Neutral organic extraction, pH 11 organic extraction, cation exchanged-methylation, triethylamine/methanol-silylation were performed to extract the chemical warfare agents from the sample, before analyzing with gas chromatography. The identification of chemical warfare agents was carried out by comparing the mass spectrum of chemicals with mass spectrum reference from the OPCW Central Analytical Database (OCAD) library while the retention indices calculation obtained from gas chromatography analysis was used to get the confirmation and supported data of the chemical warfare agents. Diisopropyl methylphosphonate, 2,2-diphenyl-2-hydroacetic acid and 3-quinuclidinol were found in unknown water sample. Those chemicals were classified in schedule 2 as precursor or reactant of chemical weapons compound in schedule list of Chemical Weapon Convention.

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