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All Journal The Journal of Pure and Applied Chemistry Research As-syifaa Jurnal Farmasi Window of Health : Jurnal Kesehatan Chemistry Indonesian Journal of Chemical Research Molekul: Jurnal Ilmiah Kimia
Seniwati Dali
Jurusan Kimia, Fakultas Matematika dan Ilmu Pengetahuan Alam, Universitas Hasanuddin
Biochemistry, Genetics & Molecular Biology Chemical Engineering, Chemistry & Bioengineering Chemistry Engineering Environmental Science Health Professions Immunology & microbiology Materials Science & Nanotechnology Medicine & Pharmacology Nursing Public Health

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Analisis Logam Berat Cd Dalam Alga Eucheuma cottoni Di Perairan Kabupaten Bantaeng Teheni, Muhammad T.; La Nafie, Nursiah; Dali, Seniwati
Indonesian Journal of Chemical Research Vol 4 No 1 (2016): Edisi Bulan Juli (Edition For July)
Publisher : Jurusan Kimia, Fakultas Matematika dan Ilmu Pengetahuan Alam, Universitas Pattimura

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.30598/ijcr.2016.4-teh

Abstract

Algae is a plant which life in the marine with a lot of diversification such as: single and multi-cellular. Commonly, it contains chlorophyll without stem and roots. A species of algae in Indonesia which has high economic value is Eucheuma cottoni. It is cultured in Bantaeng as the central production of algae in South Sulawesi. The aim of this research is to know the concentration of heavy metals Cadmium in algae at region Bantaeng coastal. Concentration of cadmium was determined by atomic absorption spectrophotometer (AAS). This analysis was done by destruction process using concentrated HNO3. Sampling was done at 6 different location, they are: Nipa-nipa, Bakara, Boroloe, Tapaloe, Baruga village and Baruga from north to south. The experiment result show that the highest concentration of Cd is in Nipa-nipa village, with 0.2920 ppm and the lowest in Baruga village is 0.1824 ppm. The concentration of Cd in algae Eucheuma cottoni in those 6 different location had been more than limited which had been determined by the decision of national of environmental ministry number 51 year 2004, they are 0.01 and 0.05 ppm.
Analisis Senyawa Piren pada Alga Laut Eucheuma cottoni Di Perairan Kabupaten Bantaeng Yusuf, Evana Y.; La Nafie, Nursiah; Dali, Seniwati
Indonesian Journal of Chemical Research Vol 4 No 1 (2016): Edisi Bulan Juli (Edition For July)
Publisher : Jurusan Kimia, Fakultas Matematika dan Ilmu Pengetahuan Alam, Universitas Pattimura

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.30598/ijcr.2016.4-eva

Abstract

The compounds pyrene is one of the polycyclic aromatic hydrocarbons (HAP) which is derived from petroleum. These compounds are carcinogenic and toxic for the marine biota. The purpose of this study to determine the levels of pyrene compounds in marine algae. In this research, analysis of pyrene compounds in marine algae Eucheuma cottonii using the method of GC - MS (Gas Chromatography - Mass spectrophotometry). Sampling was conducted in the waters the Bantaeng Regency with a 6 point sampling different locations namely Nipa-nipa, Bakara, Boroloe, Tapaloe, Baruga village and Baruga. The results showed that the concentration of pyrene compounds found in marine algae Eucheuma cottonii at 6 locations in waters the Bantaeng Regency has a concentration low enough pyrene compounds that is 0009-0063 ppm. This means that the concentration of pyrene was obtained below the threshold value determined by the decision of national of Environmental ministry for the marine life.
Produksi DAG Dari Virgin Coconut Oil (VCO) Melalui Reaksi Trans-Esterifikasi Menggunakan Enzim Lipase Dedak Padi (Oryza Sativa L.) Spesifik C18-20 Terimobilisasi Karbon Aktif Sebagai Biokatalis Dali, Seniwati; Firdaus, Firdaus; Rusman, Hendra J.
Indonesian Journal of Chemical Research Vol 5 No 1 (2017): Edisi Bulan Juli (Edition For July)
Publisher : Jurusan Kimia, Fakultas Matematika dan Ilmu Pengetahuan Alam, Universitas Pattimura

