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Seminar Nasional Teknik Kimia Kejuangan
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Prosiding Seminar Nasional Teknik Kimia Kejuangan adalah media online dari makalah yang telah diseminarkan pada acara Seminar Nasional Teknik Kimia “Kejuangan” (SNTKK). SNTKK merupakan agenda tahunan yang diselenggarakan oleh Program Studi Teknik Kimia FTI UPN ”Veteran” Yogyakarta. Seminar ini merupakan sarana komunikasi bagi para peneliti dari perguruan tinggi, institusi pendidikan, serta lembaga penelitian maupun industri, dalam mengembangkan teknologi kimia untuk pengolahan sumber daya alam Indonesia.
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Articles 132 Documents
Search results for , issue "2023: PROSIDING SNTKK 2023" : 132 Documents clear
Sintesis dan Karaterisasi CuO/rGO Maulana, M Sifal; Riyani, Kapti; Setyaningtyas, Tien
Prosiding Seminar Nasional Teknik Kimia "Kejuangan" 2023: PROSIDING SNTKK 2023
Publisher : Seminar Nasional Teknik Kimia "Kejuangan"

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Abstract

Semiconductor material is a material that is widely used in the chemical industry, especially as a photocatalyst. CuO is a semiconductor material that is active in the visible light range. Semiconductor materials can undergo recombination, rGO was used as a composite material into CuO to reduce recombination in this study. This study aims to look at the characteristics of the synthesized CuO/rGO. The processes performed include synthesis of CuO/rGO and characterization of CuO/rGO. The XRD results show the peaks of the diffractogram indicating of rGO peaks interpreted (002), peaks at (110), (-111), (111), (-202), (020), (202), (-113), (- 331), (220), (311) and (004) indicate the monoclinic phase of CuO has been formed. FTIR results indicating Cu-OH absorption show peak at wave numbers 3441.0 cm-1 and 894.97 cm-1, O-C-O vibrations present in CuO/rGO indicating adsorption at 2360.8 cm-1, 1975.1 and 1512 .1 cm-1 appears due to the C=C stretching vibrations in the rGO layer, 1033.8 cm-1 absorbs C-O stretching vibrations and 609.51 and 439.77 cm-1 have relative peaks indicating Cu-O stretching vibrations. The DRS results show that CuO/rGO has band gap value of 1.54 eV.
Pengaruh Lapisan Kalsium pada Devais Sel Surya Organik Berbasis Bahan Polimer Budiawan, Widhya; Widodo, Slamet
Prosiding Seminar Nasional Teknik Kimia "Kejuangan" 2023: PROSIDING SNTKK 2023
Publisher : Seminar Nasional Teknik Kimia "Kejuangan"

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Abstract

Organic solar cells (OSC) as an emerging photovoltaics devices have potential clean energy source due to their advantages properties, including low-cost production, light weight, and promising for flexible devices. In this study, we investigated the effect of calcium as buffer layer on top photoactive layer of the polymer based solar cell device. Poly-3-hexylthiophene (P3HT) as donor material combining with phenyl-C61-butyric acid methyl ester (PC61BM) were blended to form bulk heterojunction. Calcium was deposited on top of polymer (P3HT) and fullerene derivative (PC61BM) photoactive layer using thermal evaporation inside ultrahigh vacuum chamber. Calcium was selected as buffer layer because of its low-work -function in order to improve performance of polymer solar cells. Our study presented that calcium buffer layer enhanced the performance of solar cells mainly in open circuit voltage, VOC, (0.45 V to 0.61 V) and fill factor, FF, (44% to 65%), increasing power conversion efficiency (PCE) from 1.79% to 3.79%. This result suggested that the improvement of polymer solar cells performance because of the recombination suppression and more efficient charge transfer in cathode. The energy level alignment and work function properties of calcium form an ideal ohmic contact between the active layer and the cathode, thus ensuring effective electron injection from the active layer to the cathode. We also demonstrated the fabrication of polymer solar cells device under ambient atmosphere. However, the devices fabricated under ambient atmosphere have lower performances than fabricated inside nitrogen filled glovebox, because polymer photoactive material and calcium are easily degraded by moisture.
Penentuan Dimensi Pipa Pada Lapangan Panasbumi Gedongsongo Pramudiohadi, Eko Widi
Prosiding Seminar Nasional Teknik Kimia "Kejuangan" 2023: PROSIDING SNTKK 2023
Publisher : Seminar Nasional Teknik Kimia "Kejuangan"

