Indah Raya
Chemistry Department, Faculty Of Mathematics & Natural Sciences Hasanuddin University

Published : 18 Documents Claim Missing Document
Claim Missing Document
Check
Articles

Found 18 Documents
Search

Uji FTIR dan uji fitokimia dari madu trigona spp. Untuk persiapan suplemen wanita prakonsepsi -, Emmasitah; Raya, Indah; Usman, Andi Nilawati; Mauludiyah, Indah; Prihartini, Ade Rahayu
Jurnal Keperawatan Muhammadiyah 2020: EDISI KHUSUS
Publisher : UNIVERSITAS MUHAMMADIYAH SURABAYA

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (693.874 KB) | DOI: 10.30651/jkm.v5i2.4099

Abstract

Objective: This study aims to identify functional groups and chemical compounds using FTIR (Fourier Transform Infrared), phytochemical tests to identify the content of saponins, tannins, flavonoids, alkaloids, terpenoids and steroids using chemical solutions and total phenol test using 20D+ spectroscopy to determine the amount of polyphenols in Trigona spp. honey. This research is a laboratory study conducted at the Integrated Chemistry Laboratory and Biochemistry Laboratory, Faculty of Mathematics and Natural Sciences, Hasanuddin University Makassar. The sample used in the study was Trigona spp. honey which is a local livestock honey from Masamba, North Luwu regency, South Sulawesi, and has been processed by the Halal Center of Hasanuddin University Makassar.Results: Flavonoids and polyphenols were found in phytochemical tests using Pb(CH3COO)2 and FeCl3 reagents. The FTIR test results indicate the presence of phenolic structures included in the flavonoid group. The total phenolic results from the total phenol test on Trigona spp. honey samples. The amount of polyphenols was 0.28%.Conclusion: This study concluded that there are flavonoids and polyphenols in honey Trigona spp. with a total phenol of 0.28%. Trigona spp. honey has antioxidant effects, so it is well used as a complementary therapeutic supplement for preconception women for handling reproductive health problems.
Pemanfaatan Kitin Sebagai Bahan Membran Elektroda Enzim Diamin Oksidase Untuk Biosensor Histamin Abdul Karim; Abd. Rauf Patong; Abd. Wahid Wahab; Indah Raya
Al-Kimia Vol 2 No 2 (2014): Desember
Publisher : Study Program of Chemistry - Alauddin State Islamic University of Makassar

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (593.928 KB) | DOI: 10.24252/al-kimia.v2i2.1642

Abstract

This research aims to utilize isolated chitin from shrimp waste to develop histamine biosensors basedon diamine oxidase (DAO) enzyme electrode with cyclic voltammetry. DAO enzyme trapped in the chitin-cellulose acetate membranes with various comparisons were layered on the Pt electrode. Histamine will be oxidized by the DAO enzyme produces aldehydes and H2O2 which acts as an electron transfer mediator. Biosensor performance is influenced by several factors, especially the concentration and composition of electrode  membranei.Comparison of chitin-cellulose acetate used in this study were 1:1, 2:1 and 3:1. Isolated chitin from the shrimp waste is chemically obtainedrendamen of 23.6%, and characterization of electrode membrane by FTIR and cyclic voltammetry showed that the DAO enzymes electrode with chitin-cellulose acetate membrane 2:1 is the best composition.
Optimasi Penggunaan Hidrogen Peroksida (H2O2) Terhadap Penurunan Kadar Sianida Pada Limbah Cair Muntasir Muntasir; M. Sjahrul; Muhammad Zakir; Indah Raya
Al-Kimia Vol 3 No 2 (2015): December
Publisher : Study Program of Chemistry - Alauddin State Islamic University of Makassar

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (333.903 KB) | DOI: 10.24252/al-kimia.v3i2.1667

Abstract

Optimation studies have been conducted using hydrogen peroxide (H2O2) to the reduction of cyanide levels in the wastewater. Parameters studied were the optimum concentration of hydrogen peroxide (H2O2), the optimum pH and optimum contact time between hydrogen peroxide (H2O2) with wastewater in reducing the cyanide content. Cyanide obtained from steam distillation of liquid waste and the assay using 0.02N silver nitrate. Concentration used were 500 ppm, 400 ppm, 300 ppm, 200 ppm and 100 ppm; pH range is (7, 8, 9, 10 and 11) and the variation of the contact time is: 0, 30, 60, 90, 120 and 150 minutes. The result of the research reveals at early treatment the cyanide content is 50,22% w / w and underwend a reduction in levels after addition of various concentrations of H2O2; variations in pH variation of contact time. Optimum condition treatment at 500 ppm of H2O2  basicity at pH 8 and contact time for 60 minutes result reduction of cyanide level of 36,40% w/w, 40,91% w/w and 37,09% w/w respectively.
Docking Molecular dari Kompleks Zn(II)Amina (Prolin)dithiokarbamat terhadap Reseptor Estrogen-α Rizal Irfandi; Ruslang Ruslang; Indah Raya; Ahmad Yani; Muhammad Nasir; Nurcaya Nurcaya; Sulistiani Jarre
Al-Kimia Vol 9 No 2 (2021): DESEMBER
Publisher : Study Program of Chemistry - Alauddin State Islamic University of Makassar

