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All Journal Reaktor Jurnal Sains Materi Indonesia JURNAL INTEGRASI PROSES Jurnal Teknologi ASEAN Journal of Chemical Engineering Jurnal Teknik Kimia Indonesia Proceedings Series on Physical & Formal Sciences Makara Journal of Technology Proceeding ISETH (International Summit on Science, Technology, and Humanity) Jurnal Teknik Kimia dan Lingkungan Scientific Contributions Oil and Gas LEMBARAN PUBLIKASI MINYAK DAN GAS BUMI (LPMGB)
Nelson Saksono
Department Of Chemical Engineering, Universitas Indonesia, Depok 16424, Indonesia
Automotive Engineering Biochemistry, Genetics & Molecular Biology Chemical Engineering, Chemistry & Bioengineering Chemistry Civil Engineering, Building, Construction & Architecture Computer Science & IT Control & Systems Engineering Electrical & Electronics Engineering Energy Engineering Materials Science & Nanotechnology Mechanical Engineering Medicine & Pharmacology Social Sciences Other

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Effects of Ph on Calcium Carbonate Precipitation Under Magnetic Field Saksono, Nelson; Yuliusman, Yuliusman; Bismo, Setijo; Soemantojo, Roekmijati W.; Manaf, Azwar
Makara Journal of Technology Vol. 13, No. 2
Publisher : UI Scholars Hub

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Abstract

Magnetic field effect on CaCO3 precipitation is the key parameter in evaluating the effectiveness of Anti-scale Magnetic Treatment (AMT). The purpose of this study was to investigate magnetic fields influence on CaCO3 precipitation in high and low super-saturated CaCO3 solution by varied pH CaCO3 solution using circulation flow fluid system. The observation results in the high super saturated solution (pH 8.5) showed the increase of precipited CaCO3 in magnetized solutions compared to those in non-magnetic solution during circulation process. In the low super-saturated CaCO3 solution (pH 6.4) it was found that magnetic treatment increased CaCO3 precipitation after circulation process. In high super-saturated solution, magnetic field strengthens ion interactions, which reduce precipitation during circulation process. However, in low super-saturated CaCO3 solution, magnetic field weakens hydrate ion interaction which indicated by decreasing of the conductivity of solution. It increases the precipitation of CaCO3 after the circulation of magnetization process has completed.
Formation of CaCO3 Particle and Conductivity of Na2CO3 and CaCl2 Solution Under Magnetic Field on Dynamic Fluid System Saksono, Nelson; Bismo, Setijo; Widaningroem, Roekmijati; Manaf, Azwar
Makara Journal of Technology Vol. 15, No. 1
Publisher : UI Scholars Hub

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Abstract

Hard water causes the CaCO3 scale formation on the pipe walls and heat exchanger equipments in industrial or domestic water processes. A great number of experimental researches on the prevention of the CaCO3 precipitation process by magnetic field have been carried out. In this research, Na2CO3 and CaCl2 solutions was magnetized in the circulated flow condition (dynamic fluid system). The velocity of fluid and the circulation time was modified to examine its influences to the magnetization process. CaCO3 content was measured by titration method of EDTA complexometry. Conductivity test was conducted to find out hydrate ion bonding. The results showed that magnetization increased the CaCO3 formation and the optimum process reaches for 10 minutes circulation on 0.554 m/s of flow rate. Magnetic field decreases the conductivities of Na2CO3 and CaCl2 solution, hence reduced the ion hydrate bonding. These results showed that magnetization on Na2CO3 and CaCl2 ionic solution was effective in controlling the CaCO3 formation by increasing CaCO3 precipitation.
The Plasma Electrolysis Phenomenon in a Two-Compartment Reactor for Chlor-Alkali Production Saksono, Nelson; Abqari, Fakhrian; Bismo, Setijo
Makara Journal of Technology Vol. 17, No. 2
Publisher : UI Scholars Hub