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Abstract

To meet the demand for electricity in the Ungaran area in particular, it is necessary to build geothermal power in the Gedongsongo area, but there are no production facilities, both below and on the surface, so the authors plan production facilities on the surface, regarding the selection of optimum pipe diameters. The goal is to build a power plant with a capacity of 110 MWe based on the optimum diameter, which provides the smallest possible loss of pressure and temperature and the maximum possible mass flow, for this the authors use the pressure loss profiles from Begg and Brill and temperature loss using the 1st law of thermodynamics, With two-dimensional Newton Rapson manipulation, it can be seen that the drop in pressure and temperature at the exit point simultaneously on a pipe segment. In this field, there are 4 clusters, including: cluster 1 (4 wells), cluster 2 (5 wells), cluster 4 (2 wells), each 2 wells served by 1 separator, starting from the pressure of each wellhead 15 Barg, dryness 0.25 and rate 105.5 kg/s, insulation thickness 8 cm, polyurethane type, pipe length from wellhead to separator 150 m, resulting in pipe diameter from 18-24 in, minimum thickness from 30.82-39.62 mm, pressure drop 0.55 Barg, temperature 1.67 oC, from separator to turbine input, pipe 50-1200 m long, yield diameter from 16-48 in, minimum thickness 25.01-61.50 mm, pressure drop 1.61 Barg, temperature 3.11 oC, with a generated power of 154 MWe
Pengaruh Kosentrasi Pencampuran Tepung Bonggol Pisang Termodifikasi untuk Pembuatan Mie Basah Azizah, An Nisa Luthfi Nur; Hamid, Hamid
Prosiding Seminar Nasional Teknik Kimia "Kejuangan" 2023: PROSIDING SNTKK 2023
Publisher : Seminar Nasional Teknik Kimia "Kejuangan"

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Abstract

Banana tuber flour is a type of non-wheat flour which has a high carbohydrate content so it has the potential to be processed into noodles. However, due to the low protein content and immature physicochemical properties, it is necessary to modify it enzymatically and mix it with wheat flour to obtain good quality noodles. This study aims to obtain enzymatically modified banana tuber flour with suitable characteristics for application in the manufacture of wet noodle products, as well as to obtain a formula (comparison of modified banana tuber flour and wheat flour) which can produce wet noodles that meet the SNI quality requirements. The treatment tested was enzymatically modified banana tuber flour substitution 10%, 20%, 30%, 40% and 0% were used as control variables. Wet noodle products were tested for water content and noodle organoleptic (smell, color and texture) according to SNI 2987:2015 wet noodle quality requirements. The results showed that the level of wet noodles met SNI standards, namely below 65%. The organoleptic test results showed that the best quality wet noodles were obtained from a combination of 10% modified banana tuber flour and 90% wheat flour with a concentration ratio of -amylase enzyme of 10%. The aroma test obtained a combination of 10% modified banana tuber flour and 90% wheat flour with a concentration ratio of -amylase enzyme of 40%.
Pengaruh Variasi Konsentrasi Tepung Bonggol Pisang Termodifikasi dengan Metode Enzimatis sebagai Bahan Substitusi pada Pembuatan Mi Basah Widyaningsih, Arum Dewi; Abdillah, Hamid
Prosiding Seminar Nasional Teknik Kimia "Kejuangan" 2023: PROSIDING SNTKK 2023
Publisher : Seminar Nasional Teknik Kimia "Kejuangan"