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.30598/ijcr.2017.5-sen

Abstract

This research aims to produce DAG of the VCO through the substrate reaction of trans-esterification using lipase enzymes specifically C18-20 from rice bran (Oryza Sativa L.) immobiled of activated carbon as a catalyst. Phases of this research starts with the enzyme lipase do immobile using activated carbon; next enzymes of immobile used to produce DAG through the trans-esterification reaction using a VCO as a substrate and methanol as ko-substrate; DAG and methyl ester produced identified using FTIR instrument and GC-MS instruments. The results showed that there were three compounds DAG and three compound methyl ester produced trans-esterification reaction, namely (1) 1-laurin, 3-heksanoin esters of glycerol; (2) 2-laurin, 3-oktanoin esters of glycerol; (3) 1-laurin, 3-heksanoin esters of glycerol; (4) methyl ester oleic; (5) methyl ester stearic acids; and (6) methyl ester arachidat.
Imobilisasi Enzim Lipase Dedak Padi (Oryza Sativa L.) Pada Karbon Aktif: Karakterisasi, dan Uji Stabilitas Kerja Enzim Imobil Firdaus, Firdaus; Dali, Seniwati; Rusman, Hendra J.
Indonesian Journal of Chemical Research Vol 5 No 1 (2017): Edisi Bulan Juli (Edition For July)
Publisher : Jurusan Kimia, Fakultas Matematika dan Ilmu Pengetahuan Alam, Universitas Pattimura

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.30598/ijcr.2017.5-fir

Abstract

This research aims to immobilization; characterize the enzyme of immobilized, test the effectiveness of the enzyme of immobilized. This research begins with the immobilization to process of enzyme lipase using activated carbon matrix, enzyme characterization covering of immobile determination of temperature and pH optimum of the enzyme of immobilized, as well as test the stability of work covering immobilized of enzyme the test thermal stability and repeated use. The results showed that the immobile of enzyme work optimally at 50oC of temperature and pH 6.5 with each activity 0.040 U/mL; research results also showed that the immobile of enzyme has higher thermal stability in comparison with the free enzyme: with the relative activity of 57.50% at the time of 45 minutes of exposure and the exposure time at 47.50% at 75-105 minutes and it can be used as many as six times with the relative activity of 52.5% in 6 times of use.
Isolasi, Identifikasi, Karakterisasi Dan Uji Toksisitas Senyawa Metabolit Sekunder Fraksi Nonpolar Akar Babandotan (Ageratum conyzoides L) Irmawan, Muhammad; Mandey, Frederyk; Dali, Seniwati
Indonesian Journal of Chemical Research Vol 6 No 1 (2018): Edisi Bulan Juli (Edition For July)
Publisher : Jurusan Kimia, Fakultas Matematika dan Ilmu Pengetahuan Alam, Universitas Pattimura

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.30598/ijcr.2018.6-muh

Abstract

Ageratum Conyzoides L. has a toxic and bioactive component as anti-cancer and especially for the root, it has anti-tumor. In order to figure out the active component, it is necessary to do four steps; isolation, identification, characterization, and toxicity essay Brine Shrimp Lethality Test (BSLT) of non-polar fraction Ageratum conyzoides L plant. Isolation method consist of four parts; extraction, partitioning of Kupchan method, fractionation, and purification. Fractionation method uses press column chromatography (KTT). Furthermore, purification process uses thin layer chromatography (TLC) and characterization with spectroscopy FTIR, 1H-NMR and 13C-NMR. Then characterization utilizes spectroscopy FTIR, 1H-NMR and 13C-NMR. The toxicity essay toward Artemia Salina Leach n-hexane fraction and dichloromethane fraction showed that the fraction had toxic properties with number of LC50 are 0,0237 and 4,642 µg/mL respectively. Moreover, n-hexane fraction has succeed in isolating Stigmasterol compound shaped white crystalline needles with 19.6 mg weight, 143-144 °C melting point and and had toxic properties with number of LC50 are 30,33 µg/mL.
Synthesis of Glucopyranosyl Acetic from Sago Flour as Raw Material for the Synthetic Polymers Dali, Arniah; Dali, Nasriadi; Dali, Seniwati; Amalia, Hilda Ayu Melvi
Indonesian Journal of Chemical Research Vol 8 No 3 (2021): Edition for January 2021
Publisher : Jurusan Kimia, Fakultas Matematika dan Ilmu Pengetahuan Alam, Universitas Pattimura

