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Azzahra, Atina Sabila
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Chemical Engineering, Chemistry & Bioengineering Chemistry

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Screening Support of Bimetallic Ruthenium-Tin Catalysts for Aqueous Phase Hydrogenolysis of Furfuryl Alcohol to 1,5-Pentanediol Rodiansono, Rodiansono; Azzahra, Atina Sabila; Mikrianto, Edi; Ridhoni, Arif; Mustari, Ikhsan; Nurfitriani, Anggita; Bodoi, Thea Seventina Desiani; Sanjaya, Rahmat Eko; Suarso, Eka; Ansyah, Pathur Razi
Bulletin of Chemical Reaction Engineering & Catalysis 2025: BCREC Volume 20 Issue 2 Year 2025 (August 2025)
Publisher : Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.9767/bcrec.20357

Abstract

The selective aqueous phase hydrogenolysis of furfuryl alcohol (FFalc) to 1,5-pentanediol (1,5-PeD) using supported bimetallic ruthenium-tin (Ru-Sn) catalysts on various metal oxide supports (e.g., TiO2, ZnO, ZrO2, Nb2O5, g-Al2O3) and its combination were investigated systematically. The catalysts were prepared via coprecipitation-hydrothermal at 150 oC for 24 h, followed by reduction with H2 at 400 oC for 2 h. Supported Ru-Sn on TiO2(A), g-Al2O3, and ZrO2 catalysts exhibited higher yield of 1,5-PeD (55-69%) than that other catalysts at 180 oC, H2 10-30 bar for 3-5 h. However, those supported catalysts showed poor recyclability after the first reaction run, and therefore further examination on g-Al2O3 supported Ru-Sn was performed. The Ru-Sn catalyst supported on g-Al2O3-metal oxide composites (metal oxides: ZrO2, TiO2(A), TiO2(R), ZnO, Nb2O5, and C) afforded higher FFalc conversion and yield of 1,5-PeD than that of unmodified g-Al2O3 at 180 oC, H2 30 bar for 3 h. Among them, the Ru-Sn/g-Al2O3-TiO2(A) (33%) catalyst could afford the highest yield of 1,5-PeD (80%) at 99% conversion FFalc at 180 oC, H2 10 bar for 5 h. Around 95% of this catalyst can be recycled after the second reaction run and the activity can be restored to initial after reactivation with H2 at 400 oC for 2 h with a 69% yield of 1,5-PeD at 97% FFalc conversion. Copyright © 2025 by Authors, Published by BCREC Publishing Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0).
Bimetallic Ru-Sn as Effective Catalysts for the Selective Hydrogenation of Biogenic Platform Chemicals at Room Temperature Azzahra, Atina Sabila; Dewi, Heny Puspita; Mikrianto, Edi; Sembiring, Kiky Corneliasari; Sunnardianto, Gagus Ketut; Nata, Iryanti Fatyasari; Rodiansono, Rodiansono; Jayanudin, Jayanudin
Bulletin of Chemical Reaction Engineering & Catalysis 2023: BCREC Volume 18 Issue 4 Year 2023 (December 2023)
Publisher : Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.9767/bcrec.20067

Abstract

Supported bimetallic ruthenium-tin (denoted as Ru-Sn(x); x = molar ratio of Ru/Sn) catalysts were examined for room temperature (RT) hydrogenation of biogenic platform chemicals of levulinic acid (LA) to g-valerolactone (GVL). Six types of metal oxide support c.a. Nb2O5, TiO2, ZnO, ZrO2, g-Al2O3, active charcoal (AC), were employed as the support for Ru-Sn(x). Ru-Sn(3.0)/Nb2O5 (Ru/Sn = 3.0) that reduced at 500 oC demonstrated the highest yield of GVL (98%) at 30 oC, 30 bar H2 for 3 h. The increase in Sn loading amount (Ru/Sn = 1.5) resulted in decreasing of LA conversion (83%) under the same reaction conditions. Among the studied supported Ru-Sn catalysts, Nb2O5 and ZnO supports exhibited better catalytic performances than that other for RT hydrogenation of LA and various biogenic platform chemicals. The Ru-Sn(3.0)/Nb2O5 catalyst was characterized by means of various adsorption and spectroscopic techniques. The Ru-Sn(3.0)/Nb2O5 catalyst was found to be reusable without any significant loss of its activity. Copyright © 2023 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA  License (https://creativecommons.org/licenses/by-sa/4.0). 
Crystal Phase-Dependence of Ru@TiO2 Catalysts on the Product Selectivity in the Aqueous Phase Hydrogenolysis of Furfuryl Alcohol Bodoi, Thea Seventina Desiani; Rifwanda, Shauqi Aulia; Rodiansono, Rodiansono; Azzahra, Atina Sabila; Irawati, Utami; Oemry, Ferensa; Sunnardianto, Gagus Ketut; Adilina, Indri Badri; Hara, Takayoshi
Bulletin of Chemical Reaction Engineering & Catalysis 2026: BCREC Volume 21 Issue 1 Year 2026 (April 2026)
Publisher : Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.9767/bcrec.20547

Abstract

The crystal phase-dependence of ruthenium supported on titania (Ru@TiO2) catalysts on the product selectivity in the aqueous phase hydrogenolysis of furfuryl alcohol (FFalc) was investigated. The supported ruthenium nanoparticles (RuNPs) catalysts on TiO2 with different phases, c.a. rutile (R), anatase (A), and brookite (B) were employed. The Ru@TiO2(R) catalysed the hydrogenation-rearrangement reaction of furan ring to afford cyclopentanone/cyclopentanol (CPO/CPL) as the main product. The presence of high surface acidity in Ru@TiO2(R) catalyst promoted the hydrogenation-rearrangement of furan ring leading to CPO/CPL as the main product as indicated by NH3-TPD and pyridine-ATR-IR results. In contrast, the Ru@TiO2(A) catalyst selectively hydrogenolysed the furan ring to produce 1,5-pentanediol (1,5-PeD). This high selectivity of 1,5-PeD over Ru@TiO2(A) catalyst may be affected by the high dispersion of Ru NPs on TiO2 facets as depicted by the high H2-uptake and small particle sizes. Copyright © 2026 by Authors, Published by BCREC Publishing Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0).
Co-Authors Adilina, Indri Badri Bodoi, Thea Seventina Desiani Dewi, Heny Puspita Edi Mikrianto Ferensa Oemry Iryanti Fatyasari Nata, Iryanti Fatyasari Jayanudin Jayanudin Kiky Corneliasari Sembiring Mustari, Ikhsan Nurfitriani, Anggita Pathur Razi Ansyah Rahmat Eko Sanjaya Ridhoni, Arif Rifwanda, Shauqi Aulia Rodiansono Rodiansono Suarso, Eka Sunnardianto, Gagus Ketut Takayoshi Hara Utami Irawati