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Abstract

The banana tuber contains high carbohydrates, but it is still rarely used because of the brown color of the flour due to heating. To cover this deficiency, modification with α-amylase enzyme was carried out. The purpose of this study was to obtain a suitable formulation for the manufacture of wet noodles that meet the requirements of SNI quality standards. The treatment variation made was the ratio of 3 tapioca: 9 banana tuber: 48 wheat (80% wheat), 3 tapioca: 6 banana tuber: 21 wheat (70% wheat), 3 tapioca: 5 banana tuber: 12 wheat (60% wheat). The variation of α-amylase enzyme used was 10%, 20%, 30%, 40% with 0% as the control variable. Organoleptic test to determine the most preferred noodle variation. The test parameters were color, aroma and texture. The results showed that the best quality with color and aroma wet noodles were obtained from a combination of 60% with 40% α-amylase enzyme concentration ratio. As the texture parameters were obtained from a combination of 60% wheat with 10% α-amylase enzyme concentration ratio. The results showed that the moisture content of wet noodles had met the SNI 2987:2015 standard, which is below 65%.
Modifikasi Pati Secara Asetilasi dan Aplikasinya Sebagai Bahan Dasar Filamen Jaring Ikan Ramah Lingkungan Triastuti, Warlinda Eka; Suprapto, Suprapto; Muyassaroh, Tisnuliah; Bawafi, Suardhana; Sampurno, Ade Citra Oktaviana Elok; Meghotsah, Muhammad Akha; Aditama, Fitra Diannico; Ardhana, Krisna Setya
Prosiding Seminar Nasional Teknik Kimia "Kejuangan" 2023: PROSIDING SNTKK 2023
Publisher : Seminar Nasional Teknik Kimia "Kejuangan"

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Abstract

Fishing nets are generally made of synthetic polyamides such as nylon. The use of nylon nets has negative impacts, such as habitat destruction. So it is necessary to consider the use of biodegradable nets. One of the potential natural materials that can be used as eco-friendly fishing net filaments is starch. The research aims to modify cassava and corn starch by acetylation method to improve their characteristics. Starch modification was carried out by adding acetic acid with variable concentrations of 10%, 15%, 20%, 25%, and 30% into the starch. Modified starch was analysis for water content, swelling power, solubility, and FTIR. In the manufacture of filaments using modified corn 15% with a test result of 0.04; 0.13; 0.05. The results of the FTIR analysis showed a combined functional group between HDPE and starch at wave numbers 2922.2cm-1 and 1371.7cm-1. Starch content has an effect on reducing the weight of filament degradation. SEM analysis showed that the compatibility of the filament with the addition of MA increased but the internal structure of the filament gradually expanded with increasing starch content. The results of the analysis of tensile strength and elongation at break of the filament are 1.81 kgf and 119.77%
Penentuan Kadar Sulfat pada Air Sumur di Wilayah Surabaya Menggunakan Spektrofotometer Agustiani, Elly; Triastuti, Warlinda Eka; Sampurno, Ade Citra Oktaviana Elok; Zahrah, Hanifah Fauziyah; Tyas, Sunia Rahma Cahyaning; Santoso, Yustia Dwi Fitria; Rahmawati, Affy Milatur; Martasari, Amelia; Wintara, Ellen Septia; Amali, Hafid
Prosiding Seminar Nasional Teknik Kimia "Kejuangan" 2023: PROSIDING SNTKK 2023
Publisher : Seminar Nasional Teknik Kimia "Kejuangan"

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Abstract

The quality of drinking water can be assessed based on three aspects: physical, chemical, and microbiological aspects. One of the chemical aspects in determining water quality is the sulfate content. UV-Vis spectrophotometry method has been widely used to analyze sulfate content. UV-Vis spectrophotometry is a spectroscopic analysis technique that uses an electromagnetic wave source with ultraviolet (UV) for wavelength (190-380 nm) and visible light with wavelength (380-780 nm). The purpose of this study is to determine the absorbance and concentration of samples using spectrophotometric analysis, calculate the sulfate content in the samples, and compare it with the Indonesian Ministry of Health Regulation Permenkes RI No. 32//2017. The research stages include calibration, calibration curve creation, making standard H2SO4 solutions, measuring the absorbance of the standard solutions, and analyzing the sulfate content in water samples. The research results showed that the sulfate concentration in the Bangkalan, Nginden, Sidoarjo, Keputih, and Kapas Madya well water samples were 14.0817, 27.551, 29.1837, 49.0817, 54.6939 ppm, respectively. Based on the Indonesian Ministry of Health Regulation Permenkes RI No. 32//2017, the maximum sulfate content in water is 400 mg/L, thus it can be concluded that the water samples in those areas have met the clean water standards.
Pengaruh Variasi Kosentrasi Tepung Tapioka Termodifikasi Dengan Metode Enzimatis Sebagai Bahan Substitusi Pada Proses Pembuatan Mie Putri, Itci Amada; Abdillah, Hamid
Prosiding Seminar Nasional Teknik Kimia "Kejuangan" 2023: PROSIDING SNTKK 2023
Publisher : Seminar Nasional Teknik Kimia "Kejuangan"

