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Contact Name
Istadi
Contact Email
istadi@che.undip.ac.id
Phone
+6281316426342
Journal Mail Official
bcrec@live.undip.ac.id
Editorial Address
Editorial Office of Bulletin of Chemical Reaction Engineering & Catalysis Laboratory of Plasma-Catalysis (R3.5), UPT Laboratorium Terpadu, Universitas Diponegoro Jl. Prof. Soedarto, Semarang, Central Java, Indonesia 50275
Location
Kota semarang,
Jawa tengah
INDONESIA
Bulletin of Chemical Reaction Engineering & Catalysis
ISSN : -     EISSN : 19782993     DOI : https://doi.org/10.9767/bcrec
Bulletin of Chemical Reaction Engineering & Catalysis, a reputable international journal, provides a forum for publishing the novel technologies related to the catalyst, catalysis, chemical reactor, kinetics, and chemical reaction engineering. Scientific articles dealing with the following topics in chemical reaction engineering, catalysis science, and engineering, catalyst preparation method and characterization, novel innovation of chemical reactor, kinetic studies, etc. are particularly welcome. However, articles concerned on the general chemical engineering process are not covered and out of the scope of this journal. This journal encompasses Original Research Articles, Review Articles (only selected/invited authors), and Short Communications, including: fundamentals of catalyst and catalysis; materials and nano-materials for catalyst; chemistry of catalyst and catalysis; surface chemistry of catalyst; applied catalysis; applied bio-catalysis; applied chemical reaction engineering; catalyst regeneration; catalyst deactivation; photocatalyst and photocatalysis; electrocatalysis for fuel cell application; applied bio-reactor; membrane bioreactor; fundamentals of chemical reaction engineering; kinetics studies of chemical reaction engineering; chemical reactor design (not process parameter optimization); enzymatic catalytic reaction (not process parameter optimization); kinetic studies of enzymatic reaction (not process parameter optimization); the industrial practice of catalyst; the industrial practice of chemical reactor engineering; application of plasma technology in catalysis and chemical reactor; and advanced technology for chemical reactors design. However, articles concerned about the "General Chemical Engineering Process" are not covered and out of the scope of this journal.
Articles 838 Documents
Kinetics and Thermodynamics of Ultrasound-Assisted Depolymerization of κ-Carrageenan Ratnawati Ratnawati; Aji Prasetyaningrum; Dyah Hesti Wardhani
Bulletin of Chemical Reaction Engineering & Catalysis 2016: BCREC Volume 11 Issue 1 Year 2016 (April 2016)
Publisher : Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.9767/bcrec.11.1.415.48-58

Abstract

The ultrasound-assisted depolymerization of κ-carrageenan has been studied at various temperatures and times. The κ-carrageenan with initial molecular weight of 545 kDa was dispersed in water to form a 5 g/L solution, which was then depolymerized in an ultrasound device at various temperatures and times. The viscosity of the solution was measured using Brookfield viscometer, which was then used to find the number-average molecular weight by Mark-Houwink equation. To obtain the kinetics of κ-carrageenan depolymerization, the number-average molecular weight data was treated using midpoint-chain scission kinetics model. The pre-exponential factor and activation energies for the reaction are 2.683×10-7 mol g-1 min-1 and 6.43 kJ mol-1, respectively. The limiting molecular weight varies from 160 kDa to 240 kDa, and it is linearly correlated to temperature. The results are compared to the result of thermal depolymerization by calculating the half life. It is revealed that ultrasound assisted depolymerization of κ-carrageenan is faster than thermal depolymerization at temperatures below 72.2°C. Compared to thermal depolymerization, the ultrasound-assisted process has lower values of Ea, ΔG‡, ΔH‡, and ΔS‡, which can be attributed to the ultrasonically induced breakage of non-covalent bonds in κ-carrageenan molecules. 
The Role of Ti and Lewis Acidity in Manganese Oxide Octahedral Molecular Sieves Impregnated with Titanium in Oxidation Reactions Fitri Hayati; Sheela Chandren; Halimaton Hamdan; Hadi Nur
Bulletin of Chemical Reaction Engineering & Catalysis 2014: BCREC Volume 9 Issue 1 Year 2014 (April 2014)
Publisher : Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.9767/bcrec.9.1.5603.28-38

