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INDONESIA
Jurnal Zeolit Indonesia
Published by Institut Teknologi Bandung
ISSN : -     EISSN : -     DOI : -
Core Subject : Education,
Education
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Articles 202 Documents
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APPLICATION OF NATURAL ZEOLITE AS A COMPONENT OF CATALIST BUFFER FOR HYDROGENATION REACTION OF CO2 AND CRACKING OF PALM OIL Setiadi, Setiadi; Darmawan, Yanes; Fitria, R. Melisa
Jurnal Zeolit Indonesia Vol 6, No 1 (2007)
Publisher : Jurnal Zeolit Indonesia

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Abstract

This research was started with making a catalyst of CuO/ZnO/ZSM-5 with copresipitation method which using nitrate salts of Cu and Zn at buffer of zeolite ZSM-5 with loading (weight CuO and ZnO into their buffer) 10%, 20%, 30%, 40% and the pure of ZSM-5. The product of catalyst is then activated tested by hydrogenation reaction, where CO2 gas become the methanol by reacting of CO2 dan H2 into unggun reaction in operation condition: the pressure of 25 bar, with temperature at 250ºC, feeding ratio CO2/H2 = 1 : 3. The making catalyst of CuO/ZnO/ natural zeolite each with impregnation method and physical mixing at the best loading in the result of activities test from all of catalyst CuO/ZnO/ZSM-5 by the results of preparation of copresipitation methods. The result of catalyst test indicate that the methanol (CH3OH) can be made of the main feeding of CO2 and H2 gas with catalyst of CuO/ZnO/ZSM-5 and catalyst of CuO/ZnO/ natural zeolite from the result of copresipitate preparation, impregnation and physical mixing. The test of CuO/ZnO/ZSM-5 catalyst resulting of preparation copresipitation indicate that catalyst with loading 30% yielding methanol (0.1359%). The method of copresipitation is the best among the other methods. We also obtained the buffer of natural zeolite from Malang can also give yield of methanol product although it’s not as high as with buffer of ZSM-5. The cracking reaction of oil palm using a natural zeolite toproduce gasoline fraction of hydrocarbon compound in fixed bed reactor in atmospheric pressure and the temperature at 350-500ºC. The natural zeolite with addition of B2O3 0-20% is used as catalyst with variabel temperature, type of feeding and B2O3 addition. The characteristic for seeing the surface area with BET method and crystalization of B2O3 with XRD method. Addition of B2O3 optimum of 5% gave the yield 52.3% for feeding POME and 38% oil palm and methanol.
PROCESSING OF URANIUM WASTE USING ALUMINA SILICA PHOSPHATE Aisyah, Aisyah; Martono, Herlan; Wati, Wati
Jurnal Zeolit Indonesia Vol 7, No 2 (2008)
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Abstract

Uranium waste generated from the utilization of nuclear technology on radioisotope production, nuclear fuel production, calibration of fuel post-irradiation, and the purification of uranium from yellow cake. Uranium is a long-lived radionuclides and hazardous if it was entered in human body, thus requiring appropriate treatment with high safety. The processing conducted by separated the uranium which was contained on waste with ions exchange process. Uranium has been separated, later then immobilized with the polymer. The study of simulation uranium waste processing using an Alumina Silica Phosphate (ASP) has been conducted. Simulation uranium waste with the concentration of 0,05 g/l was contacted to ASP with contact timer and pH as a parameters. The Alumina Silica Phosphate which saturated with uranium, later then immobilized with epoxy resin polymer by total of waste contents as a parameter. The immobilization was conducted by mixing ASP which saturated with uranium and epoxy resin. The study showed that the best composition of ASP was obtained at the ratio of 1:1, contact time of 15 minute, and pH of 7 with absorption of uranium about 93,5%. The characteristic of polymer and the immobilization waste showed that optimum of waste content is 20% of weight with the density of 1,0538 g/cm3; compressive strength of 19,96 kN/cm2 and there was not detected the leaching of uranium which out from the polymer-waste. Therefore, ASP can be used on processing of uranium waste and could be suggested to be applied on Radioactive Waste Management Installation.
THE INFLUENCE OF SLOW RELEASE FERTILIZER UREA-ZEOLITE-HUMIC ACID (UZA) TO PADDYS PRODUCTIVITY VARIETY CIHERANG Pratomo, Kurniawan Riau; Suwardi, Suwardi; Darmawan, Darmawan
Jurnal Zeolit Indonesia Vol 8, No 2 (2009)
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Abstract