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Abstract

Indonesia has dependency to rice Enough high , so request rice very tall And when happen scarcity rice inside _ country . So needed innovation product For cope problem such , ie Wrong only one replace rice with noodles wet as alternative  replacement source carbohydrates . Material raw making noodles wet on study This is flour tapioca modified And flour wheat as material substitution . Expected with use material non- flour basis For product noodles capable replace dependency use flour flour . On study This use variation comparison composition flour tapioca modified And flour different flour _ namely ; (10%:90%, 25 % : 75%, and 30%:70%) use variation concentration enzyme 10%, 20%, 30%, 40%, and 0% as control parameters . Results study show comparison flour tapioca modified influential to noodle water content wet And quality noodles wet include (aroma, elasticity , and color ). Highest water content that is sample noodles wet on ratio of 30% flour tapioca modified and 70% flour wheat with 40% enzyme concentration of 64.54 % . According to Body Standard Indonesian National requirements quality noodle water content good wet is 65%, got concluded that noodles wet fulfil requirements.
Pengaruh Waktu Pemasakan dan Konsentrasi NaOH Terhadap Penurunan Kadar Lignin Pulp dari Batang Pisang Kepok dengan Proses Soda Maulana, Imam; Widayatno, Tri
Prosiding Seminar Nasional Teknik Kimia "Kejuangan" 2023: PROSIDING SNTKK 2023
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Banana is a plant that has very high cellulose content so it can be used as a raw material for making pulp. This research was conducted with the aim of knowing the effect of cooking time and sodium hydroxide concentration on reducing the lignin content of banana stem pulp by soda process. The cooking solution used in the soda process is NaOH solution. With various concentrations of NaOH 20%, 25%, and 30% and cooking time 40, 80, and 120 minutes. The highest lignin content was 1.8785% during pulping for 40 minutes with 20% NaOH concentration. While the lowest lignin content was 1.3093% during pulping for 120 minutes with 30% NaOH concentration.
Bioconversion of Fruit Wastes into High Economic Value of Lipids using Heterotrophic Microalgae Aurantiochytrium from Mangrove Forests of Bunyu Island, North Kalimantan Suhendra, Suhendra; Hutari, Andri; Pratiwi, Sekar; Sari, Hutri Puspita
Prosiding Seminar Nasional Teknik Kimia "Kejuangan" 2023: PROSIDING SNTKK 2023
Publisher : Seminar Nasional Teknik Kimia "Kejuangan"

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Aurantiochytrium microalgae is recognized as heterotrophic microalgae enables to produce high economic value of lipids for the use in health care industries. This research presents the production of biomass containing lipids through the bioconversion of fruit waste using Aurantiochytrium microalgae. Aurantiochytrium microalgae isolate was obtained from isolated mangrove leaves in the mangrove forest of Bunyu Island, North Kalimantan. The production process takes place in three stages, namely standing culture (SC), pre-culture (PC), and main culture. The SC and PC stages took place 48 hours respectively, while the MC took place 120 hours. The source of nutrition at the main cultivation stage (MC) used monosodium glutamate (MSG) as a nitrogen source, while the carbon source was from fruit waste. Amount of 250 grams of fruit waste was mixed and blended, added with 250 ml of water and then sonicated. The mass ratio of nitrogen source and carbon source was 1:3. The maximum of observed microalgal cell diameters for each stage were 14.5 μm (SC), 19.2 μm (PC) and 25.5 μm (MC). Produced biomass in this experiment has the characteristics of a yellow emulsion liquid, pH 6.2, fishy smell and total dissolved solids (TDS) of 4,820 ppm and a wet biomass of 68 g/l