Abstract

Octahedral manganese oxide molecular sieves (OMS-2) was prepared by precipitation method and modified by impregnation of titanium with different titanium/manganese (Ti/Mn) ratio. It was also discovered that Ti/Mn ratio of less than 0.5 still retains the original pure cryptomelane structure of OMS-2. However, for sample with Ti/Mn ratio of more than 0.5, some rutile phases of titania (TiO2) can be detected together with the cryptomelane phase. Lewis acid sites were also observed in the titanium modified OMS-2 (Ti-OMS-2). Ti-OMS-2 was then used as catalysts for the oxidation of cyclohexane, cyclohexene and styrene, where Ti-OMS-2 with Ti/Mn ratio of 0.67 was most active in all three of the oxidation reactions as compared to TiO2 and OMS-2. The results suggest that both titanium sites in framework and non-framework and the Lewis acidity created by the impregnation of Ti, increased the activity of OMS-2 in oxidation reactions. © 2014 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0)
Deaktivasi Katalis Konverter-Hidrogen Di Pabrik Urea Kaltim-3 Agus Subekti; Achmad Syamsul Arief; Praharso Praharso; Subagjo Subagjo
Bulletin of Chemical Reaction Engineering & Catalysis 2007: BCREC: Volume 2 Issues 2-3 Year 2007 (October 2007)
Publisher : Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.9767/bcrec.2.2-3.7130.52-55

Abstract

Di pabrik urea, konverter-hidrogen adalah satu reaktor yang berfungsi untuk mengkonversi hidrogen yang terikut dalam karbondioksida dengan cara mengoksidasi dengan udara, sehingga karbondioksida umpan reaktor urea itu hanya mengandung tidak lebih dari 100 ppm hidrogen. Konversi dilangsungkan pada tekanan 145 kg/cm2 dan suhu umpan reaktor 130°C, menggunakan katalis platinum berpenyangga alumina (0,3%Pt/Al2O3). Dalam dua tahun terakhir, terjadi kenaikan kandungan hidrogen dalam karbondioksida umpan konverter-hidrogen Kaltim-3 yang menyebabkan peningkatan temperatur keluaran konverter dari biasanya sekitar 152oC menjadi sekitar 190°C. Hasil analisis kadar Pt, luas permukaan katalis dan dispersi Pt terhadap katalis-baru dan katalis-terpakai menunjukkan bahwa katalis konverter-hidrogen Kaltim-3 telah terdeaktivasi. Oleh karena itu, pada kesempatan perbaikan-tahunan Juli 2006 yang lalu, katalis tersebut telah diganti dengan yang baru. Selain itu telah dilakukan pula perbaikan kondisi operasi di pabrik amoniak Kaltim-3, sehingga kadar H2 dalam aliran CO2 umpan pabrik urea Kaltim-3 menjadi normal kembali (0,4%). Dengan tindakan-tindakan tersebut, sejak Agustus 2006 yang lalu konverter hidrogen Kaltim-3 dapat beroperasi secara normal kembali. © 2007 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0)
Structural, Thermal, Morphological, Adsorption and Catalytic Properties of Poly(BPDAH-co-ODA/PPDA)-Ag/V2O5 Nanocomposites Govindharajan Sribala; Balakrishnan Meenarathi; Ramasamy Anbarasan
Bulletin of Chemical Reaction Engineering & Catalysis 2020: BCREC Volume 15 Issue 1 Year 2020 (April 2020)
Publisher : Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.9767/bcrec.15.1.5595.155-174

Abstract

Thermally stable polyimides (PIs) were prepared by condensation technique at 160 ºC for 5 hours in N-methylpyrrolidone (NMP) medium under N2 atmosphere both in the presence and absence of metal (Ag) and metaloxide (MO) (V2O5) nanoparticles (NPs). The synthesized polymers are characterized by Fourier Transform Infra Red (FT-IR) spectroscopy, 1H Nuclear Magnetic Resonance (1H NMR) spectroscopy, Differential Scanning Calorimetry (DSC), Thermal Gravimetric Analysis (TGA), Scanning Electron Microscopy (SEM), Transmission Electron Microscopy (TEM), Field Emission Scanning Electron Microscopy with Energy Dispersive X-Ray (FE-SEM and EDX). The FT-IR spectrum showed a peak at 1786 cm-1 corresponding to the C=O stretching of dianhydride. The aromatic proton signals appeared between 6.7 and 7.5 ppm in the 1H-NMR spectrum of the resultant PIs. The oxydianiline (ODA) based PI with Ag NP loaded system exhibited the highest Tg value. The apparent rate constant values for the adsorption and catalytic reduction of p-nitrophenol (PNP), Cr6+ and rhodamine 6G (R6G) dye were determined with the help of UV-visible spectrophotometer. Among the catalysts, the system loaded with V2O5 NP has higher kapp values. The experimental results are critically analyzed and compared with the previously available literature values. Copyright © 2020 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0). 
Manufacture of n-Propyl Propionate Using Ion Exchange Resins: Reaction Kinetics and Feasibility of Reactive Distillation Reshma R. Devale; Bipin S. Deogharkar; Yogesh S. Mahajan
Bulletin of Chemical Reaction Engineering & Catalysis 2022: BCREC Volume 17 Issue 4 Year 2022 (December 2022)
Publisher : Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.9767/bcrec.17.4.15928.811-820

