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Proses Torefaksi Untuk Meningkatkan Nilai Kalor Cangkang Sawit dengan Metode COMB Gde Suastika, Komang; Karelius, Karelius; Dirgantara, Made; Rumbang, Nyahu
Risalah Fisika Vol 3, No 2 (2019): Risalah Fisika ISSN 2548-9011
Publisher : Physical Society of Indonesia (PSI)

Abstrak – Indonesia merupakan negara produsen dan eksportir kelapa sawit terbesar di dunia, yang menghasilkan limbah biomassa yang melimpah. Pemanfaatan limbah hasil industri kelapa sawit menjadi bahan bakar dengan modifikasi termokimia dapat menjadi salah satu solusi untuk membuat nilai tambah dari limbah tersebut. Berdasarkan tinjauan dan penelitian terdahulu, cangkang kelapa sawit merupakan bahan baku yang baik untuk dimanfaatkan sebagai bahan bakar berbasis biomassa. Pada penelitian ini dilakukan proses torefaksi cangkang sawit dengan ukuran lolos ayakan 0,5 cm kemudian diuji nilai kalor sebelum dan setelah torefaksi. Torefaksi cangkang sawit dengan menggunakan metode COMB (Counter Flow Multi-Buffle) pada suhu 250 °C dan flowrate 4 cm3/menit meningkatkan nilai kalor sebesar 824,43 cal/g dengan nilai sebelum dan setelah torefaksi sebesar 4018,78 cal/g dan 4843,21 cal/g. Dibandingkan dengan metode batch pada penelitian sebelumnya nilai kalori yang dihasilkan tidak berbeda jauh. Keunggulan metode COMB adalah waktu prosesnya yang singkat yakni sebesar 5 menit, sedangkan metode batch memerlukan waktu 15-60 menit, sehingga kebutuhan energi untuk prosesnya lebih besar. Kata kunci: bahan bakar, cangkang sawit, counter flow multi-buffle, nilai kalori, torefaksi

Pemurnian Asap Cair Hasil Torefaksi Cangkang Sawit dengan Cara Destilasi dan Filtrasi dengan Arang Aktif: Purification of Liquid Smoke from Torrefaction of Palm Oil by Distillation and Filtration with Activated Charcoal Karelius, Karelius; Rosmainar, Lilis; Novia Toemon, Angeline; Dirgantara, Made
Jurnal Jejaring Matematika dan Sains Vol. 2 No. 2 (2020): Edisi Desember 2020
Publisher : Fakultas Matematika dan Ilmu Pengetahuan Alam, Universitas Palangka Raya

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.36873/jjms.2020.v2.i2.407

The liquid smoke produced from the torrefaction process of oil palm shells has the potential to be used as an antiseptic base for hand sanitizer and disinfectant products. It is due to its high phenol and acetic acid content. Apart from phenol and acetic acid, there are many other compounds that must be separated in the hope of obtaining liquid smoke with the main components of acetic acid and phenol, which function as antibacterial agents. This research begins with the production of liquid smoke through a torrefaction process. The liquid smoke obtained is distilled at 150 oC and followed by adsorption with activated charcoal for the purification process. The pH value and acetic acid content in the purified liquid smoke were determined and analyzed using GC-MS to determine the chemical compounds. The pH value has decreased after the refining process by distillation, and activated charcoal is inversely proportional to the increase in acetic acid levels after purification. Based on GC-MS analysis results, it can be seen that the levels of acetic acid, phenol, propanoic acid, and 2-propanone increased after distillation. The loss of 1,2-Benzenediol and 2-Furancarboxaldechde compounds shows that distillation of liquid smoke at 150oC is effective for separating the heavy fraction of liquid smoke. Furthermore, the distilled liquid smoke is filtered using activated charcoal. The GC-MS analysis results showed that the filtration results with activated charcoal could increase acetic acid and propanoic acid levels in liquid smoke.

Perancangan Filter Penjernih Air Sungai Kahayan Berbasis Pasir Silika Dan Lempung Alam Asal Kalimantan Tengah: Design of Kahayan River Water Treatment Filter Based Silica Sand and Natural Clay of Central Kalimantan Coenraad, Revianti; Wiratno; Karelius, Karelius
Jurnal Jejaring Matematika dan Sains Vol. 1 No. 2 (2019): Edisi Desember 2019
Publisher : Fakultas Matematika dan Ilmu Pengetahuan Alam, Universitas Palangka Raya