Slow Release Fertilizer (SRF) is a modification fertilizer which aims to improving subtances efficiency on fertilizers by organizing the release slowly or gradually. The methods which used to made a SRF has any variety such as enlarging size, smoothing fertilizer surface, mixing with another difficult soluble materials, and covering fertilizer with certain ingredients so releasing fertilizer under soil more slowly. Some materials can be used as SRF materials are zeolite and humic acid. Zeolite is a silicate mineral which have a high cation exchange capacity (CEC) (varying between 80-180 meq/100g), fit hollow space to ammonium ion size so it have high adsorption capacity to ammonium ion. Meanwhile, humic acid which extracted from inorganic materials has a high CEC too. In this study, urea fertilizer has easily lost characteristics because of leaching and evaporation was conducted by covering zeolite and humic acid. The study aimed to find a proper dosage from combinations of urea, zeolite, and humic acid (UZA) for the paddy and to find proper applications of UZA for paddy. The experiment was conducted in green house with paddy variety Ciherang as an indicator plant. Paddy was fertilized with a standard dosage of N fertilizer from UZA with humic acid value of 0%, 1%, 2%, 3%, 4%, and 5%. UZA fertilizer can improving paddy growth and productivity. UZA fertilizer with 1% humic acid dose is a the best dosage for paddy. The spread distribution of UZA was better than buried on the mud.
ENGINEERING OF ZEOLITE MINERAL WITH WET IMPREGNATION INHIBITOR METAL METHOD AS RAW MATERIAL OF ANTISEPTIC BY CONTINOUS FLOW METHOD Estiaty, Lenny Marilyn
Jurnal Zeolit Indonesia Vol 9, No 2 (2010)
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Abstract

Industrial minerals, such as natural zeolite can be engineered into raw materials on manufacturing of medical products, especially as an antiseptic. Zeolite with the crystal structure characteristic could be function as an antiseptic carrier and active subtances would be saved on crystal structure of zeolite which was on certain circumstances will be work or out of the frame structure. The active substances are an inhibitor metal with low concentration and could be a toxic for microbial cell plasma. The used natural zeolite as an antiseptic carrier with inhibitor metal Cu has not yet developed. In this study, antiseptic substances has made by impregnation method with flow continuously were a compound or metal substances put in crystal structure without changing the crystal structure. The impregnation conducted by purification process and modification of natural zeolite become a zeolite-H in order easily to substituted by Cu metal. The products is much metals K, Na, Ca, Mg out from zeolite making a Zeolite-H was perfect, so the planting of Cu metals was maximum. The purification, modification, and impregnation process did not change the shape of crystal zeolite, and degradation do not occur on modernite peaks so expected the characteristic from zeolite does not change so it is could be functions as antiseptic carrier. Absorption test and power test of bacterial growth was conducted to try the antiseptic substances against bacteria and fungi. The result that zeolite-Cu had been successfully made although not optimal. The absorption capacity of natural zeolite higher than the absorption capacity of zeolite-Cu, because the absorption capacity of zeolite-Cu was disrupted by entry of metal Cu. Inhibition of bacteria and fungi growth occurs more on media with addition zeolite-Cu. It was because the inhibition of zeolite-Cu already functioning.
EFFECTS OF ZEOLITE AND BLOOD FLOUR RATE AS THE SOURCE OF PROTEIN ON RANSOM ON PIG CARCASS QUALITY Siagian, Pollung H.; Muladno, Muladno; Gurmilang, Alfonsus Agan
Jurnal Zeolit Indonesia Vol 2, No 1 (2003)
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Abstract