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Abstract

Chlor-alkali is one of the most important processes in the chemical industry. It produces chlorine and caustic soda, which become the main feedstock of daily products. The aim of this study is to report the phenomenon of plasma electrolysis and how it can be used in chlor-alkali production for more efficient energy consumption. When the plasma is formed, the current fluctuates and gradually declines. Plasma electrolysis begins with the process of electrolysis itself. Due to Joule heating, gas bubbles are formed and a sheath is made on both electrodes, resulting in the plasma field. Plasma electrolysis can be identified by its radical production. The higher the voltage and concentration, the greater the production of radicals. In 10 minutes or less, the number of OH radicals produced can reach 4 ppm at 400 V and 0.1 M. This amount is relatively small and is caused by other reactions consuming OH radicals to form other radicals such as chlorine. The energy consumption of plasma electrolysis in this study can reach 16 kJ/mmol Cl2 at 0.5 M NaCl solution.
The Effect of Power on Nitrate Synthesis and The Emission Intensities of Reactive Species Using Anodic Plasma Electrolysis Harianingsih Harianingsih; Nelson Saksono; Eva Fathul Karamah; Zainal Zakaria
ASEAN Journal of Chemical Engineering Vol 22, No 2 (2022)
Publisher : Department of Chemical Engineering, Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22146/ajche.76790

Abstract

Nitrates are used as fertilizer to fulfill nutrients for plants. Anodic plasma electrolysis technology can be an effective and environmentally friendly solution in nitrogen fixation into nitrate compounds. This research aimed to determine the effect of controlling voltage and power in nitrate synthesis using plasma electrolysis with air as the raw material injected at the anode. The material used is an electrolyte solution of 0.02 M K2SO4, the electrodes used are in the form of tungsten and stainless steel, and a nitrate reagent is used for the nitrate test. The results of the study showed that at 400 W, the optimal rate was 0.8 L men-1 with 1889 mg L-1 of nitrate formed. While at 500 W and 600 W, the optimal rate of 1 L men-1 with nitrate formed was 2213 mg L-1 and 2453 mg L-1. The emission intensities of reactive species N, N2*, N2+,•OH, •H, and •O at an optimal rate of 0.8 L men-1 400 W 700 V in 20139 au, 28540 au, 18023 au, 30863 au, 12547 au, 49800 au. The addition of air injection will increase the oxygen input into the plasma zone, which can produce reactive species •O and nitrogen produces reactive species N, N2*, N2+ forms NO. The formed NO compounds can be oxidized to NO2, and the reaction between NO2 and reactive species •OH forms nitrates. 
Pengaruh Kedalaman Anoda pada Metode Contact Glow Discharge Electrolysis (CGDE) dalam Degradasi Pewarna Tekstil Remazol Red Dian Ratna Suminar; Nelson Saksono
Jurnal Teknik Kimia dan Lingkungan Vol. 2 No. 2 (2018): October 2018
Publisher : Politeknik Negeri Malang

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (892.228 KB) | DOI: 10.33795/jtkl.v2i2.74

Abstract

Limbah pewarna tekstil yang mempunyai komponen utamanya zat pewarna sintesis berbahaya bagi lingkungan sekitar. Pengolahan limbah pewarna tekstil secara fisika dan biologi kurang efektif. Elektrolisis plasma dengan menggunakan metode Contact Glow Discharge Electrolysis (CGDE) merupakan bagian dari pengolahan secara kimiawi, yang efektif dalam mengolah limbah pewarna batik. Parameter kedalaman anoda sangat mempengaruhi dalam proses elektrolisis plasma metode CGDE. Tujuan penelitian ini adalah untuk mengetahui pengaruh kedalaman anoda terhadap produksi •OH, energi yang digunakan proses degradasi, persen dekolorisasi Remazol Red RB 133, serta mengetahui penurunan konsentrasi COD limbah pewarna batik Remazol Red RB 133. Kedalaman anoda dalam penelitian ini adalah 1,5 cm dimana produksi •OH sebesar 11,63 mmol dan energi proses selama 30 menit adalah 806,4 KJ. Persen dekolorisasi Remazol Red RB 133 pada konsentrasi 250 ppm, terbesar selama 30 menit mencapai 99,66 %, pada kedalaman 4,5 cm dengan energi 1075,212 KJ. Nilai COD limbah pewarna batik Remazol Red RB 133 menurun dari 169 mg/L menjadi 3,6 mg/L setelah proses CGDE selama 180 menit (sesuai dengan baku mutu limbah). Textile dye waste having the main component of synthetic dye is hazardous to the surrounding environment. Textile dye waste treatment is physically and biologically less effective. Electrolysis plasma that used Contact Glow Discharge Electrolysis (CGDE) method is part of chemical treatment. The anode depth parameters greatly affect the electrolysis CGDE method. The purpose of this study was to determine the effect of anode depth on • OH production, the energy used in the degradation process, percent decolorization of Remazol Red RB 133, as well as knowing the decrease in COD concentration of Remazol Red batik dye RB 133. The anode depth in this study is 1.5 cm where the production of OH • 11.63 mmol and the processing energy for 30 minutes is 806.4 KJ. The largest Percentage degradation of Remazol Red RB 133 at concentration 250 ppm is 99,66%, that’s reach at depth 4.5 cm for 30 minutes with energy 1075,212 KJ. COD value has decreased from 169 mg/L to 3,6 mg/L after 180 minutes CGDE process (conform to waste quality standards).
The Effect of Air Injection for Formation of Radicals in Liquid Glow Discharge Plasma Electrolysis with K2SO4 Solution Harianingsih, Harianingsih; Rengga, Woro Dyah Pita; Kusumaningrum, Maharani; Imani, Nadya Alfa Cahaya; Saksono, Nelson; Zakaria, Zainal
Reaktor Volume 23 No.2 August 2023
Publisher : Department of Chemical Engineering, Faculty of Engineering, Universitas Diponegoro