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.30598/ijcr.2021.8-dal

Abstract

Synthesis of glucopyranosyl acetic from sago flour as raw material for the synthetic polymers has been successfully carried out. The synthesis product is obtained through two reaction stages, namely the hydrolysis and esterification reactions. Sago flour is hydrolyzed with 25% HCl and neutralized with 45% NaOH. Glucose hydrolysis of sago starch and acetic anhydride was esterified using a zinc chloride catalyst. Synthesis product was obtained as a white solid substance (57.31% recovery), a melting point of 110 - 111oC, and Rf 0.79 on TLC (SiO2, n-hexane: ethyl acetate = 9:1 v/v). The results of the analysis of synthesis products with FTIR and GC-MS spectrometers showed that the synthesis product was glucopyranosyl acetic or 2,3,4,6-tetra-O-acetyl glucopyranose.
Extraction of The Chemical Components of Dengen Leaves (Dillenia serrata Thunb) by MAE Method and Activity Test as Antioxidant and Toxicity Wela, Nasriadi Dali; Dali, Seniwati; Chairunnas, Armadi; Amalia, Hilda Ayu Melvi; Puspitasari, Sri Ayu Andini
Indonesian Journal of Chemical Research Vol 10 No 2 (2022): Edition for September 2022
Publisher : Jurusan Kimia, Fakultas Matematika dan Ilmu Pengetahuan Alam, Universitas Pattimura

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.30598//ijcr.2022.10-wel

Abstract

Research on the extraction of chemical components of Dengen (Dillenia serrata Thumb) leaves using the MAE (microwave-assisted extraction) method and activity as an antioxidant and toxicity test has been carried out. This study aimed to extract the chemical components of Dengen leaves using the MAE method and to test the antioxidant activity and toxicity of the ethanol extract of Dengen leaves. The chemical components of Dengen leaves were extracted by the MAE method and obtained ethanol extract with a yield of 47%. Dengen leaves ethanol extract was partitioned with n-hexane and ethanol as solvents and obtained yields of 5% (n-hexane) and 65% (ethanol). The chemical components of Dengen leave ethanol extract were identified by phytochemical screening. The results of phytochemical screening showed the presence of secondary metabolites of alkaloids, flavonoids, saponins, polyphenols, terpenoids, and steroids. The antioxidant activity test of the ethanol extract of Dengen leaves was carried out using the DPPH (2,2-diphenyl-1-picrihydrazil) method and obtained the value of IC50 = 100,363 ppm (strong antioxidant). A toxicity test of the ethanol extract of Dengen leaves was carried out using the BSLT (Brine Shrimp Lethality Test) method and obtained the value of LC50 = 18.3443 ppm (very toxic).
Adsorption of Bismarck Brown R Dyes Using Mesoporous Silica MCM-48 Zakir, Muhammad; Nuraeni, Andi; Taba, Paulina; Wahab, Abdul Wahid; Dali, Seniwati; Kasim, Syaharuddin; Nafie, Nursiah La
Indonesian Journal of Chemical Research Vol 10 No 2 (2022): Edition for September 2022
Publisher : Jurusan Kimia, Fakultas Matematika dan Ilmu Pengetahuan Alam, Universitas Pattimura

