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INDONESIA
Jurnal Zeolit Indonesia
Published by Institut Teknologi Bandung
ISSN : -     EISSN : -     DOI : -
Core Subject : Education,
Education
Arjuna Subject : -
Articles 202 Documents
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POTENCY OF ZEOLITE IN INDONESIA Kusdarto, Kusdarto
Jurnal Zeolit Indonesia Vol 7, No 2 (2008)
Publisher : Jurnal Zeolit Indonesia

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Abstract

Zeolite is one of non-metallic minerals or multi-use industrial minerals due to its physical and chemical characteristic as an absorbent, ion exchange, molecular filters and as a catalyst. Minerals in zeolite group are generally found in tufa rocks formed from volcanic-ash sediments resulting from alteration, diagenesis, and hydrothermal processes. Indonesia is laid in the volcanic series from Sumatra, Java, Nusa Tenggara, until Sulawesi Islands. One of the products of volcanic tuff wide spreading form the volcano, partially or wholly have undergone a process of alteration or diagenesis to become zeolite. Geologically, Indonesia has big potential to produce zeolites such as those found in Lampung, West Java, Central Java, East Java, East Nusa Tenggara, and Sulawesi, with the estimate resources of 447,490,160 tons.
THE PATTERN OF NITROGEN RELEASE FROM SLOW RELEASE FERTILIZER UREA-ZEOLITEHUMIC ACID Nainggolan, Ganda Darmono; Suwardi, Suwardi; Darmawan, Darmawan
Jurnal Zeolit Indonesia Vol 8, No 2 (2009)
Publisher : Jurnal Zeolit Indonesia

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Abstract

Nitrogen is essential nutrient for plants, deficiency of nutrient causes plants could not growth normally. Nitrogen is easily lost from soil so to reduce his lost by forming fertilizers available in slow form (slow release). Some materials can be used to create a slow release of which having high cation exchange capacity (CEC). Zeolite and humic acid are materials which have a highest CEC so it make possible to use as a slow release materials. The study aimed to determine the rate and pattern of nitrogen release from mixture formulas Slow Release Fertilizer (SRF) and urea-zeolite and humic-acid (UZA) and comparing rate of nitrogen release with urea pril. The study conducted in laboratory with incubation experiment during 14th weeks. Determination ammonium and nitrate was conducted by extracting the soil with extractant hydrodistillation 0.1 N HCl + 1 N KCl. The result showed that a higher humic acid concentration was given on fertilizer causes a nitrogen release become ammonium and nitrate more slowly. SRF H5 (urea:zeolit, 70%:30% with humic acid of 5%) have a slowest nitrogen release rate rather than five types of Slow Release Fertilizer (SRF) formulas which containing a humic acid. However, SRF H1 and H3 fertilizer (with humic acid of 1% and 3%) have a most efficiency nitrogen release rate rather than five types of Slow Release Fertilizer (SRF) which is containing a humid acid.
THE KINETIC AND DIFUSSION ION EXCHANGE OF Cs ON ZEOLITE BAYAH, LAMPUNG, AND TASIKMALAYA Anggraini, Dian; Noviarty, Noviarty; Nugroho, Arif
Jurnal Zeolit Indonesia Vol 9, No 2 (2010)
Publisher : Jurnal Zeolit Indonesia

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Abstract

The ion exchange of Cs on NH4-Zeolite which has been activated become a zeolite monocation has been conducted on natural zeolite from Bayah, Lampung, and Tasikmalaya. On these three types of zeolite, the process of ion exchange of Cs with ammonium ion was conducted at various time (from 1 hour up to 24 hours) and temperature (303 K and 323 K). Cation exchange kinetics and diffusion process on each type of zeolite was observed and calculated the parameters included diffusion coefficient and activation energy using Arrhenius formula. The study showed that diffusion coefficient from Cs-ions into zeolite of Bayah, Lampung, and Tasikmalaya almost same, which is about 2,3 10-13 , 2,3 10-13 and 2,1 10-13 m2.det.-1 at temperature 303 K, and 9,3 10-14, 9,6 10-14, and 9,6 10-14 m2.det.-1 at temperature 323 K. The parameter calculation result of ion exchange reaction is activation energy Ea (kJ/mol) on that types of zeolite are almost same value, which is 36.61, 36.61, and 31.09 for each zeolite of Bayah, Lampung, and Tasikmalaya. The study showed that Ea value was greater than the previous study by using artificial zeolite (zeolit-A with Ea = 9,96 kJ/mol), so it can be concluded that Cs-ions exchange into natural zeolite has a greater barrier because the composition of natural zeolite more complex which was might contain more than one types of zeolite structure.
SELECTIVITY OF LAMPUNG ZEOLITE TOWARDS MATRICES CATIONS GENERATED FROM URANIUM FISSION Amini, Siti; Anggraini, Dian; Nampira, Yusuf; Rosika, Rosika; Noviarti, Noviarti; Nugroho, Arif
Jurnal Zeolit Indonesia Vol 2, No 1 (2003)
Publisher : Jurnal Zeolit Indonesia

