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Indonesian Journal of Chemistry

ijc
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Published by Universitas Gadjah Mada

ISSN : 14119420 EISSN : 24601578 DOI : -

Core Subject : Science, Engineering,

Chemical Engineering, Chemistry & Bioengineering Chemistry

Indonesian Journal of Chemistry is an International, peer-reviewed, open access journal that publishes original research articles, review articles, as well as short communication in all areas of chemistry including applied chemistry. The journal is accredited by The Ministry of Research, Technology and Higher Education (RISTEKDIKTI) No : 21/E/KPT/2018 (in First Rank) and indexed in Scopus since 2012. Since 2018 (Volume 18), Indonesian Journal of Chemistry publish four issues (numbers) annually (February, May, August and November).

Arjuna Subject : -

Articles 1,981 Documents

58 59 60 61 62

EXTRACTION, CLEAN-UP, AND HPLC DETECTION OF CARBARYL AND CARBOFURAN FROM CABBAGE (Brassica oleracea) Iip Izul Falah
Indonesian Journal of Chemistry Vol 9, No 3 (2009)
Publisher : Universitas Gadjah Mada

Carbaryl (1-naphthyl-N-methylcarbamate) and carbofuran (2,3-dihydro-2,2-dimethyl-7-benzofuranol-N-methylcarbamate) are very important N-methylcarbamate pesticides due to their high insecticide and nematocide effects, and widely used in vegetables plantations. The increasing use of carbamate pesticides poses a risk to human and environment. Thus, it is necessary to quantify their residue amount in food and vegetables to prevent harmful effect on animals, human and environment. This work was aimed to study of carbaryl and carbofuran analysis from fortified cabbage (Brassica oleracea) by liquid-liquid extraction, clean-up using SPE, followed by HPLC detection. Result of the work showed that detection of carbaryl using spectrophotometer detector at wavelength of 220 nm was better than at 230 and 280 nm, respectively. When the carbamates were extracted from cabbage using methanol, followed by liquid-liquid extraction using dichloromethane, cleaned-up with SPE-C18 and eluted by acetonitrile, the recovery was 96.8%. The detection by HPLC involved 4.6 x 25 mm, 5 µm C18 column, spectrophotometer detector at wavelength of 220 nm, and isocratic mobile phase at ratio of 35:65 of acetonitrile:aquabidest gave a good separation between co-extracted compounds and the carbamates.

AN EFFICIENT SYNTHESIS OF 1,3-BENZODIAZINE-2,4-DIONES ANALOGS Fredryk Mandey
Indonesian Journal of Chemistry Vol 1, No 3 (2001)
Publisher : Universitas Gadjah Mada

An investigation of base promoted reaction of phenylanthranilate and isocyanate has been carried out. The reaction between phenylanthranilate (11) and phenylisocyanate and n-butylisocyanate gave remarkable yields of corresponding 1,3-Benzo-diazine-2,4-diones (12a) and (12b).

EFFECT OF SODIUM DODECYLBENZENESULFONIC ACID (SDBS) ON THE GROWTH RATE AND MORPHOLOGY OF BORAX CRYSTAL Suharso Suharso
Indonesian Journal of Chemistry Vol 7, No 1 (2007)
Publisher : Universitas Gadjah Mada

An investigation of the effect of sodium dodecylbenzenesulfonic acid (SDBS) on both growth rate and morphology of borax crystal has been carried out. This experiment was carried out at temperature of 25 °C and relative supersaturation of 0.21 and 0.74 under in situ cell optical microscopy method. The result shows that SDBS inhibits the growth rate and changes the morphology of borax crystal.

SYNTHESIS OF Fe2O3-MONTMORILLONITE AND ITS APPLICATION AS A PHOTOCATALYST FOR DEGRADATION OF CONGO RED DYE Karna Wijaya; Iqmal Tahir; Nanik Haryanti
Indonesian Journal of Chemistry Vol 5, No 1 (2005)
Publisher : Universitas Gadjah Mada