The objectives of this research is to know the effects of zeolite and blood flour rate effects as the source of protein on ransom on pig carcass quality. Pig carcass quality is influenced by several factors before and after slaughtering. One of the factors that influences pig carcass before slaughtering is feeding. The right feeding can fulfill the pig needs and increases the pig carcass quality. The average weight of 27 pigs used on this research is 25,59 ± 2,67 kg and the research design is 3´3 complete randomize design which the first factor is zeolite rate (0, 3, and 6%) and second rate is blood flour rate (0, 5, and 10%), so we have nine treatments ransom (R1 to R9) with three repetition on each treatment. The result showed that zeolite rate on ransom did not affect any parameter (P>0,05) and neither the blood flour, except for the loin eye area larger than 10% and without blood flour on ransom with the scores 31,16 ± 4,25; 27,74 ± 3,32, and 29,18 ± 4,85 cm2. The effect of interaction between zeolite rate and blood flour on ransom is very real (P0,05) on carcass percentage and the thickness of pig carcass back fat. The highest and the lowest slaughter weight and carcass weight is the pig whose have R5 and R4. The highest average of back fat thickness and loin eye area is the pig whose have R8 and R4 is the lowest. The pig whose have R7 and R4 each have the longest and shortest carcass while the highest carcass percentage is the pig whose have R4 and the lowest is R6.
THE EFFECT OF ZEOLITE ADDITION IN RATIONS ON EGG QUALITY IN PHASE TWO OF PRODUCTION Kurtini, Tintin
Jurnal Zeolit Indonesia Vol 4, No 2 (2005)
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Abstract

This research was conducted to evaluate that the effect of zeolite addition in ration on egg quality in phase two of production. This experiment was arranged in a completely randomize design with 5 zeolite levels in rations (0; 2; 4; 6 and 8%) and 4 replications. The total hens were 40 of CP 909 (60 weeks of age), and this experiment was done 4 weeks. The parameters that: feed consumption, the shell thickness, fat of yolk levels, and cholesterol of yolk levels. The data were analyse by using Analysis of Variance, and orthogonal polynom test was used , analysis were in 5% significant degree. The result of this research showed that zeolite addition in ration until 8% had significant effect (P0.05) on cholesterol of yolk levels and feed consumption.
BLEACHING OF CRUDE PALM OIL BY ADSORPTION METHOD WITH USING NATURAL ZEOLITE FROM LAMPUNG Astuti, Widi; Amin, Muhammad; Aprimal, Aprimal
Jurnal Zeolit Indonesia Vol 5, No 2 (2006)
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Abstract

The research about bleaching of crude palm oil by adsorption method with using natural zeolite from Lampung has been done. The experiment result shows that natural zeolite from Lampung can be used as adsorbent for bleaching process of crude palm oil. Zeolite had been activated by chemical method with hydrochloric acid (HCl) solution before it was used as adsorbent. From the experiment result, we know that the best condition for bleaching process are weight percentage of zeolite that was used to get the highest of transmittance is 20% and the best concentration of HCl solution is 4%. The highest of transmittance for this condition is 48.5.
OVERCOME LAND DEGRADATION WITH SOIL AMELIORANT APPLICATION (STUDY OF FARMER PERCEPTIONS IN MALANG, EAST JAVA) Al-Jabri, M.
Jurnal Zeolit Indonesia Vol 7, No 1 (2008)
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Abstract

Improving the quality of soils degradation can be achieved using the soil ameloirant (i. e. Zeolite, manure, compost, etc.), conservation farming systems, organic management, system balanced fertilization specific location, and efficiency of water use. This study aimed to determine: (1) the type of soil ameloirant that is still used by farmers, sources of information, and its use of doses, (2) constraints and benefit of use, (3) fertilizer efficiency, and (4) development opportunities. This study conducted by survey method that is structured interview included: farmer characteristics, identification, and soil ameloirant development prospects in the future. Identification of soil ameloirant, such as: type of soil ameloirant used by farmers, sources of information, applications, the impact of the use, benefits and constraints of use. The results showed that: the distribution age of respondent ≤ 55 years (80.7%) and > 55 years (19.3%). Dissemination through counseling, pilot project on farmers land in order to developing the confidence of farmers will benefit and importance of the use soil ameloirant to repair land degradation, increasing productivity, and agricultural production. The soil ameloirant have been used by 24% of respondents farmers is zeolite granules (Agro-88) and dolomite; measurement of soil ameloirant for rice field: 500 kg of zeolit /ha and 577 kg dolomite/ha; garden: 219 kg zeolite/ha and 409 kg dolomite/ ha; mixedgarden: 600 kg of zeolit/ha and 143 kg dolomite/ha. Soil ameloirant benefits is for increasing the production: paddys, corns, and vegetables (cauliflower, peppers, tomatoes) around 10-30%, improving the soil fertility and reducing dosage of urea fertilizer as much as 15-30% and SP-36 as much as 30%.
Cs ION EXCHANGE CAPACITY OF ZEOLITE BAYAH, LAMPUNG, AND TASIKMALAYA Noviarty, Noviarty; Anggraini, Dian; Nugroho, Arif
Jurnal Zeolit Indonesia Vol 8, No 1 (2009)
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Abstract