Abstract

Reaction kinetics of esterification of propionic acid with 1-propanol to produce n-propyl propionate using Amberlyst-15 as a catalyst was investigated in this work. Effect of various parameters was studied. Initially, the efficacy of different catalysts was investigated which revealed that Amberlyst-15 can be suitably used for the reaction. This was followed by mass transfer exclusion which included effect of agitation speed, catalyst size and calculation of Weisz-Prater Criterion. Parameters selected for kinetic study were mole ratio of propionic acid to 1-propanol, temperature, catalyst loading and initial water concentration. Catalyst reusability was also verified. Aspen      Custom Modeler (ACM) was used to regress kinetic parameters and a good match was obtained. Reactive Distillation (RD) runs in the batch mode were performed which showed that RD is a better option for process intensification (PI) for this reaction. Copyright © 2022 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0). 
Activities of Heterogeneous Acid-Base Catalysts for Fragrances Synthesis: A Review Hartati Hartati; Mardi Santoso; Sugeng Triwahyono; Didik Prasetyoko
Bulletin of Chemical Reaction Engineering & Catalysis 2013: BCREC Volume 8 Issue 1 Year 2013 (June 2013)
Publisher : Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.9767/bcrec.8.1.4394.14-33

Abstract

This paper reviews various types of heterogeneous acid-base catalysts for fragrances preparation. Catalytic activities of various types of heterogeneous acid and base catalysts in fragrances preparation, i.e. non-zeolitic, zeolitic, and mesoporous molecular sieves have been reported. Generally, heterogeneous acid catalysts are commonly used in fragrance synthesis as compared to heterogeneous base catalysts. Heteropoly acids and hydrotalcites type catalysts are widely used as heterogeneous acid and base catalysts, respectively. © 2013 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0)
Kinetic Modeling of Flocculation and Coalescence in the System Emulsion of Water-Xylene-Terbutyl Oleyl Glycosides Harsa Pawignya; Tutuk Djoko Kusworo; Bambang Pramudono
Bulletin of Chemical Reaction Engineering & Catalysis 2019: BCREC Volume 14 Issue 1 Year 2019 (April 2019)
Publisher : Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.9767/bcrec.14.1.2594.60-68

Abstract

The development of a mathematical model for explaining the kinetics of flocculation and coalescence of emulsion droplets is essential to study the stability of an emulsion system of the kinetics of emulsion stability. Mathematic models was developed from the equation Van Den Tempel by modifying emulsion systems. The emulsion was made by mixing water-xylene and surfactant tert-butyl oleyl glycosides. This research studied the effect of stirrer speed on the value of flocculation rate constant (a) and coalescence rate constant (K). The model identified the emulsion development condition whether controlled by coalescence or flocculation. It was observed that under lower agitation speed (1000 rpm) the emulsion development was controlled by flocculation mechanism, while a faster agitation (2000 rpm or higher) exhibited coalescence controlled mechanism. The results confirmed that the 1st model was the most appropriate for water-xylene-TBOG emulsion system. From four models after fitting with experimental data, the most suitable model is 4th model, because it has the smallest error of 2.22 %. 
A Novel Synthetic Nano-Catalyst (Ag2O3/Zeolite) for High Quality of Light Naphtha by Batch Oxidative Desulfurization Reactor Amer Talal Nawaf; Shymaa Ali Hameed; Layth T. Abdulateef; Aysar Talib Jarullah; Mohammed S. Kadhim; Iqbal M. Mujtaba
Bulletin of Chemical Reaction Engineering & Catalysis 2021: BCREC Volume 16 Issue 4 Year 2021 (December 2021)
Publisher : Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.9767/bcrec.16.4.11383.716-732