The preparation of Fe2O3-montmorillonite and it's application as a catalyst for congo red dye photodegradation has been carried out. Fe2O3-montmorillonite was prepared by mixing the iron complexes pillaring agent and montmorillonite. The product was calcined at 250 oC for 5 hours. Montmorillonite and calcined product was analyzed by X-ray diffractometry (X-RD), infrared spectrophotometry (FTIR), gas sorption analyser, X-ray fluorescense (X-RF) and UV/Vis diffuse reflectance spektrophotometry (UV-DRS). Fe2O3-montmorilonite then was used as a catalyst on congo red dye photodegrdation by UV-illuminating a mixture of 50 mg Fe2O3-montmorillonite and 25 mL congo red 10-4M at 365 nm at various illuminating times. Adsorption of congo red on Fe2O3-montmorillonite and montmorillonite was also performed as a comparison.Result of X-RD analysis showed that the 001 reflection of Fe2O3-montmorillonite was not detected that probably indicating the formation of house of card stucture and this result was supported also by the analysis result of distribution of pores and SEM photography result. Results of the XRF analysis showed that iron content increased from 5.21 % (w/w) in montmorillonite to 25.12 % (w/w) in Fe2O3-montmorillonite. UV- DRS analysis showed the increament of band gap energy from 3.69 eV in the iron oxide bulk to 3.8 eV in Fe2O3-montmorillonite. Specific surface area of the montmorillonite also increased significantly from 69,71 m2/g to 126,49 m2/g and total pores volume increased from 50.70x10-3 mL/Å/g to 107.89x10-3 mL/Å/g, respectively. Photodegradation of congo red using Fe2O3-montmorillonite caused the decreament of congo red concentration up to 90.22 % on UV illumination for 60 minutes. Adsorption of congo red on Fe2O3-montmorillonite reached 84.4% and on montmorillonite was 75.15 %.

SURFACE MODIFICATION OF SEMICONDUCTOR THIN FILM OF TiO2 ON GRAPHITE SUBSTRATE BY Cu-ELECTRODEPOSITION Fitria Rahmawati; Sayekti Wahyuningsih; Nurani Handayani
Indonesian Journal of Chemistry Vol 8, No 3 (2008)
Publisher : Universitas Gadjah Mada

Surface modification of graphite/TiO2 has been done by mean of Cu electrodeposition. This research aims to study the effect of Cu electrodeposition on photocatalytic enhancing of TiO2. Electrodeposition has been done using CuSO4 0,4 M as the electrolyte at controlled current. The XRD pattern of modified TiO2 thin film on graphite substrate exhibited new peaks at 2θ= 43-44o and 2θ= 50-51o that have been identified as Cu with crystal cubic system, face-centered crystal lattice and crystallite size of 26-30 nm. CTABr still remains in the material as impurities. Meanwhile, based on morphological analysis, Cu particles are dissipated in the pore of thin film. Graphite/TiO2/Cu has higher photoconversion efficiency than graphite/TiO2.

A Kinetic Study of Aluminium(III) and Chromium(III) Adsorption by Silica Gel Chaetoceros calcitrans Biomass Immobilized on Silica Gel Indah Raya; Narsito Narsito; Bambang Rusdiarso
Indonesian Journal of Chemistry Vol 1, No 1 (2001)
Publisher : Universitas Gadjah Mada

The kinetics of aluminium(III) and chromium(III) adsorption in an adsorbent prepared by immobilization of Chaetoceros calcitrans biomass on silica ge has been investigated. The functional groups which were probable involved in the adsorption processes also identified. Experimentally, the adsorption was conducted by coloumn and batch method. In this work atomic adsorption spectrophotometric techniques was applied indirectly to determine of the metal ion adsorpted, and infra red spectroscopic technique was used for the identification of functional groups present in the adsorbent. The study included two parts of experiment, i.e. 1) the determination of rate of adsorption and 2) the determination of capacity and energy of adsorption. Results showed that the AI(III) and Cr(III) adsorption data fit quiet well with non linear kinetics model proposed by Langmuir-Hinshelwood giving a first order rate constant, (k1) of 8.65.10-3 min-1 for AI(III) and 9.92.10-4 min' for Cr(III) when the immobilized biomass used as the adsorbent in agreement with the activation energy calculation giving values of 1.184 kcal/mole for Al(111) and 1.877 kcal/mole for Cr (Ill). It was concluded that the adsorption of Al(III) and Cr(III) on Chaetoceros calcitrans immobilized and free Chaetoceros calcitrans adsorbents, may be classified as chemical adsorption, involving entalphi of adsorption in the range of 6-17 kcal/mole. And the infra red spectroscopic data indicated that the functional groups i.e.: carboxylate (-COO), hydroxyl (-OH) silanol (SI-OH), siloksil (SI-O-Si) and amine (NH2) are present in free Chaetoceros calcitrans biomass and silanol (Si-OH), siloksil (Si-O-Si), hydroxyl (-OH)and C-H metilene (-CH2) are present in immobilized biomass Chatoceros calcitrans, while only siloksil (Si-O-Si) and silanol (Si-OH) in silica gel.