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.14710/reaktor.23.2.37-43

Abstract

Glow discharge is part of the phenomenon of plasma formation on the electrode side in contact with the electrolyte solution and begins with an electrolysis reaction with direct electric current. In this research, 0.02 M K2SO4 electrolyte was used, the anode in the form of tungsten and stainless steel for the cathode in a direct current plasma electrolysis reactor. The phenomenon of plasma formation is explained using a strong current and voltage characteristic curve. There are three plasma formation zones: the ohmic zone, the transition zone and the glow discharge plasma zone. Air injection affects the formation of glow discharge plasma and radicals. Without the injection of air, radicals formed only •OH, •H and •O with emission intensities of 20012 a.u, 10121 a.u and 10245 a.u. Air injection 0.8 L men-1 produced radicals •OH, •N, •N2*, •N2+, •H and •O with emission intensities of 30863a.u, 20139 a.u, 28540 a.u, 18023 a.u, 12547 a.u and 49800 a.u. Many radicals are generated when the plasma reaches stability. The plasma is dominated by H2O ionization, and the plasma is more stable if formed in the gas phase. Other results from this research at 0 L men-1, 0.2 L men-1, 0.4 L men-1 and 0.8 L men-1 stable plasma were formed at 675 V, 660 V, 650 V and 650 V. The plasma that can be seen from the bright light, the injection of air accelerates the formation of a gas envelope to reduce energy.
Techno Economic of CNG & GTG Technology Applied in Gas Flare Management Nafiscatoha, Dicgorry; Saksono, Nelson
Proceeding ISETH (International Summit on Science, Technology, and Humanity) 2019: Proceeding ISETH (International Summit on Science, Technology, and Humanity)
Publisher : Universitas Muhammadiyah Surakarta

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.23917/iseth.1416

Abstract

Our environment is being endangered by greenhouse gases from gas flaring processes. Approximately 4 mmscfd is contributed by flare gas from JWB field. The flare gas would be concentrated to become the most economic value and prevent the greenhouse effect. The analysis of economic value is getting the fastest investment return and the most annual profit. This Study would discuss a techno-economic aspect of flare gas utilization technology. In this paper, two methods of compressed natural gas (CNG) and gas to wire (GTW) was combined with CNG would be introduced and applied in this field. For both methods are introduced and compared to the best method from an economic standpoint identified. According to the results, the production of the CNG method of flare gas utilization is the most economical technology; with has a greater ROR, an annual profit of about $3.65 million, and a payback period of 2.09 years. Economic analysis shows there improved gas flare value and improvement environmental protection.
DEVELOPMENT OF WRIGHT BLENDING METHOD IN VISCOSITY ESTIMATION OF LIQUID-BINARY MIXTURE OF BASE OIL AND OLEFIN COPOLYMERS (OCPs) Nelson Saksono; Subiyanto Subiyanto; Setyo Widodo
Scientific Contributions Oil and Gas Vol 34 No 1 (2011)
Publisher : Testing Center for Oil and Gas LEMIGAS

