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All Journal Journal of Tropical Soils Jurnal Sumberdaya Akuatik Indopasifik Indonesian Journal of Chemistry Cassowary SEMAR Jurnal Natural Panrita Inovasi: Jurnal Pengabdian Kepada Masyarakat
Markus Heryanto Langsa
Jurusan Kimia FMIPA Universitas Papua
Agriculture, Biological Sciences & Forestry Humanities Chemical Engineering, Chemistry & Bioengineering Chemistry Earth & Planetary Sciences Education Environmental Science Languange, Linguistic, Communication & Media Mathematics Physics Public Health Social Sciences

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Journal : Journal of Tropical Soils

 1 
Assessing Biodegradation Susceptibilities of Selected Petroleum Hydrocarbons at Contaminated Soils Markus Heryanto Langsa
JOURNAL OF TROPICAL SOILS Vol 15, No 1: January 2010
Publisher : UNIVERSITY OF LAMPUNG

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.5400/jts.2010.v15i1.39-47

Abstract

Assessing Biodegradation Susceptibilities of Selected Petroleum Hydrocarbons at Contaminated Soils (M.H. Langsa): The susceptibility to biodegradation of selected saturated hydrocarbons (SHCs), polycyclic aromatic hydrocarbons (PAHs) and asphaltenes in a Barrow crude oil and extracts isolated from soils contaminated with the Barrow crude oil at day 0 and 39 was determined. Soil samples were contaminated with a Barrow crude oil across the surface (5% w/w) as part of a mesocosm experiment in order to mimic similar conditions in the environment.  The extent of biodegradation of the Barrow oil extracted from the contaminated soils at day 0 and day 39 was assessed by GC-MS analyses of SHCs and PAHs fractions. Changes in the relative abundances of n-alkanes (loss of low-molecular-weight hydrocarbons) and pristane relative to phytane (Pr/Ph) and their diastereoisomers were determined. Changes in the diastereo-isomer ratios of Pr and Ph relate to the decrease in abundance of the phytol-derived 6(R),10(S) isoprenoids with increasing biodegradation. The percentage change in abundances of each of selected alkylnaphathalenes with time (day 0 to 39) was determined, enabling an order of susceptibility of their isomers to biodegradation. It was established that the 2-methylnaphthalene isomers (2-MN) is more susceptible to microbial attack than 1-MN isomer indicated by decreasing in percent abundance from day 0 to 39 for the 2-MN isomer. The GC-MS analyses of the original Barrow oil indicated the oil had not undergone biodegradation. When this oil was used in the soil mesocosm experiments the oil was shown to biodegrade to about a level 2 -3 based on the biodegradation susceptibility of the various SHCs and PAHs described above.
Assessing Biodegradation Susceptibilities of Selected Petroleum Hydrocarbons at Contaminated Soils Langsa, Markus Heryanto
JOURNAL OF TROPICAL SOILS Vol. 15 No. 1: January 2010
Publisher : UNIVERSITY OF LAMPUNG

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.5400/jts.2010.v15i1.39-47

Abstract

Assessing Biodegradation Susceptibilities of Selected Petroleum Hydrocarbons at Contaminated Soils (M.H. Langsa): The susceptibility to biodegradation of selected saturated hydrocarbons (SHCs), polycyclic aromatic hydrocarbons (PAHs) and asphaltenes in a Barrow crude oil and extracts isolated from soils contaminated with the Barrow crude oil at day 0 and 39 was determined. Soil samples were contaminated with a Barrow crude oil across the surface (5% w/w) as part of a mesocosm experiment in order to mimic similar conditions in the environment.  The extent of biodegradation of the Barrow oil extracted from the contaminated soils at day 0 and day 39 was assessed by GC-MS analyses of SHCs and PAHs fractions. Changes in the relative abundances of n-alkanes (loss of low-molecular-weight hydrocarbons) and pristane relative to phytane (Pr/Ph) and their diastereoisomers were determined. Changes in the diastereo-isomer ratios of Pr and Ph relate to the decrease in abundance of the phytol-derived 6(R),10(S) isoprenoids with increasing biodegradation. The percentage change in abundances of each of selected alkylnaphathalenes with time (day 0 to 39) was determined, enabling an order of susceptibility of their isomers to biodegradation. It was established that the 2-methylnaphthalene isomers (2-MN) is more susceptible to microbial attack than 1-MN isomer indicated by decreasing in percent abundance from day 0 to 39 for the 2-MN isomer. The GC-MS analyses of the original Barrow oil indicated the oil had not undergone biodegradation. When this oil was used in the soil mesocosm experiments the oil was shown to biodegrade to about a level 2 -3 based on the biodegradation susceptibility of the various SHCs and PAHs described above.
Co-Authors Alfhons D. Sirampun Alfhons Daniel Sirampun Alfhons Daniel Sirampun Aprilia Regita Sari Aronggear, Pitornela Ribka Aulia Ekamala Wakang Wakang Bertha Mangallo Bimo Budi Santoso Darma Santi Darma Santi Darma Santi Emma Manjauna Hendri Islam, Muhammad Fajar Jacson Victor Morin Jacson Victor Morin Kristina Daundi Lisna Efiyanti, Lisna Efiyanti Maria Ludya Pulung Morin, Jacson Viktor Novitasari, Agnes Dyah Pramesty Wulan Ramadhanty Rina A. Mogea Roy Klivorth Max Raturoma Santoso, Bimo Budi Sirampun, Alfhons Daniel Somar, Evelina Sumarna, Sabir Susilowati Susilowati Taher, Achmad Tresia Tururaja Yuliana Yuliana