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.24252/al-kimia.v9i2.23949

Abstract

Estrogen-α (ER-α) is a major target in cancer therapy. Targeting the ER-α target protein is known to slow the proliferation of breast cancer cells. The purpose of this study was to determine the interaction of the complex compound Zn(II)Prolinedithiocarbamate against the Estrogen-α Receptor. The Zn(II)Prolinedithiocarbamate complex was predicted canonical SMILE by Cheminfo online application (O=C(O)C1CCCN1C2S[Zn]S2) and modeled with online corina to obtain a three-dimensional structure. The structure of the complex compound Zn(II)Prolinedithiocarbamate interacted with Estrogen receptor alpha protein to test its potential anticancer activity. Molecular docking results show the interaction of the Zn(II)Prolinedithiocarbamate complex with the Estrogen- receptor on the amino acid residues ARG394, LEU387, GLU353, LEU346, LEU349, and PHE404. The Zn(II)Prolinedithiocarbamate complex interacts directly with ER-α in the estrogen region which causes the failure of the interaction between estrogen and the estrogen receptor, so it can be predicted that the Zn complex has activity as an ER-α inhibitor and has the potential to be developed in the treatment of breast cancer.
Pengaruh Penambahan Ion Mg2+ Terhadap Kandungan Lipid Fitoplankton Chlorella vulgaris Sebagai Bahan Baku Pembuatan Biodiesel dengan Metode Ultrasonik Alfani M Datu; Indah Raya; Muhammad Zakir
Marina Chimica Acta Vol. 14 No. 2 (2013): Volume 14 No. 2 (2013)
Publisher : Hasanuddin University

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (423.409 KB) | DOI: 10.20956/mca.v14i2.1185

Abstract

An investigation on the effect   of Mg2+     on its lipid content from phytoplankton Chlorella vulgaris as a raw material for producing biodiesel by ultrasonic method has been carried out. The  results  showed  that  Mg2+   is  good  as  a  nutrient  for  phytoplankton.    The  optimum concentration was 0.4 ppm. Total of dry biomass was 32.7902 grams. Lipid was extracted  by ultrasonic method using ethanol 95% as solvent. Biodiesels were syntesized in two steps namely esterification by methanol solvent and H2SO4 as catalyst, folowed by transesterification by using methanol solvent with KOH as a catalyst. Total of biodiesel made was 11.5727 grams and the yield  was  35.29%. The result  of  biodiesel  characterised  in term of  physical  and  chemical characteristics including:   density, viscosity, free fatty acid, saponification value, and iodine value, respectively.   Result of the analysis showed that biodiesel characteristics have fulfilled standard the American  Society for Testing and  Materials  (ASTM D6751), except  value of density and Free Fatty Acid.
Produksi Biodiesel dari Lipid Fitoplankton Nannochloropsis sp. Melalui Metode Ultrasonik Raymond Kwangdinata; Indah Raya; Muhammad Zakir
Marina Chimica Acta Vol. 14 No. 2 (2013): Volume 14 No. 2 (2013)
Publisher : Hasanuddin University

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (215.201 KB) | DOI: 10.20956/mca.v14i2.1187

Abstract

A research on production of biodiesel from lipid of phytoplankton Nannochloropsis sp. through ultrasonic extraction method has been done. In this research, we carried out a series of phytoplankton culture to determine the optimum time of growth and biodiesel synthesis process from phytoplankton lipids. Process of biodiesel synthesis consists of two steps, i.e isolation of phytoplankton lipids and biodiesel synthesis from  that  lipids.  Oil  isolation  process  was  carried  out  by  ultrasonic  extraction method using ethanol 96 % while biodiesel synthesis was carried out by transesterification reaction using methanol and KOH catalyst under sonication. Percentage rendement  of  weight  per  biomass  Nannochloropsis  sp.    is  48,33  %. Characterization of biodiesel was carried out in terms of physical properties: density, viscosity, and chemical properties: FFA content, saponification value, and iodine value. The result showed that analysis characterization biodiesel phytoplankton Nannochloropsis  sp.  that  biodiesel  from  that  species  phytoplankton  generally fullfilled the American Society for Testing and Materials (ASTM D6751) standard, except  density value was 0,8151 g.cm-3,  viscosity value was 1,15 cSt, and FFA content was 0,5381 %, to be used as fuel.
THE EFFECT OF Fe2+ DAN Mn2+ IONS TOWARD β-CAROTENE PRODUCTIVITY BY PHYTOPLANKTON Isochrysis aff galbana (T-iso) Erna Mayasari; Indah Raya; Hasnah Natsir
Marina Chimica Acta Vol. 13 No. 2 (2012): Volume 13 No. 2 (2012)
Publisher : Hasanuddin University