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.29017/SCOG.34.1.642

Abstract

This study aims to develop mathematical equations used in Wright’s method to predictkinematic viscosity of liquid-binary mixture consisting of base oil and additive. The equationis developed by addition of specific constants (αi and αc), representing interaction ofeach component in the mixtures. Evaluation is done using 70 empirical data from 35 samplesderived from liquid blending of 4 types of base oils (B.1, B.2, B.3 and B.4) and olefincopolymers (OCPs), varied in the range of 5-30 % of weight. Kinematic viscosity is measuredat 40oC and 100oC using a cannon automatic viscometer series 2000 (CAV 2000)according to ASTM method D 445. Validation of the equation (Developed-Wright’s method)is performed over all of liquid-binary mixtures of base oil-OCPs, and the accuracy isindicated by percent average absolute deviation (%AAD). The results show that the additionof specific constants could minimize the deviations of estimated values. The averagedeviation of Developed-Wright’s method on kinematic viscosity estimation at 40oC and100oC becomes 2.056 % and 1.917% respectively, lower than Wright’s method which are8.341 % and 14.696%; meanwhile the maximum deviation reaches 5.821 % and 4.657%,lower than Wright’s method which are 21.256 % and 25.265% respectively. These valuesindicate that the Developed-Wright’s method has better accuracy.
Evaluasi Metode Estimasi Viskositas Kinematik Campuran Biner Base Oil dan Aditif Viscosity Modifiers (VMs) Setyo Widodo; Nelson Saksono Saksono; Subiyanto Subiyanto
Lembaran publikasi minyak dan gas bumi Vol 45 No 1 (2011)
Publisher : BBPMGB LEMIGAS

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.29017/LPMGB.45.1.682

Abstract

Penyusunan formula minyak lumas selalu melibatkan pencampuran base oil dan aditif melaluitahapan estimasi dan formulasi skala laboratorium, dilanjutkan dengan produksi skala komersial.Parameter kunci dalam penyusunan formula adalah viskositas kinematik yang nilainya dapatdihitung secara teoretis dan pengujian laboratorium. Beberapa metode estimasi viskositas campuranyang dikenal antara lain persamaan Refutas, metode Wright, dan metode yang dikembangkandan digunakan dalam American Society for Testing and Material (ASTM D 7152).Penelitian ini dilakukan untuk mempelajari akurasi ketiga metode tersebut dalam memprediksiviskositas kinematik campuran biner base oil dan aditif. Sampel campuran biner tersusun daridua jenis base oil mineral produksi PT Pertamina (Persero) dan aditif viscosity modifiers (VMs)produksi Lubrizol yang divariasikan pada kisaran konsentrasi 5-30 % berat. Nilai viskositaskinematik diukur pada temperatur uji 40 dan 100oC menggunakan cannon automatic viscometerseries 2000 (CAV 2000) dengan mengacu pada metode uji ASTM D 445. Evaluasi data dilakukanuntuk mendapatkan nilai persen average absolute deviation (%AAD) sebagai indikator akurasihasil estimasi dari setiap metode dibandingkan dengan data empiris.Hasil penelitian menunjukkan bahwa nilai %AAD pada 24 data uji dari 12 sampel campuranbiner dan temperatur uji 40oC adalah 10,56 %, lebih rendah dibandingkan persamaan Refutas danmetode ASTM, yaitu 41,19 dan 41,25 %. Pada temperatur uji 100oC nilai %AAD metode Wrightadalah 15,03 %, lebih rendah daripada persamaan Refutas dan metode ASTM yaitu 39,15 dan39,43 %. Berdasarkan hasil tersebut, dapat disimpulkan bahwa metode Wright memberikan nilaiestimasi yang lebih akurat dibandingkan dengan persamaan Refutas maupun metode ASTM.
Co-Authors Adiwar Adiwar Adiwar Adiwar, Adiwar Anak Agung Istri Sri Wiadnyani Azwar Manaf Bondan Ariawan, Bondan Chalid, Mochamad Dian R. Suminar Elisabeth A. S. Elsa Krisanti Eva Fathul Karamah Fakhrian Abqari Fakhrian Abqari Fakhrian Abqari, Fakhrian Harianingsih, Harianingsih Harianingsih, Harianingsih Imani, Nadya Alfa Cahaya Iwan Febrianto Maharani Kusumaningrum Miranda Talitha Zagita Muhammad Fadhillah Ansyari Nafiscatoha, Dicgorry Nono Darsono Nono Darsono, Nono Pangestika, Widya Rahma Muthia, Rahma Ratih Tien Seratri, Ratih Roekmijati Soemantojo Roekmijati Soemantojo, Roekmijati Roekmijati W. Roekmijati W. Soemantojo, Roekmijati W. Roekmijati Widaningroem Roekmijati Widaningroem, Roekmijati Roekmijati Widaningrum Roekmijati Widaningrum, Roekmijati Setijo Bismo Setyo Widodo Setyo Widodo Setyo Widodo Subiyanto Subiyanto Subiyanto Subiyanto Subiyanto Suminar, Dian Ratna TATI NURHAYATI Tri S. Budikania Wara Dyah Pita Rengga Yuliusman Yuliusman Yuliusman Yuliusman Zainal Zakaria Zakaria, Zainal