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Abstract

Selectivity of zeolite-lampung (ZKK) towards some matrices cations generated from uranium fission products has been investigated using some typical fission product-non-radioactive cations by cation exchange batch-system process. The previous investigation showed that zeolite-lampung is effectively able to absorb cesium ion from radioactive waste, consequently the presence of others cations i.e. generated cations from the uranium fission products are assumed as the competitive cations which may affect the zeolite selectivity on to Cs exchanges, on the otherhand the Cs-exchange capacity of zeolite would decrease. The main matrices cations which present in the natural zeolite are K+, Na+ and Ca2+and those are generated from fission products such as Cs+, Ba2+, Sr2+ and Ce4+ exist in the nuclear spent fuel solution. The ion exchanges of counterpart cations in zeolites with that each of Cs+, Ba2+, Sr2+ and Ce4+ ion or/and its mixtures have been examined. The selectivity of zeolite onto mentioned exchanged cations has been shown by the correlation of fraction of the cations concentration in the zeolite (Az) towards that in equilibrated solution (As). The results show that the raw zeolite Lampung selectivity is decrease in order to Cs+> Ba2+= Sr2+ > Ce4+. The exchanged capacity of zeolite into Cs+ ion is decreased by the presence of combining ions of Ba2+, Sr2+ and Ce4+, and so are those competitive cations.
APPLICATION OF ZEOLITE IN AGRICULTURE Sastiono, Astiana
Jurnal Zeolit Indonesia Vol 3, No 1 (2004)
Publisher : Jurnal Zeolit Indonesia

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Abstract

Chemical and physical characteristic of zeolite are use not only as nutrient absorber to increases fertilizer efficiency, but also as compost mixing for plant growth media or compost humidity regulator. This agriculture advantages specially to increases nitrogen fertilizer efficiency. Many efforts carried out to minimize ammonia lost from nitrogen fertilizer, one of the alternatives is using zeolite through the process of making slow release fertilizer. As a mineral with the high rate of cation exchange capacity, zeolite have the ability to absorb ammonium ion, so it will increases nitrogen fertilizer efficiency by mixing zeolite with fertilizer or spreading zeolite into the fields. Zeolite urea capsules use on paddy plant on several regions on West Java showing production increasing and nitrogen fertilizer efficiency increases. Zeolite use as vegetables plant media showing a quite well result. Furthermore zeolite reduces heavy metal take over from the food chain. With these results zeolite have a big role in increasing agriculture production.
STUDY ON THE EXISTING OF METAL ELEMENTS NI, PB, CR AND CD IN THE ZEOLITIZATION PRODUCTS OF FLY ASH WITH NAOH SOLUTION Wibowo, Widajanti; Hermiati, Teti
Jurnal Zeolit Indonesia Vol 4, No 2 (2005)
Publisher : Jurnal Zeolit Indonesia

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Abstract

Directly reuse of fly ash waste from electricity power plant as soil conditioner is often not recommended, because of its content on heavy metals elements. This research studied the existence of metal elements, Ni, Pb, Cr and Cd in the zeolitization products of fly ash produced in PLTU Suralaya. Zeolitization process was conducted hydrothermal using NaOH solutions of 3N and 4N at temperature of 90oC and 120oC and heating time of 12 hours, 24 hours and 48 hours. 10 kinds of zeolite products were identified as a mixture of zeolite Na-PI, Na6(Si10Al6O32).12H2O and zeolite Na Hydroxysodalite, Na6(SiAlO4)6.4H2O, which had cation-exchange capacity much higher than the original fly ash. Metals ions content of Ni, Pb, Cr and Cd in the zeolite products, analyzed by AAS, were found much decrease compared to its content in the fly ash. Further study on leaching of metals ions from the zeolite products with water on pH neutral did not show a significant losses of these metals ions.
CATALIST PERFORMANCE OF SYNTETIC ZEOLITE ZSM-5 – Al2O3 IN CRACKING REACTION OF PALM OIL TO BECOME GASOLINE FRACTION OF HYDROCARBON Setiadi, Setiadi; W., Benny A.
Jurnal Zeolit Indonesia Vol 5, No 2 (2006)
Publisher : Jurnal Zeolit Indonesia