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (352.29 KB) | DOI: 10.20956/mca.v13i2.1194

Abstract

The research aimed to find out the effect of Fe2+ and Mn2+ towards β-carotene productivity as result of oxidative stress from photosystem (PS II). The phytoplanton Isocrysis aff galbana (T-iso) were the microalgae species which had the high lipid content primarily and had potentiality to produce β-carotene as the β-carotene supplement. Analysis method was carried out by the sonication extraction for short and cheap in the lysis cell of phytoplankton biomassa, infra red (IR) to find out the interaction metal ion and UV/VIS spectrophotometer to determine β-carotene concentration. The research result indicateds that Fe2+ has higher impact than Mn2+ on the β-carotene productivity. The interaction of ions metal indicates as   M-N, -O-M and M←OH-C complex in the phytoplankton amino acid. The β-carotene concentration is 4,97 µg/g DW in addition Fe2+ 0,30 ppm and 1,95 μg/g DW in Mn2+  0,20 ppm. The dry weight concentrations of β-carotene indicates that  I. aff galbana with Fe2+ addition has potential as β-carotene supplement. 
THE BIOACCUMULATION OF Cd(II) IONS On Euchema Cottoni SEAWEED BIOAKUMULASI ION Cd(II) PADA RUMPUT LAUT Euchema Cottoni Indah Raya; Rahmah Rahmah
Marina Chimica Acta Vol. 13 No. 2 (2012): Volume 13 No. 2 (2012)
Publisher : Hasanuddin University

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (669.895 KB) | DOI: 10.20956/mca.v13i2.1197

Abstract

Cadmium is an element that can accumulated in seaweed thallus. One of an alternative methode was used to determine the amount of Cd(II) ions were accumulated in Euchema Cottoni thallus is adsorption methode, that was conducted with variations of contact time and concentrations. The concentrations of Cd(II) ions in solutions were determined by using Atomic Absorption Spectrophotometer (AAS). Isothermal model to evaluated the maximum adsoprtions capacity were used Freundlich and Langmuir isotherms. Based on both isothermal models the results showed that adsorption capacity were 33,898 mg/g wet weight by Langmuir and 0,00625 mg/g wet weight by Freunlich isotherms respectively. The adsorptions energy (ΔG) is 9,7482 KJ/mol indicated as physisorptions. While infrared spectrum showed Euchema cottoni have –OH,  CO2,  -CH2,  -CH3,  and  - SO3- functional groups.
MICROALGAE AS GREEN ENERGY SOURCES AND THEIR HIGH VALUE CO PRODUCTS Indah Raya
PROSIDING SEMINAR KIMIA PROCEEDING OF INTERNATIONAL CONFERENCE 2015
Publisher : PROSIDING SEMINAR KIMIA

Show Abstract | Download Original | Original Source | Check in Google Scholar

Abstract

Energy and microalgae
STUDIES OF USE HYDROGEN PEROXIDE (H2O2) OXIDIZING TO REDUCTION CYANIDE LEVEL IN WASTEWATER Muntasir -; M. Sjahrul; Muhammad Zakir; Indah Raya
PROSIDING SEMINAR KIMIA PROCEEDING OF INTERNATIONAL CONFERENCE 2015
Publisher : PROSIDING SEMINAR KIMIA

Show Abstract | Download Original | Original Source | Check in Google Scholar

Abstract

Has done conducted research studies the use of oxidizing hydrogen peroxide (H2O2) to the reduction of cyanide levels in the wastewater. Parameters measured were the optimum concentration of hydrogen peroxide, pH optimum, optimum contact time between Hydrogen Peroxide with wastewater in reducing the cyanide content. Cyanide obtained from steam distillation of liquid waste and assay using 0.02 N silver nitrate. Variations in the concentration used was 100 ppm, 200 ppm, 300 ppm, 400 ppm and 500 ppm; pH variation is (7, 8, 9, 10 and 11) and the variation of contact time are: 30, 60, 90, 120 and 150 minutes. The results showed early treatment of cyanide content of 50.22% w/w and experienced a reduction after the addition of H2O2 concentration of 100 ppm, 200 ppm, 300 ppm, 400 ppm and 500 ppm; variations in pH is 7, 8, 9, 10 and 11 and the variation of contact time are: 30, 60, 90, 120 and 150 minutes. The optimum treatment is the optimum concentration of H2O2 at 500 ppm with a reduction in levels of 36.40% w/w, pH Optimum pH 8 with reduced levels of 40.91% and an optimum contact time at 60 minutes with a reduction in levels of 37.09% w/w.