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ANALISIS PARAMETER MIKROSTRUKTUR NANOPARTIKEL Mn1-xZnxFe2O4 BERDASARKAN POLA DIFRAKSI SINAR X Indrayana, I Putu Tedy
JST (Jurnal Sains dan Teknologi) Vol. 8 No. 1 (2019)
Publisher : Universitas Pendidikan Ganesha

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (1488.068 KB) | DOI: 10.23887/jstundiksha.v8i1.13016

Abstract

The Mn-Zn Ferit is a magnetic material which has potential applications for data storage device, the inductor coil and catalysis. This material has unique electrical and optical properties. Their properties are microstructural dependent. In this work, we studied the microstructural parameters of Mn1-xZnxFe2O4 which x assigns the mole fraction of Mn2+ and Zn2+ (x = 0.6; 0.7 and 0.8). Samples were synthesized by using coprecipitation method and NaOH as a coprecipitant. Microstructural parameters were investigated based on X-ray diffraction pattern. The crystallite size and strain were determined by using Size-strain plot (SSP) method. The crystallite size of nanoparticles is in a range of 18.9 nm – 24.8 nm, while the strain is in a range of 0.0012 – 0.0099. The lattice parameter is in a range of 8.531Ǻ - 8.567Ǻ bigger than the values were calculated theoretically according to the theoretical cation distribution model. The cation distribution in crystal lattice takes important rule in determining the microstructural parameters of nanoparticles. 
PARTICLES SIZE AND LATTICE STRAIN EFFECT ON THE OPTICAL CONSTANTS OF Fe3O4 NANOPARTICLES Indrayana, I Putu Tedy; Tuny, Margaretha Tabita
Indonesian Physical Review Vol. 4 No. 1 (2021)
Publisher : Universitas Mataram

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.29303/ipr.v4i1.71

Abstract

In the case of optical sensors such as the Surface Plasmon Resonance (SPR) sensor, the Fe3O4 nanoparticles play a role to boost the signal however they can increase the detection sensitivity of the biosensor. For this application, the optical properties of Fe3O4 nanoparticles need to be studied. The optical properties are described in terms of their optical constants. Therefore, this work was purposed to study the effect of the particle size and lattice strain on the optical constants of Fe3O4 nanoparticles. Samples were synthesized by using the coprecipitation technique. Two calcination temperatures, i.e., 150oC and 250oC for 4 hours were applied to the samples. Samples were characterized for their diffraction pattern and optical properties by using XRD and Specular UV-Vis Spectroscopy technique, consecutively. The particle size and lattice strain were estimated by using the Williamson-Hall (W-H) method. The effect of the particle size and their optical constants on the reflectance curve in the SPR sensor application was also performed toward a simulation by using Winspall 3.02 software. The results show that calcination temperature causes an increase in particle size and a decrease in lattice strain. The optical constants, such as absorbance (A), absorption coefficient (α), extinction coefficient (k), refractive index (n), dielectric constants (ε), optical conductivity (σ), and the Urbach energy (Eu) significantly depended on particles size and lattice strain. However, the particle size and optical constant were significantly influent the SPR angle in the reflectance curve of Fe3O4