Cs ions exchange process has been conducted on natural zeolite (from Bayah, Lampung, and Tasikmalaya) which was activated with ammonium chloride. NH4-zeolite which was formed, is used to exchanger or absorber material of Cs ions. The duration of ions exchange process was optimized by varying the stirring time of 1 hours, 2 hours, 3 hours, 4 hours, 5 hours, and 24 hours. In all three zeolite types was obtained the optimization process time are the contact time of 1 hours. Cation exchange capacity (CEC) of natural zeolite was determined by standard methods. Attempts to obtain a monocation zeolite as a NH4-zeolite effectively acquired about 88% which used as a exchanger or absorber Cs ions. The effectiveness of Cs ions Cation exchange capacity with the ammonium was determined by batch-exchange for 1 hour. The calculation result o effectiveness CEC-Cs are 1.4269 Meq/gram ± 0.0397, RSD: 2.79% for Bayah zeolite, 1.4476 Meq/gram ± 0.0103, RSD: 0.71% for Lampung zeolite, 1.4044 Meq/gram ± 0.0050, RSD: 0.36% for Tasikmalaya zeolite. Stability of Cs-zeolte bond against heat treatment was tested at temperature of 25°, 300°, 600 °, 900°, and 1200 °C. The result showed that the relea se of Cs-ions is not significant from zeolite structure. The heating below 900°C, the release of Cs-ions jus t occurs on the surface (it was not change the initial of zeolite structure), whereas above that temperature was occurs the changed of zeolite structure, although there was not visible the release of Cs-ions on leaching process at the water. The conclusion is all three types of natural zeolite was potentially to be used as Cs-ions isolate which is especially useful to absorbing Cs-radioactive isotope as a result from fission of nuclear fuel element.
PROSPECT OF ZEOLITE APPLICATION IN AGRICULTURE Suwardi, Suwardi
Jurnal Zeolit Indonesia Vol 1, No 1 (2002)
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Abstract

Although zeolites have been known since the 50s the application of zeolites in Indonesia started in the 80s after promotion by the Mineral Technology Research Centre. Before that period, zeolites were only used as construction materials for wall decoration. Zeolites became popular after publication of zeolite research into many aspects of possible applications. Applications of zeolites are based on their characteristics. Initially natural zeolites were used as fillers in the paper industry, ion exchangers in water treatment, separation of nitrogen and oxygen, sorbents in drying, and construction materials. At the same time, applications of zeolites were developed as feed additives for animals and for water treatment in shrimp ponds. In some countries, zeolites have been used as industrial materials, improvement of agricultural production, and environmental protection. In agriculture, applications of zeolites can be used directly to soils as materials for growth media, mixed with manures during decomposition process, and for mixing with urea as slow release agent. The number of zeolite factories in Indonesia is still low and they produce zeolites in powder and grain forms. In recent years, some zeolite factories have been built to produce zeolites for material of industry, agriculture and environmental protection. The most important effort for zeolite factories is how to produce high quality of zeolite. The prospect of zeolite applications in agriculture is very good as (1) soil amelioration for low cation exchange capacity of soils, (2) material for mixing with fertilizer, (3) material as growth media for horticulture and seedling plantation plants, (4) material for improvement of compost quality, (5) material for water treatment of fish ponds, (6) food additives for animals.

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