Abstract

Oxidative desulfurization process (ODS), enhanced with a novel metal oxide (Ag ions) as an active component over nano-zeolite that has not been reported in the literature, is used here to improve the fuel quality by removing mercaptan (as a model sulfur compound in the light naphtha). Nano-crystalline (nano-support (Nano-zeolite)) composite is prepared by Incipient Wetness Impregnation method loaded with a metal salt to obtain 0.5, 1 and 1.5% of Ag2O3 over Nano-zeolite. The new homemade nano-catalysts (Ag2O3/Nano-zeolite) prepared are characterized by Brunauer–Emmett–Teller (BET) (surface area, pore volume and pore size), X-ray Diffraction (XRD), Fourier Transform Infra Red (FTIR), and Scanning Electron Microscopy (SEM) analysis. The ODS process is then used to evaluate the performance of the catalysts for the removal of sulfur at different reaction temperatures (80–140 °C) and reaction times (30–50 min) in a batch reactor using the air as oxidant. 87.4% of sulfur removal has been achieved using 1% silver oxide loaded on Nano zeolite (1% of Ag2O3/Nano-zeolite) giving a clear indication that our newly designed catalyst is highly efficient catalyst  in the removal of sulfur compound (mercaptan) from naphtha. A new mechanism of chemical reaction for sulfur removal by oxygen using the new homemade catalyst (Ag2O3/Nano-zeolite) prepared has been suggested in this study. The best kinetic model parameters of the relevant reactions are also estimated in this study using pseudo first order technique based on the experimental results. Copyright © 2021 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0). 
CuAl LDH/Rice Husk Biochar Composite for Enhanced Adsorptive Removal of Cationic Dye from Aqueous Solution Neza Rahayu Palapa; Tarmizi Taher; Bakri Rio Rahayu; Risfidian Mohadi; Addy Rachmat; Aldes Lesbani
Bulletin of Chemical Reaction Engineering & Catalysis 2020: BCREC Volume 15 Issue 2 Year 2020 (August 2020)
Publisher : Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.9767/bcrec.15.2.7828.525-537

Abstract

The preparation of CuAl LDH and biochar (BC) composite derived from rice husk and its application as a low-cost adsorbent for enhanced adsorptive removal of malachite green has been studied. The composite was prepared by a one-step coprecipitation method and characterized by X-ray Diffraction (XRD), Fourier Transform Infra Red (FTIR), Brunauer-Emmett-Teller (BET), and Scanning Electron Microscopy - Energy Dispersive X-ray (SEM−EDX). The result indicated that CuAl LDH was successfully incorporated with the biochar that evidenced by the broadening of XRD peak at 2θ = 24° and the appearance of a new peak at 1095 cm−1 on the FTIR spectra. The BET surface area analysis revealed that CuAl/BC composite exhibited a larger surface area (200.9 m2/g) that the original CuAl LDH (46.2 m2/g). Surface morphological changes also confirmed by SEM image, which showed more aggregated particles. The result of the adsorption study indicated the composite material was efficient in removing malachite green with Langmuir maximum adsorption capacity of CuAl/BC reaching 470.96 mg/g, which is higher than the original CuAl LDH 59.523 mg/g. The thermodynamic analysis suggested that the adsorption of malachite green occurs spontaneously (ΔG < 0 at all tested temperature) and endothermic nature. Moreover, the CuAl/BC composite showed strong potential as a low-cost adsorbent for cationic dye removal since it showed not only a high adsorption capacity but also good reusability. Copyright © 2020 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0). 
The Effect of Variations in Calcination Temperature on the Character of ZnO and ZnO/Mopl-CTAB in Degrading Methyl Orange Aulia Dewi Rosanti; Fahmi Hidayat; Yuly Kusumawati; Arif Fadlan; Rizky Arief Shobirin; Fanni Kurnia Wijaya
Bulletin of Chemical Reaction Engineering & Catalysis 2023: BCREC Volume 18 Issue 2 Year 2023 (August 2023)
Publisher : Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.9767/bcrec.18305

Abstract

Medan orange peel (Mopl), which has been modified using cetyltrimethylammonium bromide (CTAB), has the potential to adsorb methyl orange (MO), and thus it can be used as a supporting material for ZnO. The ZnO is a photocatalytic material that is environmentally friendly, inexpensive, non-toxic, and has a wide band gap value. This study aims to determine the effect of calcination temperature on ZnO and ZnO characteristics due to modification using Mopl-CTAB and its effect on the degradation of MO. This research was carried out by synthesizing ZnO and ZnO/Mopl-CTAB materials using impregnation method and varying the calcination temperatures at 150, 250, 350, and 450 °C. The solid material powder obtained was characterized by using Scanning Electron Microscope-Energy Dispersive X-ray (SEM-EDX), Brunauer–Emmett–Teller (BET), Fourier Transform Infra Red (FTIR), X-ray Diffraction (XRD), and Diffuse Reflectance Spectroscopy (DRS). Based on the results of the characterization, greater calcination temperature can affect the characteristics of the photocatalyst, including its morphology, functional groups, crystal structure, crystal lattice, crystallinity, surface area, pore size, pore volume, and energy band gap. The MO photodegradation activity test using the synthesized material was conducted under dark and light conditions. The results of the test revealed that the best or optimum material to be used in degrading MO is a calcined material at 450 °C under light conditions. ZnO material using Mopl-CTAB is better in degrading ZnO/Mopl-CTAB 450 °C than ZnO 450 °C. This study found that ZnO material using Mopl-CTAB  had a percent removal of 78% in 50 min, while ZnO 450 °C only had a percent removal of 53% in 40 min. The reaction kinetics in dark and light conditions follow the pseudo-second-order kinetic model. Copyright © 2023 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0). 

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