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Abstract

The requirement of fuel increases without balancing with its production causing the oil resources from fuel will immediately finished. Therefore, palm oil as renewable energy resources is selected for fuel production especially gasoline. Catalitic cracking process by using ZSM-5/Alumina catalys is selected in this research. The reaction was conducted in a simple fixed bed reactor with the pressure of 1.5 atm during half hour and WHSV 1,8 h-1 dan 2,4 h-1. The reaction result product then analyzed by using GC-FID for identify the gasoline fraction obtained, and FT-IR for identify the bonding kind of the samples. The baits used were pure palm oil, oxydized oil,POME (Palm Oil Methyl Esther), and oil with methanol. The parameters of the research were temperature (350 – 500 °C), catalist composition (5 - 20 %), and kinds of baits. The results showed that the composition of catalist 5% at reaction temperature of 400 °C with the bait of POME resulting the highest gasoline yield of 63,1%.
PRODUCTION OF Y AND USY ZEOLITE FOR THE ACTIVE COMPONENT OF CRACKING CATALYST Subagjo, Subagjo
Jurnal Zeolit Indonesia Vol 7, No 1 (2008)
Publisher : Jurnal Zeolit Indonesia

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Abstract

Standard Y zeolite has been prepared from sodium aluminate as an alumina source and Cab-O-Sil or sodium silicate as a silicate source. This study in particular aimed to obtain a reliable procedure to produce Y zeolite with Si/Al ratio ≥5. The resulted zeolite was then converted into Ultra Stable Y Zeolite (USY) through hydrothermal dealumination at high temperature. The study managed to procure a formulae and procedure to produce a zeolite Y which has SiO2/Al2O3 > 5 and a very stable USY. The procedure succeeded in obtaining synthesized USY that is ready to use as an active phase of cracking catalyst by combining it with other components which are matrix (modified clay and active matrix) and additives (ZSM- 5).
Application of Zeolite as Carrier for Humic Acid for Increasing Food Crops Production Suwardi, Suwardi; Dewi, Evi Mutiara; Hermawan, Bagus Ahmad
Jurnal Zeolit Indonesia Vol 8, No 1 (2009)
Publisher : Jurnal Zeolit Indonesia

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Abstract

Soils in Indonesia are mostly classified as Ultisol having physico-chemical properties such as low pH, low organic matter and very low in nutrients. As a result, the agricultural production on land is very low. Today the use of chemical fertilizers without addition of organic matter to cause a decline in soil organic matter content, soil physical properties become increasingly hard due to structural damage and no development of most soil microorganisms. In such conditions, the soil becomes no more responsive to fertilization so that agricultural production including food crops is leveling of. Therefore, efforts to overcome the barriers of soil properties to increase production of food crops must be done. Recently busy talking people active ingredients that can increase agricultural production spectacular. The material is humic acid extracted from organic materials. The result of this study showed that application of 10 liter/ha humic acid to the soils through zeolite as carrier increased the production of paddy by 15% and corn by 10%. The increase of crop production is due to the development of root then stimulating the absorption of nutrients
STANDARDIZATION OF ZEOLITE MINERAL FOR QUALITY CONTROL Sastiono, Astiana
Jurnal Zeolit Indonesia Vol 1, No 1 (2002)
Publisher : Jurnal Zeolit Indonesia

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Abstract

Zeolite minerals in the past 20 years have been used n many aspect of agriculture, industry and environmental protection. Application of zeolites commercially depends on one or more of their physical and chemical characteristics. Natural zeolites are obtained as tuff rocks together with other minerals with the variation in their composition. Separation of the mineral is very difficult with any chemical process. In order to guarantee the quality of natural zeolites as a commercial product, we need to establish national standard of zeolites. Properties of zeolite such as particle size, mineral compositions, chemical properties and other properties need to be standardized.

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