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.36873/jjms.v1i2.213

Salah satu cara pengolahan air yang sederhana dan ramah lingkungan adalah melalui proses penyaringan dengan instalasi penyaringan air sederhana (IPAS) menggunakan bahan alam. Bahan alam yang dapat digunakan sebagai filter dalam instalasi penjernihan air sederhana adalah pasir silika dan lempung alam yang diaktivasi. Pengambilan sampel sungai akan dilakukan di DAS (Daerah Aliran Sungai) Kahayan Kalimantan Tengah. Sampling air akan dilakukan pada saat musim kemarau sehingga tidak ada pengaruh pengenceran. Filter pasir silika dan kerikil diperoleh dari toko penjual ikan hias yaitu pasir ukuran halus dan kasar. Filter lempung mangan dapat dibuat dengan menggunakan lempung alam yang perlakukan dengan MnCl2 dan KMnO4. Hasil pengujian menunjukkan filter lempung mangan dan arang aktif mampu menyaring zat-zat berbahaya yang terlarut dalam air, menghilangkan bau dan menjernihkan air sungai kahayan yang keruh. Air sungai kahayan yang sebelum dilakukan penjernihan memiliki nilai pH 5,5, kandungan Fe 2,16 mg/L, total padatan tersuspensi (TSS) 258 mg/L, total padatan terlarut 30 mg/L, kekeruhan 140 NTU dan sangat bau. Setelah dilakukan penjernihan dengan instalasi penjernihan air, penjernihan memiliki nilai pH 6,5, kandungan Fe 0,7 mg/L, total padatan tersuspensi (TSS) 134 mg/L, total padatan terlarut 32 mg/L, kekeruhan 35,3 NTU dan tidak berbau. Hasil penjernihan air ini cukup layak digunanakan sebagai air bersih karena nilai pH, kandungan Fe, TDS, TSS, kekeruhan dan bau sesuai dengan syarat air bersih menurut Permenkes RI No: 416/MENKES/PER/IX/1990.

Evaluasi Prediksi Nilai Higher Heating Value (HHV) Biomassa Berdasarkan Analisis Ultimate: Evaluation of Prediction Higher Heating Value (HHV) of Biomass-Based on Ultimate Analysis Dirgantara, Made; Kristian, Novi; Karelius, Karelius
Jurnal Jejaring Matematika dan Sains Vol. 1 No. 2 (2019): Edisi Desember 2019
Publisher : Fakultas Matematika dan Ilmu Pengetahuan Alam, Universitas Palangka Raya

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.36873/jjms.v1i2.218

Biomassa merupakan energi terbarukan yang sangat penting, dimana keberadaannya dapat menggantikan bahan bakar fosil baik padat maupun cair. Sebagai bahan bakar tentu perlu adanya analisis-analisis untuk mengetahui karakteristik dan kualitas biomassa sehingga kita dapat mengklasifikasikan biomassa yang potensial digunakan sebagai bahan bakar. Nilai kalori atau higher heating value (HHV) merupakan sifat terpenting dari suatu bahan bakar. Pada umumnya pengukuran nilai kalori menggunakan bomb calorimeter, akan tetapi pengukuran ini memerlukan waktu dan biaya sehingga tidak efektif jika yang dianalisis dalam jumlah banyak. Dalam makalah ini akan dibahas persamaan untuk memprediksi nilai HHV biomassa berdasarkan analisis ultimate yang di dapatkan dari penelitian sebelumnya. Empat prediksi nilai HHV menggunakan 15 data komposisi kimia biomassa dari penelitian sebelumnya kemudian dibandingkan berdasarkan ketepatan untuk mendapatkan prediksi terbaik. Persamaan P1 dan P4 terbaik dalam memprediksi nilai HHV berdasarkan data analisis ultimate, dimana masing-masing memprediksi terbaik di lima biomassa. Berdasarkan sumber biomassa, persamaan P1 baik dalam memprediksi hasil perkebunan dan pertanian yang berupa serabut/serat tinggi dengan kadar karbon dan oksigen yang tinggi dan tidak memiliki sulfur. P4 baik dalam memprediksi biomassa hasil sampingan kehutanan dengan karakter tinggi kadar karbon dan oksigen, rendah hydrogen dan oksigen serta memiliki sulfur.

Pemurnian Asap Cair Hasil Torefaksi Cangkang Sawit dengan Cara Destilasi dan Filtrasi dengan Arang Aktif: Purification of Liquid Smoke from Torrefaction of Palm Oil by Distillation and Filtration with Activated Charcoal Karelius, Karelius; Rosmainar, Lilis; Novia Toemon, Angeline; Dirgantara, Made
Jurnal Jejaring Matematika dan Sains Vol. 2 No. 2 (2020): Edisi Desember 2020
Publisher : Fakultas Matematika dan Ilmu Pengetahuan Alam, Universitas Palangka Raya