ISOLATION AND IDENTIFICATION FLAVONOID COMPOUND FROM THE STEM BARK OF Saccopetalum horsfieldii BENN Mahmiah Mahmiah
Indonesian Journal of Chemistry Vol 6, No 3 (2006)
Publisher : Universitas Gadjah Mada

Isolation and identification flavonoid compound from the stem bark of Indonesian plant Saccopetalum horsfieldii Benn. Annonaceae family have been done. Extraction was carried out by maseration method using methanol at room temperature, the product was then extracted by n-hexane and etil acetate. Etil acetate extract separation carried out by liquid vacuum column chromatography and flash column chromatography. The product purificated by recristalization using acetone p.a. into yellow solid that having melting point of 224-226 °C. The structure of flavonoid compound was determinated by spectroscopy method : UV-vis, IR, 1H-NMR and 12C-NMR. The flavonoid compound known as quercetin-3,7-dimetil eter or 3,7-dimetoksi quercetin.

THE DISTRIBUTION OF COMMERCIAL CROWN ETHER DC18C6 AND THE EXTRACTION STUDY OF ALKALI AND EARTH ALKALI METALS Bambang Rusdiarso
Indonesian Journal of Chemistry Vol 7, No 2 (2007)
Publisher : Universitas Gadjah Mada

Distribution of A and B isomers of crown-ether DC18C6 on their organic and water phases (chloride, nitrate and sulphocyanide salts) and extraction of alkali and earth alkali metals has been studied. In LiCl 0.1 M environment, lithium extraction could be ignored. The presence of extracted potassium metal may affect the crown ether DC18C6 distribution albeit only a little. In KNO3 0.1 M environment, the distribution coefficient values (d) were 6.1 and 10.3 for A and B isomers, respectively ; while in KCl 0.1 M environment the values were 4.9 and 11.8, respectively. In KSCN 0.1 M, d values for A and B isomers were 40.4 and 36.6, respectively, which were higher than the value obtained from both KNO3 and KCl 0.1 M environments. Caesium metal extraction using DC18C6 occurred weakly, up to only 5%. Strontium extraction using DC18C6 achieved better yield than the caesium extraction. The percentage of extraction increased under organic solvent according to the following: toluene (4%) < chloroform (28%) < TBP (35%).

ADSORPTION KINETICS OF Pb(II), Cd(II) AND Cr(III) ON ADSORBENT PRODUCED BY PROTECTED-CROSSLINKING OF HUMIC ACID-CHITOSAN Dewi Umaningrum; Uripto Trisno Santoso; Radna Nurmasari; Rahmat Yunus
Indonesian Journal of Chemistry Vol 10, No 1 (2010)
Publisher : Universitas Gadjah Mada

Study on adsorption kinetics of of Pb(II), Cd(II) and Cr(III) on adsorbent which was produced by protected-crosslinking of humic acid-chitosan has been done. The Langmuir-Hinshelwood, pseudo first- and second-order kinetics models were used to describe the kinetic data, and the rate constants of adsorption were also evaluated. The experimental data fitted well the second-order kinetics model, indicating that the chemical sorption is the rate-limiting step, instead of mass transfer. The initial metal ion concentration significantly affects the adsorption rate. An increase in initial metal ion concentration results in the decrease in adsorption rate of the metals.

ADSORPTION OF Am-241, Cs-137 AND Sr-90 RADIONUCLIDES WITH BENTONITE-HUMIC ACID IMMOBILIZED YIELD Kris Tri Basuki; Muzakky Muzakky
Indonesian Journal of Chemistry Vol 10, No 1 (2010)
Publisher : Universitas Gadjah Mada

Adsorption of Am-241, Cs-137 and Sr-90 radionuclides to bentonite-humic acid immobilized yield have been done. The aims of this study are (1) making of adsorbent materials from resulted immobilization humic acid into bentonite mineral, and it's characterization with spectroscopy infrared and X-ray diffractometer and (2) adsorption of Am-241, Cs-137 and Sr-90 radionuclides into bentonite mineral as adsorbent at various pH. Experiments showed that result of immobilization of bentonite-humic acid were optimum at 100 g bentonite, 60 g humic acid, 0.1 M NaNO3 ionic strength, and 2.5 pH. At the optimum condition bentonite could be bonded by the functional COOH from humic acid maximum equal to 75.2%. Base on infrared spectroscopy and X-ray diffractometer showed that humic acid can immobilized into bentonite to form of bentonite-humic acid alloy. Application of adsorbent bentonite-humic acid immobilized yield to adsorb radionuclides of Am-241, Cs-137 and of Sr-90, showed that can adsorb at the range of pH 3 until 10. The phenomenon adsorption as species radionuclides was predicted by ";;Visual minteq";; software. By each the feeds of radionuclide 0.001 mMol/L, 0.1 M NaNO3 ionic strength and pH 5 showed that bentonite-humic acid can adsorb radionuclides 98.50-99.1% of Am-241, Cs-137, and Sr-90.

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