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.30598//ijcr.2022.10-muh

Abstract

The adsorption of Bismarck Brown R (BBR) dye has been conducted using mesoporous silica (MCM-48). We synthesized the adsorbent using Ludox HS-40 as a silica source and surfactants of Cetyl Trimethylammonium Bromide (CTAB) and Triton X-100. The characterization of MCM-48 was performed using Fourier transform infrared (FTIR), X-ray diffraction (XRD), and scanning electron microscopy (SEM). Various contact times were used to study the adsorption kinetics, and concentrations were used to study the adsorption isotherm. The optimum contact time of Bismarck Brown R dye was 120 minutes, and the adsorption followed a pseudo-second-order model. Based on the equation Langmuir and Freundlich adsorption isotherms, the adsorption capacity values of each are obtained 158.7301 mg g-1 and 4.3601 mg g-1. Our results showed that the material can be used as a new dye adsorbent.
Potential Cassava Skin Waste (Manihot esculenta C.) In the Production of Bioethanol by Enzymatic Hydrolysis and Fermentation Using Zymomonas mobilis Bacteria Permatasari, Nur Umriani; Dali, Seniwati; Wahyuni, Eka Sry
The Journal of Pure and Applied Chemistry Research Vol 12, No 2 (2023): May-August 2023
Publisher : Chemistry Department, The University of Brawijaya

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.21776/ub.jpacr.2023.012.02.3304

Abstract

Cassava is one of the most widely produced agricultural products in Indonesia with cassava peel waste of 20%. Cassava peel contains carbohydrates and stores a high cellulose content so that it has a potential to be a bioethanol. This study aims to utilize cassava peel waste for bioethanol production with an alkaline pretreatment process, cellulase enzyme hydrolysis and fermentation by using Zymomonas mobilis bacteria. Alkaline pretreatment with 14% NaOH is used to hydrolyze lignocellulose. The hydrolysis optimization process enzymatically applies the Surface Response Method (RSM) to determine the optimum conditions at hydrolysis pH in the range of 2-10 and hydrolysis temperature in the range of 30-70 °C by analyzing glucose levels using the Dinitrosalicylic Acid (DNS) method and UV-vis spectrophotometry instruments. Surface Response Method (RSM) is likewise implemented to decide the greatest conditions of the fermentation process. The pH measurement ranges 2-10, and fermentation time takes 6 to 168 hours. Based on the results of research, it results a lignin content of 6.68% (b/b), cellulose content of 58.4% (b/b), and hemicellulose content of 27.3% (b/b). The optimum conditions of the hydrolysis process obtained an optimum glucose level of 9.22mg/mL at pH 2 and a hydrolysis temperature of 50°C. The optimum conditions of the fermentation process use Zymomonas mobilis at pH 6 while fermentation time takes 168 hours analyzed using a refractometer produced a bioethanol content of 37.75% (v/v) and a gas chromatography produced a bioethanol content of 54.94% (v/v).
Co-Authors A Amaliah Dahlia Abdul Wahid Wahab Amalia, Hilda Ayu Melvi Arfah, Rugaiyah Chairunnas, Armadi Dali, Arniah Firdaus Firdaus Harti Widiastuti Hasnah Natsir Irmawan, Muhammad Jayawarsa, A.A. Ketut Mandey, Frederyk Maswati Baharuddin Maulidiyah, Zakiya Muammar Fawwaz Muhafidzah, Zahrah Muhammad Zakir Nasriadi Dali Nasution, Annio Indah Lestari Nur Ramadhana Dewi Safitri, Nur Ramadhana Dewi NURAENI, ANDI Nursiah La Nafie Nursiah La Nafie Nuryadin, Yudhi Nuryadin, Yudhi Paulina Taba Permatasari, Nur Umriani Puspitasari, Sri Ayu Andini R. Rusli Riskawati Riskawati, Riskawati Rusman, Hendra J. Sarni Sarni Syaharuddin Kasim Syarif, Rezky Amriati Tadjuddin Naid Teheni, Muhammad T. Uto, Sahriani Wabula, Rheytno Asdin Wahyuni, Eka Sry Yusuf, Evana Y.