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.36873/jjms.2020.v2.i2.407

The liquid smoke produced from the torrefaction process of oil palm shells has the potential to be used as an antiseptic base for hand sanitizer and disinfectant products. It is due to its high phenol and acetic acid content. Apart from phenol and acetic acid, there are many other compounds that must be separated in the hope of obtaining liquid smoke with the main components of acetic acid and phenol, which function as antibacterial agents. This research begins with the production of liquid smoke through a torrefaction process. The liquid smoke obtained is distilled at 150 oC and followed by adsorption with activated charcoal for the purification process. The pH value and acetic acid content in the purified liquid smoke were determined and analyzed using GC-MS to determine the chemical compounds. The pH value has decreased after the refining process by distillation, and activated charcoal is inversely proportional to the increase in acetic acid levels after purification. Based on GC-MS analysis results, it can be seen that the levels of acetic acid, phenol, propanoic acid, and 2-propanone increased after distillation. The loss of 1,2-Benzenediol and 2-Furancarboxaldechde compounds shows that distillation of liquid smoke at 150oC is effective for separating the heavy fraction of liquid smoke. Furthermore, the distilled liquid smoke is filtered using activated charcoal. The GC-MS analysis results showed that the filtration results with activated charcoal could increase acetic acid and propanoic acid levels in liquid smoke.

Formulation and Evaluation of Physical Quality of Peel-Oof Masks of Essential Oils of Galam Kalimantan Plants Ayuchecaria, Noverda; Karelius, Karelius; Rosmainar, Lilis; Aryzki, Saftia
Berkala Kedokteran Vol 20, No 1 (2024)
Publisher : Fakultas Kedokteran Universitas Lambung Mangkurat

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.20527/jbk.v20i1.18766

The Kalimantan galam plant (Melaleuca cajuputi subsp cajuputi) has been used for generations but its use is very limited, only as wooden piles which form the basis of buildings in swamps (cerucuk), pillars for building construction, stakes (supports for newly planted seedlings) and siring. Street. The use of galam essential oil as an active ingredient in peel-off mask preparations can be efficacious in reducing inflammation and infection of acne or other skin problems. Facial masks in the form of peel-off itself have many advantages, namely their practical use and are easy to remove or lift like elastic membranes compared to conventional masks which leave residue. This study aims to design a peel-off mask formulation by utilizing the active ingredient in the essential oil of the galam plant. The preparations were then tested for physical quality requirements including organoleptic tests, homogeneity tests, pH tests, drying time tests, spreadability and adhesion tests. The results of the tests that have been carried out include the extraction of essential oils as the active substance. The yield of essential oil obtained was 0.12%. Organoleptic quality tests showed changes in color, smell and shape in the three formulations. The homogeneity test for formulas I and II remained homogeneous, while for formula III the consistency changed to 2 layers. The pH test showed that all formulations met the pH requirements for topical preparations, namely 4-8. The drying time test for formula I was more difficult to remove, formula II was not too stiff while formula III was stiffer. Spreadability test on formulas I, II and III 5-7 cm. The gel viscosity test decreased and the adhesion test on formulation I was easily released, formulas II and III were not easily released while the irritation test of 30 people did not experience redness in 3 formulas.

Significance of Torrefaction Effect on Energy Properties Palm Kernel Shell Dirgantara, Made; Karelius, Karelius; Rumbang, Nyahu
JPSE (Journal of Physical Science and Engineering) Vol 8, No 2 (2023): JPSE (Journal of Physical Science and Engineering)
Publisher : Universitas Negeri Malang

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.17977/um024v8i22023p118

The process of torrefaction is a thermochemical process that is widely used for the conversion of biomass into renewable fuels. In this study, the significance of temperature was determined by carrying out the torrefaction process at temperatures ranging from 275 to 350 degrees Celsius with a fixed residence time of 60 minutes. To ascertain the impact of time on the process, the torrefaction procedure was conducted over a residence time of 20 to 60 minutes at 300°C. Increasing the torrefaction temperature can substantially increase the palm kernel shell's calorific value, decrease water content, decrease volatility, increase fixed carbon, especially from 275 oC to 325 oC, and decrease ash content from 275 oC to 300 oC. Increasing the torrefaction residence time can significantly increase the palm kernel shell's calorific value from 20-40 minutes, decrease ash content and volatile content, and increase fixed carbon from 20-30 minutes. The residence time did not affect the water content in torrefaction temperature at 300 oC. The statistical analysis revealed that temperature and residence time have a substantial impact on the heating value and proximate analysis.

Study on Utilizing Oil Palm Empty Fruit Bunch Waste into Carbon Nanodots Anindita, Faradisa; Naani, La; Permana, Dian; Karelius, Karelius; Kedang, Yohana Ivana
Journal of The Indonesian Society of Integrated Chemistry Vol. 16 No. 2 (2024): Journal of The Indonesian Society of Integrated Chemistry
Publisher : Pendidikan Kimia FKIP Universitas Jambi

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22437/jisic.v16i2.38583

This investigation introduces a proficient synthesis of carbon nanodots (CND) utilizing empty fruit bunches (EFB) as an environmentally friendly and economical carbon precursor. The synthesis method involves a combination of pyrolysis and hydrothermal. The optical and physicochemical properties of CND were investigated through X-ray diffraction (XRD), Fourier Transform Infrared (FTIR), Transmission Electron Microscopy (TEM), Particle Size Analysis (PSA), UV-visible, and fluorescence spectroscopy. The CND exhibit a spherical morphology, as confirmed through TEM imaging, with an amorphous structure. Size distribution analysis reveals a predominant particle size range between 3.8 and 4.8 nm, and an average diameter of 4.5 nm. Additionally, these CND demonstrated excellent aqueous dispersibility and exhibited fluorescence emission dependent on excitation. The synthesis procedure utilized a simple method, efficiently converting waste materials into valuable end products.

Eco-friendly Removal of Methylene Blue Using Alginate-Activated Natural Clay Composite Rasidah, Rasidah; Jumiati, Jumiati; Nugroho, Wahyu; Agnestisia, Retno; Karelius, Karelius; Alfanaar, Rokiy; Muhamad Iqbal, Rendy
ALKIMIA Vol 7 No 1 (2023): ALKIMIA
Publisher : SCIENCE AND TECHNOLOGY FACULTY OF UNIVERSITAS ISLAM NEGERI RADEN FATAH PALEMBANG

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.19109/591htf60

Methylene blue is a poisonous, persistent, and non-biodegradable dye frequently found in textile industry wastewater that significantly influences the emergence of various environmental and health problems. Therefore, precautions must be taken to reduce the amount of methylene blue in the wastewater. Compositing clay into alginate produces an eco-friendly adsorbent, alginate-activated clay composite beads (Ag-AC 1-5%), successfully removing methylene blue. XRD and FTIR spectroscopy characterization results show that illite, a family of 2:1 clay minerals, is a primary constituent of activated clay. However, FTIR spectroscopy shows that alginate has mannuronic acid residue characteristics. Several batch experiments were carried out to evaluate the effect of the alginate: clay ratio and pH solution on the percentage of methylene blue removal.

DECOLORIZATION OF TEXTILE DYES WITH CRUDE LIGNINOLYTIC ENZYMES FROM Coriolopsis caperata Agnestisia, Retno; Karelius, Karelius; Oksal, Efriyana; Nion, Yanetri Asi
Jurnal Bioteknologi dan Biosains Indonesia Vol. 12 No. 1 (2025)
Publisher : BRIN - Badan Riset dan Inovasi Nasional

Show Abstract | Download Original | Original Source | Check in Google Scholar

The textile industry is a major contributor to global water pollution, releasing an estimated 280,000 tons of synthetic dyes annually into aquatic ecosystems. These dyes, particularly azo compounds, are often toxic, mutagenic, and resistant to conventional wastewater treatment methods. Microbial enzymatic degradation, especially by white-rot fungi, offers a promising eco-friendly alternative. This study aimed to optimize the production of ligninolytic enzymes—Laccase (Lac), manganese peroxidase (MnP), and lignin peroxidase (LiP)—from Coriolopsis caperata, and assess their efficiency in degrading two azo dyes: Reactive Red 21 (RR21) and Reactive Orange 107 (RO107). The fungus, isolated from the Peat Swamp Forest in Sebangau, Central Kalimantan, was cultured in a modified glucose-peptone medium enriched with veratryl alcohol. The optimization parameters included variations in time, dye concentration, and the addition of hydrogen peroxide (H₂O₂). Enzyme activity was quantified spectrophotometrically, and dye decolorization was assessed over time at different dye concentrations. Among the enzymes, Lac showed the highest activity (4938.05 U/L), followed by LiP (995.26 U/L) and MnP (246.47 U/L). These values notably exceed several previously reported benchmarks for fungal enzyme activity. RO107 demonstrated greater susceptibility to enzymatic degradation, with 83.71% decolorization achieved at 24 hours, while RR21 reached 65.71% at 48 hours. The addition of 1 mM H₂O₂ significantly enhanced decolorization, increasing RR21 and RO107 removal to 95.71% and 99.30%, respectively. These results underscore the oxidative synergy between H₂O₂ and ligninolytic enzymes, particularly LiP and MnP. Overall, the study demonstrates the potential scalability of C. caperata-based enzymatic treatment systems for textile effluent bioremediation, supporting compliance with environmental discharge regulations and contributing to sustainable wastewater management.

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